沈阳细河地区土壤镉污染源地球化学研究

镉是一种毒性很大、在自然界中分布广泛的重金属元素。利用辽河流域生态地球化学调查中取得的土壤、大气干湿沉降、灌溉水及农药化肥等样品,对沈阳细河地区土壤中镉污染源进行了甄别及追踪。结果表明: 沈阳细河地区土壤中镉元素污染是由人为源引起,且镉元素污染源主要为污水灌溉、大气降尘及磷肥三种途径。     

胶莱盆地莱阳凹陷莱阳组储层成岩作用及孔隙演化

以野外露头、岩心观察为基础,综合采用普通薄片、铸体薄片、阴极发光薄片、扫描电镜、物性分析、黏土矿物X衍射等多种测试手段对胶莱盆地莱阳组砂岩储层特征、成岩作用及孔隙演化进行了研究。研究结果表明：受物源差异影响,凹陷东部以长石砂岩为主,凹陷西部以岩屑砂岩为主,富含各种塑性岩屑,莱阳组砂岩总体以低成分成熟度、中等结构成熟度为特征。压实作用、压溶作用和胶结作用是造成砂岩储层致密的主要原因。凹陷东部以胶结作用减孔为主,压实程度较弱,碳酸盐胶结物是造成砂岩孔隙度降低的主要胶结物。凹陷西部以压实作用为主,但绿泥石薄膜胶结物的存在有利于保存部分原生孔隙。莱阳组砂岩储层原生孔隙残留较少,多以次生孔隙为主。溶蚀作用,尤其是长石的溶解作用,对改善储层物性有重要作用。次生孔隙发育带主要在K₁llw、K₁ls中,成岩演化达中成岩A期,溶蚀型次生孔隙成为这一阶段主要的孔隙类型,其发育带往往是有利储层发育区。     

Discussion on research advances and hot issues in diagenesis of clastic-rock reservoirs

The research on diagenesis of clastic-rock reservoir is developing rapidly in recent ten years. Thus, it is of great significance in academic and scientific exploration to summarize the domestic and international research progress and the key issues of frontier research on diagenesis. The research progress, main achievement and recognition in diagenesis of clastic-rock reservoirs in recent years is discussed, and the hot issues or developing trend of diagenesis in the future is probed in this paper, on the basis of summarizing the previous research results and understanding, combined with the typical research examples at home and abroad. It is believed that great progress was obtained in provenance and parent rock constraints on sandstone types and their diagenetic evolution pathways, impact of fluid-rock interaction and its product on diagenesis, influence of thermodynamics and overpressure background on diagenesis and pore development, the timing sequence between hydrocarbon accumulation and filling process and the sandstone reservoir becoming low permeability-densification. At present, diagenetic research is developing in direction of the spatial and temporal dynamics and quantitative evolution mechanistic and diagenetic system controlled by the basin fluid dynamics, thermal dynamic processes, combining the micro-scale diagenesis research with the basin macroscopic background such as sedimentation from the source to the basin, burial history, hydrocarbon maturity and charge into reservoirs, tectonic evolution and fluid activity, and fluid and rock interaction.The aim of this paper is to induce the academic peers and experts in diagenesis and the related research fields to come forward with their valuable contributions, to cooperate and work together and joint efforts on the research exquisite, profundity and breadth of diagenesis, and application of the most advanced analytical measurement techniques and methods, as well as integration and infiltration of multidisciplinary, in order to promote the course of the clastic-rock reservoir diagenetic research in China.     

鄂尔多斯盆地中南部三叠系延长组8油层组成岩作用及其对储层物性的控制

鄂尔多斯盆地中南部延长组8油层组主要成岩作用包括压实作用、石英次生加大、自生绿泥石膜生长、次生高岭石化、连晶方解石交代、长石溶蚀。根据铸体薄片,碳氧同位素分析,确定了各种主要成岩产物的空间分布和成因,分析了成岩产物分布与现今总面孔率的关系,从而确定8油层组的物性主要受石英次生加大、连晶方解石、长石溶孔、剩余原生孔隙分布的控制。石英次生加大和连晶方解石发育的地方,储层物性差;具自生绿泥石膜的剩余原生孔隙和长石溶孔发育的地方,储层物性好。     

