改性氢氧化镁对地下水中铅镉的稳定化性能研究

为研究OH-缓释剂对铅、镉污染地下水修复的可行性,通过室内实验制备改性氢氧化镁,并对其去除地下水中Pb和Cd的性能进行研究。实验结果表明,重金属的稳定化机理主要为沉淀反应。在去除单一重金属(Pb或Cd)实验中,Pb和Cd的去除率都可达到99%以上,反应符合一级反应动力学,反应速率常数分别为0.173 7 min-1和0.003 7 min-1。改性氢氧化镁在处理Pb和Cd的复合污染时Pb优先于Cd反应,Pb的存在会对Cd的沉淀起到抑制作用。     

BOOK REVIEWS

Book Reviewed in this article: Unfairly Structured Cities . Blair Badcock Religion and Rural Revolt . Janos M. Bak and Gerhard Benecke The Industrial Geography of Canada . Anthony Blackbourn and Robert G. Putnam The Cuban-American Experience, Culture, Images, and Perspectives. Thomas D. Boswell and James R. Curtis Quaternary Paleoclimatology . R. S. Bradley Development and Crisis in Brazil, 1930–1983 . Luiz Bresser Pereiras Centres of Origin in Biogeography . John C. Briggs Analytical Urban Geography . Martin Cadwallader Geomorphology . Richard J. Chorley , Stanley A. Schumm, and David E. Sugden South Africa: The Impact of Past Geographies . A. J. Christopher The Geography of Underdevelopment. A Critical Survey . D. K. Forbes Health Care in Developing Countries . Wilbert M. Gesler Place to Grow Old: The Meaning of Environment in Old Age . Stephen M. Golant The Emerging Marine Economy of the Pacific . Chennat Gopalakrishnan An Introduction to Agricultural Geography . David B. Grigg The Soviet Union: A Geographical Study . G. Melvyn Howe Geographical Aspects of Health: Essays in Honour of Andrew Learmonth . N. D. Mc Glashan and J. R. Blunden Physical Geography: A Landscape Appreciation . Tom L. Mc Knight Mountain Experience. The Psychology and Sociology of Adventure. Richard G. Mitchell Jr . Systematic and Regional Biogeography. Stanley A. Morain The Economic Transformation of American Cities. T. J. Noyelle and T. M. Stanback , Jr . Normal Accidents: Living With High-Risk Technologies. Charles Perrow Vanishing Farmland: A Legal Solution for the States. Sarah E. Redfield Applied Methods of Regional Analysis: The Spatial Dimensions of Development Policy. Dennis A. Rondinelli Urbanization in Romania. A Geography of Social and Economic Change Since Independence. Per Ronnas Statistical Techniques in Geographical Analysis. Gareth Shaw and Dennis Wheeler The Granite Garden: Urban Nature and Human Design. Anne Whiston Spirn Political Geography: Recent Advances and Future Directions. Peter Taylor and John House Geographia y Medio Ambiente. Manuel Valenzuela -Rubío Nãgara and Commandery: Origins of the Southeast Asian Urban Traditions. Paul Wheatley The Common Fisheries Policy of the European Community. Mark Wise Geography and Gender. Women and Geography Study Group of the IBG Technological Hazards. D. J. Zeigler , J. H. Johnson , S. D. Brunn     

From Soil Pollution to “Cadmium Rice” to Public Health Impacts: An Interdisciplinary Analysis of Influencing Factors and Possible Responses

This article discusses the causes of the contamination of rice with cadmium in China and considers what we know about the severity of the problem. It argues that it is misleading to extrapolate simply from levels of cadmium in soil to health risks, because the uptake of cadmium by crops and the health impacts of the metal are affected by multiple factors. These include not only background levels of cadmium and pollution from mining and industry, but also soil quality, climatic conditions and the type and variety of crops grown. Social and cultural factors, including dietary habits, other exposure sources, nutritional quality and general health status will also affect the intake of cadmium and the severity of health impacts. For these reasons we argue that interdisciplinary analysis is crucial to a better understanding of patterns of risk to health from cadmium pollution, and to the design of effective responsive measures.     

