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21.
Jean-Paul Vicat Hubert Mvondo Luc Willems André Pouclet 《Comptes Rendus Geoscience》2002,334(8):545-550
Numerous karstic features have been recognised in the non-carbonaceous micaschists and gneisses of the Yaoundé Pan-African nappe, south of Cameroon. It is shown that their formation was controlled by the structural features of the rocks. The wells and the pipes in the bedrock outcrops point out a current karstification process, resulting from the plagioclase dissolution by the acid rain waters. Hill wall alveoli and caves, of pre-Miocene age, are exhumed features that were done by dissolution in the aquiferous underground. To cite this article: J.-P. Vicat et al., C. R. Geoscience 334 (2002) 545–550. 相似文献
22.
R. Hellmann J.-M. Penisson R. L. Hervig J.-H. Thomassin M.-F. Abrioux 《Physics and Chemistry of Minerals》2003,30(4):192-197
Using an approach combining high-resolution and energy-filtered transmission electron microscopy (HRTEM and EFTEM), we have studied with Å to nm-spatial resolution the interfacial region that delimits the near-surface altered zone and non-altered labradorite feldspar after dissolution under acid pH conditions. The interface is characterized by extremely sharp and spatially coincident changes in structure and chemistry. The 500-nm-thick altered zone is depleted in interstitial cations (Ca, Na, K) and Al, a framework element, whereas it is enriched in H, O, and Si. Modeling H+-alkali interdiffusion within a 500-nm-thick altered zone shows that volume interdiffusion cannot reproduce the sharp chemical interfaces measured by EFTEM. Based on these new data, we propose that the near-surface altered zone is a result of interfacial dissolution-reprecipitation, and not of preferential leaching of cations and interdiffusion with H+. This implies an intrinsic dissolution process that is stoichiometric, where the breaking of bonds and release of interstitial cations and framework elements (Al, Si, and O) to solution occur contemporaneously at equal relative rates from the original fluid–mineral interface. 相似文献
23.
地球化学样品中硒的循序提取技术 总被引:11,自引:0,他引:11
研究开发了一种硒的循序偏提取步骤,将地球化学样品中的硒选择性地循序提取到六个“操作上”定义的相态中:水溶性硒(水提取);吸附在氧化矿物和粘土矿物上配位可交换的亚硒酸根离子(0.1mol/LKH2PO4提取);与有机质结合的硒(0.1mol/LNa4P2O7提取);与铁锰铝氧化物和碳酸盐结合的硒(4.0mol/LHCl提取);硫化物中的硒(KClO3+浓HCl提取);硅酸盐残渣中以副矿物和被硅质包裹的硒微粒存在的硒(HF+HNO3+HClO4强混合酸溶解)。对提取步骤的可行性和实用性作了详细的讨论。 相似文献
24.
浅层地下水氟的溶解/沉淀作用的定量研究 总被引:12,自引:0,他引:12
以河北邢台山前平原浅层高氟地下水为例,根据氟的化学热力学分析,确定了控制浅层地下水中氟迁移和富集的固相沉淀物,以及不同化学类型的浅层地下水中含氟固相沉淀物的溶解/沉淀条件;利用浅层地下水化学平衡反应模型和PHREEQE软件,确定了氟化的稳定区域,计算了氟化钙的饱和指数.研究结果表明,在浅层高氟地下水的整个形成过程中,都表现为氟由固相转入水相的趋势,有利于氟的迁移和富集 相似文献
25.
26.
Aldar P. Gorbunov 《冰川冻土》2004,26(Z1):197-200
The coarse-detrital deposits have the properties of cold accumulation and maintenance of cold for a long time. Now, at some place where the mean annual temperature of air is positive, one even can get the permafrost by artificial formation of the burial mound. According to these properties, some lowenergy storehouses are built for various purposes. 相似文献
27.
A coupled hydro-chemo-mechanical numerical model is developed for these coupled phenomena in many engineering fields. The
model has been applied to predicting the response of a stressed rockmass column to an injected reactive fluid (reagent) flow.
