新疆阿尔泰南缘巴利尔斯铁矿床稀土元素地球化学研究

巴利尔斯铁矿是阿尔泰南缘麦兹盆地新近发现的中型铁矿床.赋存于上志留—下泥盆统康布铁堡下亚组第二岩性段变粒岩、浅粒岩及斜长角闪岩中,矿体及其周围发育大量矽卡岩矿物.本文对矿体围岩、矽卡岩矿物和矿石进行了稀土元素地球化学研究,结果表明磁铁矿矿石、矽卡岩与围岩斜长角闪岩的 REE 特征具有相似性,暗示磁铁矿矿石与矽卡岩具有亲缘性,斜长角闪岩可能提供部分成矿物质.矽卡岩和矿石发育Eu正异常及所有矿石的负Ce异常,表明铁成矿作用发生在高温氧化环境.     

内蒙古乌尼克吐铅锌矿电法异常特征及试验

以时间域中梯装置激发极化、偶极—偶极装置相位激电测深和可控源音频大地电磁测深在内蒙古乌尼克吐铅锌矿试验结果为例,验证综合电法在寻找矽卡岩型铅锌矿床中的作用及找矿效果。试验结果表明,在激发极化普查测量中应注意供电电极与异常体之间相互关系,否则会产生虚假异常;在勘查区岩矿石电性条件较好的情况下,激发极化面积测量基本能够反映出异常源平面分布情况。在矿(体)与围岩之间的电阻率差异不明显的条件下,较相位激电测深,可控源音频大地电磁测深基本能够推断出矿体的空间赋存位置。所以,时间域中梯装置激发极化与可控源音频大地电磁测深的电法组合在有色金属矿产勘查中可以发挥更大作用。     

Skarn Mineral and Stable Isotopic Characteristics of Tonglushan Cu-Fe Deposit in Hubei Province

湖北大冶铜绿山铜铁矿床是长江中下游西段鄂东南矿集区一个大型夕卡岩矿床.围岩为三叠系大理岩及白云质大理岩,决定了其发育丰富的钙镁质复合夕卡岩矿物组合,包括石榴子石、辉石、角闪石、绿帘石、金云母、绿泥石等.本文详细描述了夕卡岩不同阶段矿物的特征,并对矿物进行了电子探针分析(EPMA)及碳、氧、硫稳定同位素研究.结果表明石榴子石形成于三期,成分上属于钙铝—钙铁系列,且从早到晚具有从钙铝向钙铁榴石演化趋势,反映出成矿溶液由酸性向碱性演化.环带结构的石榴子石和绿帘石从核部到边部Fe含量增高,说明磁铁矿是在Fe浓度升高的碱性溶液中沉淀.辉石为透辉石.角闪石属于单斜角闪石中的钙质角闪石,包括透闪石,韭闪石和少量阳起石.矿物成分分析表明辉石和石榴子石的Mn/Fe值与矿化金属元素存在一定的联系.相对于钙质夕卡岩,镁质或含镁质夕卡岩是铜铁矿体交代的更有利岩石.矿床硫化物的δ34 SV-CDT均为正值且变化范围较窄,介于0.6‰～3.8‰.成矿阶段方解石δ13CV-PDB变化于-2.9‰～6.3‰,δ18OV-SMOW变化于9.6‰ ～ 12.6‰,成矿后方解石的同位素值明显增大,δ13CV-PDB为-0.9‰ ～ 1.3‰,δ18OV-SMOW为15.2‰ ～ 17.3‰,趋向于围岩的同位素值.研究结果说明成矿阶段的硫和碳来自于深源或地幔,而成矿后期碳与地层发生明显的同位素交换反应.     