江西九江-彭泽沿长江南岸一带镉来源分析

对九江-彭泽沿长江南岸一带不同成土母质Cd的分布特征在垂向、横向剖面上的研究发现,长江干流冲积成因的砂砾泥质土壤、二叠纪燧石结核(含碳)灰岩质土壤、寒武纪泥页岩质土壤、震旦纪砂岩质土壤,与其它成土母质形成的的残坡积土壤Cd含量差异较大。上述四者Cd平均含量均大于0.3×10-6,是本区Cd高值异常主要赋存地质体。同时元素相关性研究表明,Cd与Zn、Cu、As密切相关,自然源是本地区Cd异常普遍存在的根本原因,而人为源却有可能是高值Cd异常沿长江干流大中城市分布的重要影响因素。     

Paleontological characteristics of the Upper Cenozoic sediments and environmental changes in the Peter the Great Bay area (Sea of Japan)

Paleontological assemblages from Cenozoic sediments of the continental slope in the Peter the Great Bay (Sea of Japan) are characterized. Paleontological remains are represented by diverse and abundant siliceous microfossils (diatoms, silicoflagellates, radiolarians) and palynological complexes. The use of high-resolution biostratigraphic zonations made it possible to specify the age of sediments and reconstruct environmental changes during the last 17 Ma. The history of paleontological studies in this area of the Sea of Japan, which is of key importance for development of methods for marine geological works, is reviewed.     

电感耦合等离子体质谱法测定地质样品中锗和镉的干扰及校正

采用HF-HClO₄-HNO₃分解样品,8 mol/L HNO₃提取剂,外标法校准,电感耦合等离子体质谱法同时测定地球化学样品中锗和镉。选择¹⁰³Rh为内标,确定了最佳仪器参数,研究了Zn、Zr、Sn、Ce、Nd、Sm对Ge和Cd的干扰,试验选择质量数⁷⁴Ge和¹¹⁴Cd作为测定同位素,采用数学公式校正法校正了来自Nd和Sm的二次电离离子对Ge的干扰、Sn对Cd的同质异位素干扰。方法检出限（10s）分别为Ge 30 ng/L、Cd 15 ng/L,精密度（RSD,n=15）为Ge 1.35%、Cd 1.47%。对多种国家一级标准物质进行分析验证,结果与标准值相符。方法适用于地质样品中微量锗和镉的测定。     

Post-mine metal transport and attenuation in the Keno Hill mining district, central Yukon, Canada

 The Keno Hill mining district in central Yukon was the second largest silver producer in Canada with mines operating from 1913 to 1989 on more than 65 vein silver deposits. The seven and a half decades of mining activities have generated large volumes of mine waste disposed on the land surface, resulting in elevated metal contents in numerous small drainages. To assess the extent of metal mobilization, old mine workings and the associated mine waste were examined and the water courses draining to a major river valley sampled. The results of field observations and an array of water and sediment analyses led to three major conclusions. 1. Acid mine drainage is not widespread because of galvanic protection of pyrite from oxidative dissolution and neutralization by carbonates in the country rock. 2. Mechanisms operative to limit aqueous metal transport in small streams in the district include cryogenic precipitation, coprecipitation and sorption. 3. The near-surface concentration of metals limits the options of waste disposal in future mining developments due to potential metal-leaching problems. Received: 12 December 1995 · Accepted: 26 March 1996     

太行山中北段拆离带型金矿的成矿作用研究

阜平、赞皇隆起是太行山区中新生代伸展体制控制的变质核杂质，变质核杂岩的强烈隆升和东、西两邻断陷的大幅度沉降，在变质杂岩核的外围形成长期活动的正向拆离滑脱带。金很容易在拆离滑脱带中迁移，聚集成矿，为此，本文依据已有研究成果及找矿实践提出，在太行山中北段应注意寻找拆离滑脱带型金矿。     

新疆哈图—萨尔托海地区蛇绿岩镁铁质火山杂岩型金矿

哈图—萨尔托海地区金矿主要见于蛇绿岩镁铁质火山杂岩的上部(并不一定是顶部)及下部(并不一定是底部)两个“层位”.成矿物质主要来源于镁铁质火山杂岩,矿化主要发育其中,是典型的蛇绿岩镁铁质火山杂岩型金矿,当属广义的层控矿床.矿化区表现为受断裂裂隙控制,但主要矿床与古火山机构有关.     

燕辽三叠纪碱性偏碱性杂岩体地球化学特征及意义

华北地台北部燕辽地区发现一批三叠纪(245—195Ma)碱性或偏碱性杂岩体。这些杂岩体均贫硅,绝大多数富含铁、镁、钾、磷和稀土等不相容微量元素。~(87)Sr/~(86)Sr初始值为0.7055—0.7057,它们可能源自被交代蚀变的上地幔。结合燕辽地区三叠系的分布及构造形变的研究,表明该地区三叠纪存在构造岩浆活动带,它是本地区印支运动的重要表现。