The response includes evolutions of porosity, permeability, reagent and mineral concentrations during dissolution. In the
model, the progress of dissolution is defined by the change in porosity ratio and the porosity increases with dissolution
assuming there is no precipitation. The numerical evolutions of porosity, permeability, reagent and mineral concentrations
during dissolution are validated against steady state solutions. The model results show that these evolutions are regulated
to a certain extent by the applied external loadings: an applied extensional stress enhances the progress of the dissolution
process while an applied compression stress slows the progress of the dissolution process.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
28.
Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field 总被引:2,自引:2,他引:2
LAI Xingyun YU Bingsong CHEN Junyuan CHEN Xiaolin LIU Jianqing MEI Mingxiang JING Weiguang & CHENG Suhua School of Earth Sciences Mineral Resources China University of Geosciences Beijing China Key Laboratory of Lithospheric Tectonics Deep-level Process Exploration of Ministry of Education Beijing China 《中国科学D辑(英文版)》2005,48(1):21-31
Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid, 相似文献
29.
Uur Doan 《Geomorphology》2005,71(3-4):389-401
Karstification-based land subsidence was found in the Upper Tigris Basin with dimensions not seen anywhere else in Turkey. The area of land subsidence, where there are secondary and tertiary subsidence developments, reaches 140 km2. Subsidence depth ranges between 40 and 70 m. The subsidence was formed as a result of subsurface gypsum dissolution in Lower Miocene formation. Although there are limestones together with gypsum and Eocene limestone below them in the area, a subsidence with such a large area is indicative of karstification in the gypsum. The stratigraphical cross-sections taken from the wells and the water analyses also verify this fact. The Lower Miocene gypsum, which shows confined aquifer features, was completely dissolved by the aggressive waters injected from the top and discharged through by Zellek Fault. This resulted in the development of subsidence and formation of caprock dolines on loosely textured Upper Miocene–Pliocene cover formations. The Tigris River runs through the subsidence area between Batman and Bismil. There are four terrace levels as T1 (40 m), T2 (30 m), T3 (10 m) and T4 (4–5 m) in the Tigris River valley. It was also found that there were some movements of the levels of the terraces in the valley by subsidence. The subsidence developed gradually throughout the Quaternary; however no terrace was formed purely because of subsidence. 相似文献
30.
Evolution of the Magma Chamber beneath Usu Volcano since 1663: a Natural Laboratory for Observing Changing Phenocryst Compositions and Textures 总被引:2,自引:1,他引:2
We have investigated the evolution of an active silicic magma-feedingsystem beneath Usu volcano, Japan, where eight eruptions havebeen recorded since AD 1663. All magmatic products contain similartypes of plagioclase and orthopyroxene phenocrysts that consistof homogeneous cores with uniform compositions, and a zonedmantle that increases in size with time. The compositions ofplagioclase and orthopyroxene phenocrysts vary gradually andregularly with time, as do the bulk-rock compositions. The textureof these phenocrysts also changes systematically, caused byprogressive crystal growth, dissolution and diffusion. On thebasis of these observations, we conclude that the same magma-feedingsystem has persisted at Usu volcano since AD 1663. Compositionalvariation of magnetite phenocrysts differs from that of plagioclaseand orthopyroxene, because magnetite has large diffusion coefficientsand should represent magmatic conditions immediately beforethe eruption. Most pumices from Usu volcano contain two typesof magnetite phenocryst, each with a different composition andcrystallization temperature, indicating that two magmas mixedbefore each eruption (approximately several days before). Theend-members changed with time: rhyolite + basaltic andesite(1663); dacite ± rhyolite (1769, 1822, 1853); dacite± dacite (1977, 2000). The temperature of the magma apparentlyincreases with time, and the increase can be explained by sequentialtapping from a magma chamber with a thermal and chemical gradientin addition to injection of high-temperature magma. KEY WORDS: continuous existence of magma chamber; dacite; dissolution and diffusion of phenocrysts; magma mixing; magnetite 相似文献