安徽淮北三铺地区镁夕卡岩金（铜、铁）矿床生成地质环境、分带和流体演化

世界上的含金夕卡岩大多属钙夕卡岩型,镁夕卡岩金矿床十分稀少。本文介绍我国安徽北部三铺地区镁夕卡岩金（铜、铁）矿床的地质地球化学特征。该区含金（铜、铁）镁夕卡岩主要产于台地断拗区燕山期石英二长闪长玢岩与中上寒武统白云质大理岩外接触带。岩体内接触带发育钙夕卡岩和钾长石化,局部有辉钼矿化产出。金矿化与铜的硫化物密切共生,属于镁夕卡岩的退化热液交代作用产物。金属矿化分带序列自蚀变石英二长闪长玢岩到镁夕卡岩     

Multi‐slicing strategy for the three‐dimensional discontinuity layout optimization (3D DLO)

Discontinuity layout optimization (DLO) is a recently presented topology optimization method for determining the critical layout of discontinuities and the associated upper bound limit load for plane two‐dimensional and three‐dimensional (3D) problems. The modelling process (pre‐processing) for DLO includes defining the discontinuities inside a specified domain and building the target function and the global constraint matrix for the optimization solver, which has great influence on the the efficiency of the computation processes and the reliability of the final results. This paper focuses on efficient and reliable pre‐processing of the discontinuities within the 3D DLO and presents a multi‐slicing strategy, which naturally avoids the overlapping and crossing of different discontinuities. Furthermore, the formulation of the 3D discontinuity considering a shape of an arbitrary convex polygon is introduced, permitting the efficient assembly of the global constraint matrix. The proposed method eliminates unnecessary discontinuities in 3D DLO, making it possible to apply 3D DLO for solving large‐scale engineering problems such as those involving landslides. Numerical examples including a footing test, a 3D landslide and a punch indentation are considered, illustrating the effectiveness of the presented method. © 2016 The Authors. International Journal for Numerical and Analytical Methods in Geomechanics published by John Wiley & Sons Ltd.     

内蒙古黄岗梁铁锡矿床成岩、成矿时代与构造背景

内蒙古黄岗梁铁锡矿床位于大兴安岭成矿带中南段,是一个典型的夕卡岩型多金属矿床。为了精确厘定该矿床的成岩、成矿时代,对与成矿关系密切的花岗岩进行了锆石LA-ICP-MS U-Pb年代学研究,结合矿石中辉钼矿的Re-Os等时线年龄,对该矿床形成的地球动力学背景进行了深入的探讨。花岗岩锆石LA-ICP-MS年代学研究表明花岗岩的结晶年龄为139.96±0.87 Ma,是早白垩世岩浆活动的产物。矿床辉钼矿Re-Os等时线年龄为134.9±5.2Ma,成岩和成矿时代在误差范围内基本一致,均处于燕山期大规模中酸性岩浆活动期内。综合矿床地质特征、成岩成矿时代和区域构造演化,认为黄岗梁铁锡矿床形成于大兴安岭成矿带140 Ma左右的锡多金属成矿高峰期,矿床形成于由全面的挤压向伸展过渡阶段的构造背景。     

铜陵天马山硫金矿床矽卡岩矿物学特征及矿石硫同位素地球化学研究

天马山硫金矿是铜陵矿集区典型的层控热液叠加改造型矿床,层状矿体中发育大量的矽卡岩矿物。为查明该矿床中矽卡岩矿物的类型及形成环境,探讨矽卡岩与硫、金成矿之间的关系,对主要的矽卡岩矿物开展了矿物学及矿物化学研究,并对矿石进行了硫同位素地球化学研究。研究表明:矿区内的矽卡岩矿物以石榴子石和辉石为主,其中石榴子石以钙铁榴石为主,属于钙铁榴石-钙铝榴石固熔体系列(Gro0~18.73And80.54~99.00Spe+Pyr+Alm0.54~1.47);辉石以透辉石为主,其次为钙铁辉石,属于透辉石-钙铁辉石系列(Di62.35~97.65Hd1.89~36.27Jo0.31~1.55)。天马山硫金矿的矿物组合(钙铁辉石+透辉石)属于氧化型矽卡岩,表明矽卡岩形成于相对高温和高氧逸度的条件。石榴子石和辉石端元组分特征及辉石Mn/Fe值(0.02~0.07)具有典型的矽卡岩型铜、金矿床特征。矿石硫同位素具有岩浆源的特征,与区内燕山期岩浆-成矿作用形成的矿石一致,而明显区别于喷流-沉积作用形成的矿石,显示成矿作用与燕山期岩浆活动具有密切的成因联系。燕山期中酸性岩浆交代碳酸盐岩围岩形成大量矽卡岩,矽卡岩矿物的形成增加了岩石的孔隙度和渗透率,为晚期硫、金矿床的形成提供了有利条件。     

