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排序方式: 共有820条查询结果,搜索用时 62 毫秒
21.
浅层地下水氟的溶解/沉淀作用的定量研究 总被引:12,自引:0,他引:12
以河北邢台山前平原浅层高氟地下水为例,根据氟的化学热力学分析,确定了控制浅层地下水中氟迁移和富集的固相沉淀物,以及不同化学类型的浅层地下水中含氟固相沉淀物的溶解/沉淀条件;利用浅层地下水化学平衡反应模型和PHREEQE软件,确定了氟化的稳定区域,计算了氟化钙的饱和指数.研究结果表明,在浅层高氟地下水的整个形成过程中,都表现为氟由固相转入水相的趋势,有利于氟的迁移和富集 相似文献
22.
23.
Aldar P. Gorbunov 《冰川冻土》2004,26(Z1):197-200
The coarse-detrital deposits have the properties of cold accumulation and maintenance of cold for a long time. Now, at some place where the mean annual temperature of air is positive, one even can get the permafrost by artificial formation of the burial mound. According to these properties, some lowenergy storehouses are built for various purposes. 相似文献
24.
A coupled hydro-chemo-mechanical numerical model is developed for these coupled phenomena in many engineering fields. The
model has been applied to predicting the response of a stressed rockmass column to an injected reactive fluid (reagent) flow.
The response includes evolutions of porosity, permeability, reagent and mineral concentrations during dissolution. In the
model, the progress of dissolution is defined by the change in porosity ratio and the porosity increases with dissolution
assuming there is no precipitation. The numerical evolutions of porosity, permeability, reagent and mineral concentrations
during dissolution are validated against steady state solutions. The model results show that these evolutions are regulated
to a certain extent by the applied external loadings: an applied extensional stress enhances the progress of the dissolution
process while an applied compression stress slows the progress of the dissolution process.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
25.
Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field 总被引:2,自引:2,他引:2
LAI Xingyun YU Bingsong CHEN Junyuan CHEN Xiaolin LIU Jianqing MEI Mingxiang JING Weiguang & CHENG Suhua School of Earth Sciences Mineral Resources China University of Geosciences Beijing China Key Laboratory of Lithospheric Tectonics Deep-level Process Exploration of Ministry of Education Beijing China 《中国科学D辑(英文版)》2005,48(1):21-31
Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid, 相似文献
26.
Uur Doan 《Geomorphology》2005,71(3-4):389-401
Karstification-based land subsidence was found in the Upper Tigris Basin with dimensions not seen anywhere else in Turkey. The area of land subsidence, where there are secondary and tertiary subsidence developments, reaches 140 km2. Subsidence depth ranges between 40 and 70 m. The subsidence was formed as a result of subsurface gypsum dissolution in Lower Miocene formation. Although there are limestones together with gypsum and Eocene limestone below them in the area, a subsidence with such a large area is indicative of karstification in the gypsum. The stratigraphical cross-sections taken from the wells and the water analyses also verify this fact. The Lower Miocene gypsum, which shows confined aquifer features, was completely dissolved by the aggressive waters injected from the top and discharged through by Zellek Fault. This resulted in the development of subsidence and formation of caprock dolines on loosely textured Upper Miocene–Pliocene cover formations. The Tigris River runs through the subsidence area between Batman and Bismil. There are four terrace levels as T1 (40 m), T2 (30 m), T3 (10 m) and T4 (4–5 m) in the Tigris River valley. It was also found that there were some movements of the levels of the terraces in the valley by subsidence. The subsidence developed gradually throughout the Quaternary; however no terrace was formed purely because of subsidence. 相似文献
27.
Numerical modeling of toxic nonaqueous phase liquid removal from contaminated groundwater systems: mesh effect and discretization error estimation 下载免费PDF全文
Numerical modeling has now become an indispensable tool for investigating the fundamental mechanisms of toxic nonaqueous phase liquid (NAPL) removal from contaminated groundwater systems. Because the domain of a contaminated groundwater system may involve irregular shapes in geometry, it is necessary to use general quadrilateral elements, in which two neighbor sides are no longer perpendicular to each other. This can cause numerical errors on the computational simulation results due to mesh discretization effect. After the dimensionless governing equations of NAPL dissolution problems are briefly described, the propagation theory of the mesh discretization error associated with a NAPL dissolution system is first presented for a rectangular domain and then extended to a trapezoidal domain. This leads to the establishment of the finger‐amplitude growing theory that is associated with both the corner effect that takes place just at the entrance of the flow in a trapezoidal domain and the mesh discretization effect that occurs in the whole NAPL dissolution system of the trapezoidal domain. This theory can be used to make the approximate error estimation of the corresponding computational simulation results. The related theoretical analysis and numerical results have demonstrated the following: (1) both the corner effect and the mesh discretization effect can be quantitatively viewed as a kind of small perturbation, which can grow in unstable NAPL dissolution systems, so that they can have some considerable effects on the computational results of such systems; (2) the proposed finger‐amplitude growing theory associated with the corner effect at the entrance of a trapezoidal domain is useful for correctly explaining why the finger at either the top or bottom boundary grows much faster than that within the interior of the trapezoidal domain; (3) the proposed finger‐amplitude growing theory associated with the mesh discretization error in the NAPL dissolution system of a trapezoidal domain can be used for quantitatively assessing the correctness of computational simulations of NAPL dissolution front instability problems in trapezoidal domains, so that we can ensure that the computational simulation results are controlled by the physics of the NAPL dissolution system, rather than by the numerical artifacts. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
28.