塔巴庙上古生界砂岩储层成岩作用对孔隙结构的影响

通过研究砂岩储层成岩作用对孔隙结构的影响,证实了引起砂岩储层中的低孔、低渗,已为成岩作用的关键因素。早期强烈的机械压实和胶结作用造成砂岩储层原生孔隙不发育,孔喉配位数以0为主,少量可发育1条~2条喉道,孔隙度损失38%~25%。随后的千枚岩岩屑及其它碎屑矿物的溶蚀和蚀变作用,形成了粒间溶孔、粒内微孔、粒内蜂窝状溶孔以及高岭石晶间隙等,此类孔隙半径一般在8μm~20μm,喉道半径在5μm~10μm,平均孔喉比在2~5左右。但其具有数量多,规模大的特点,一般占总孔隙度的70%以上,对各层段砂岩储层储集性能有一定的改善。保留下来的主要是砂岩储层储集空间类型,有极少量的原生粒间孔主要分布在下石盒子组。     

洞庭湖镉迁移转化的马尔可夫模型评价

讨论了在现时泥沙、水体、鱼类、藻类的含镉状态下洞庭湖的输入输出通量；并以其为例，在简要介绍马尔可夫链数学方法的基础上，建立了湖泊生态系统中镉迁移转化的马尔可夫链数学模型，初步评价了当洞庭湖不断有镉加入、系统到达状态稳定时各种介质中的镉总量及镉的迁移转化趋势。     

环境矿物材料治理镉（Cd^2＋）污染研究进展

近年来,环境矿物材料以其经济、有效、无二次污染等特点,在重金属废水处理和土壤修复方面显示出了众多优势,可替代传统的镉污染处理方法。本文综述了国内外环境矿物材料在处理镉污染方面的研究进展,并对今后应用环境矿物材料治理镉污染提出了一些建议。     

东营凹陷古近系层序地层对成岩规律的控制作用

东营凹陷古近系发育了沙四段底界面(T7)、沙四段与沙三段分界面(T’6)及沙二下亚段顶界面(T’2)等3个二级层序界面。根据对储集层成岩作用的深入研究发现,原有的埋藏成岩作用序列不仅受深度的影响,而且受此层序地层所控制,在层序界面附近和层序体内部存在一定的规律性。据此确定了层序界面附近发育的淋滤、溶解成岩相带和层序体内部发育的黏土矿物转换和化学胶结成岩相带。认识到层序界面通常是流体运移的通道,影响界面上下低水位体系域和高水位体系域内储集层的成岩相展布,对改善储集层储集性能有利;层序体内部储集层成岩差异性明显,储集性往往受到制约。     

Effect of the Dry Ashing Method on Cadmium Isotope Measurements in Soil and Plant Samples

A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ^114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study.     

Encounters with an unearthly mudstone: Understanding the first mudstone found on Mars

The Sheepbed mudstone forms the base of the strata examined by the Curiosity rover in Gale Crater on Mars, and is the first bona fide mudstone known on another planet. From images and associated data, this contribution proposes a holistic interpretation of depositional regime, diagenesis and burial history. A lake basin probably received sediment pulses from alluvial fans. Bed cross‐sections show millimetre to centimetre‐scale layering due to distal pulses of fluvial sediment injections (fine‐grained hyperpycnites), fall‐out from river plumes, and some aeolian supply. Diagenetic features include mineralized synaeresis cracks and millimetre‐scale nodules, as well as stratiform cementation. Clay minerals were initially considered due to in situ alteration, but bulk rock chemistry and mineralogy suggests that sediments were derived from variably weathered source rocks that probably contained pre‐existing clay minerals. X‐ray diffraction analyses show contrasting clay mineralogy in closely spaced samples, consistent with at least partial detrital supply of clay minerals. A significant (ca 30 wt%) amorphous component is consistent with little post‐depositional alteration. Theoretical modelling of diagenetic reactions, as well as kinetic considerations, suggest that the bulk of diagenetic clay mineral formation occurred comparatively late in diagenesis. Diagenetic features (synaeresis cracks and nodules) were previously thought to reflect early diagenetic gas formation, but an alternative scenario of synaeresis crack formation via fabric collapse of flocculated clays appears more likely. The observed diagenetic features, such as solid nodules, hollow nodules, matrix cement and ‘raised ridges’ (synaeresis cracks) can be explained with progressive alteration of olivine/glass in conjunction with centrifugal and counter diffusion of reactive species. Anhydrite‐filled fractures in the Sheepbed mudstone occurred late in diagenesis when fluid pressures built up to exceed lithostatic pressure. Generating fluid overpressure by burial to facilitate hydraulic fracturing suggests a burial depth of at least 1000 m for the underlying strata that supplied these fluids.