Yue Ma Xiao‐Hui Chen Lee J. Hosking Hai‐Sui Yu Hywel R. Thomas Simon Norris 《国际地质力学数值与分析法杂志》2021,45(1):64-82
Coupled thermo‐hydro‐mechanical‐chemical modelling has attracted attention in past decades due to many contemporary geotechnical engineering applications (e.g., waste disposal, carbon capture and storage). However, molecular‐scale interactions within geomaterials (e.g., swelling and dissolution/precipitation) have a significant influence on the mechanical behaviour, yet are rarely incorporated into existing Thermal‐Hydro‐Mechanical‐Chemical (THMC) frameworks. This paper presents a new coupled hydro‐mechanical‐chemical constitutive model to bridge molecular‐scale interactions with macro‐physical deformation by combining the swelling and dissolution/precipitation through an extension of the new mixture‐coupling theory. Entropy analysis of the geomaterial system provides dissipation energy, and Helmholtz free energy gives the relationship between solids and fluids. Numerical simulation is used to compare with the selected recognized models, which demonstrates that the swelling and dissolution/precipitation processes may have a significant influence on the mechanical deformation of the geomaterials. 相似文献
29.
Chemo‐mechanics of cemented granular solids subjected to precipitation and dissolution of mineral species 下载免费PDF全文
This paper studies the chemo‐mechanics of cemented granular solids in the context of continuum thermodynamics for fluid‐saturated porous media. For this purpose, an existing constitutive model formulated in the frame of the Breakage Mechanics theory is augmented to cope with reactive processes. Chemical state variables accounting for the reactions between the solid constituents and the solutes in the pore fluid are introduced to enrich the interactions among the microstructural units simulated by the model (i.e., grains and cement bonds). Two different reactive processes are studied (i.e., grain dissolution and cement precipitation), using the chemical variables to describe the progression of the reactions and track changes in the size of grains and bonds. Finally, a homogenization strategy is used to derive the energy potentials of the solid mixture, adopting probability density functions that depend on both mechanical and chemical indices. It is shown that the connection between the statistics of the micro‐scale attributes and the continuum properties of the solid enables the mathematical capture of numerous mechanical effects of lithification and chemical deterioration, such as changes in stiffness, expansion/contraction of the elastic domain, and development of inelastic strains during reaction. In particular, the model offers an interpretation of the plastic strains generated by aggressive environments, which are here interpreted as an outcome of chemically driven debonding and comminution. As a result, the model explains widely observed macroscopic signatures of geomaterial degradation by reconciling the energetics of the deformation/reaction processes with the evolving geometry of the microstructural attributes. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
30.
Why asymptotic limit of the acid dissolution capacity can lead to a sharp dissolution front in chemical dissolution of porous rocks? 下载免费PDF全文
The use of the asymptotic limit can greatly simplify the theoretical analysis of chemical dissolution front instabilities in fluid‐saturated rocks and therefore make it possible to obtain mathematical solutions, which often play a crucial role in understanding the propagation behavior of chemical dissolution fronts in chemical dissolution systems. However, there has been a debate in recent years that the asymptotic limit of the acid dissolution capacity (i.e., the acid dissolution capacity number approaching zero) alone cannot lead to a sharp dissolution front of the Stefan type in the acidization dissolution system, in which the dissolvable minerals of carbonate rocks are chemically dissolved by the injected acid flow. The acid dissolution capacity number is commonly defined as the ratio of the volume of the carbonate rock dissolved by an acid to that of the acid. In this paper, we use four different proof methods, including (i) direct use of the fundamental concepts; (ii) use of the mathematical governing equations of an acidization dissolution system; (iii) use of the different time scaling approach; and (iv) use of a moving coordinate system approach, to demonstrate that the asymptotic limit of the acid dissolution capacity can indeed lead to sharp dissolution fronts of the Stefan type in acidization dissolution systems on a much larger time scale (than the dissolution time scale). Our new finding is that on the reaction time scale, the condition of the conventional time derivative of porosity approaching zero alone can ensure that the acidization dissolution front has a sharp shape of the Stefan type. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献