Mineralogy,Fluid Inclusions,and Sulfur Isotopes of the Huanzala Deposits,Peru: Early Skarn and Late Polymetallic Replacement Style Mineralizations

Carbonate‐replacement polymetallic mineralization at the Huanzala deposits (9°51′S, 77°00′W) was conducted in two contrasting stages that occurred in almost the same location. Early‐stage mineralization has a relation with a granodiorite porphyry stock, whereas the late‐stage mineralization is genetically associated with quartz porphyry sills. The early stage involved low to intermediate sulfidation Cu–Zn–(Pb) mineralization associated with metasomatic skarn, and the late stage involved high to intermediate sulfidation Cu–Zn–Pb–(Mn) mineralization associated with hydrothermal alteration characterized by paragonitic sericitization. The orebodies are hosted by steeply dipping (approximately 60°NE) Lower Cretaceous carbonate rocks in a relatively narrow range of approximately 4 km in horizontal extent and less than 1 km in depth. The pathway of the early‐stage brine‐derived fluids (300–>400°C, >33 wt% NaCl equivalent) along a plot of log against 1000/T is best explained by the progressive dual decline of the value and the temperature under rock‐buffering conditions; this decline saw the pathway progress through the stability field of pyrrhotite to reach that of pyrite and promoted a decrease in FeS from 14.5 to 1.6 mol% in the sphalerite. In contrast, an explanation for the pathway of the late‐stage fluids (140–290°C, 3–13 wt% NaCl equivalent) is given by an almost isothermal decline at approximately 270°C, with passing through the stability field of pyrite–bornite to reach that of chalcopyrite, promoting an increase in FeS from 0.1 to 1.6 mol% in the sphalerite, suggesting gas‐buffering conditions. The ore formation pressure records in the fluid inclusions illustrate an approximately 2‐km erosion during the roughly 2‐Myr total lifetime of the hydrothermal system.     

福建政和铁山铅锌矿床地质特征及成因

福建省政和县铁山铅锌矿床位于闽东中一新生代火山活动带。大地构造上处于建瓯一遂昌上古台拱与浙闽粤沿海断陷交接处。矿体产于晚震旦世一早古生代稻香组与铁山混染正长岩及燕山晚期枫林黑云母花岗岩接触带以及接触带围岩一侧的顺层裂隙之中。矿体与接触带产状基本一致,主要受地层产状及接触带控制。矿体呈似层状、透镜状,部分呈脉状。矿石品位较高,以铅锌矿石为主,次为黄铜铅锌矿石和铅锌磁铁矿石。矿床物质来源于地层、岩体特别是沉积岩中的火山质夹层。矿床成因类型为层控矽卡岩型。     

江南钨矿带桂林郑富钼白钨矿稀土元素的富集机制及其地质意义

桂林郑钼钨多金属矿床位于江南钨矿带北部,其矿石矿物以富钼白钨矿为主。研究显示,该矿床富钼白钨矿中富集稀土元素。为探究其富集机制,文章对不同世代的富钼白钨矿进行原位LA-ICP-MS微量分析和面扫描分析。结果显示,富钼白钨矿的总稀土元素含量（∑REE）在28.59×10^-6~4863.82×10^-6之间,均值为789.21×10^-6（n=122）,从第一世代（Sch-Ⅰ）28.59×10^-6~1059.18×10^-6（平均值为203.19×10^-6,n=55）→第二世代（Sch-Ⅱ）533.54×10^-6~2536.51×10^-6（平均值=928.79×10^-6,n=30）→第三世代（Sch-Ⅲ）117.21×10^-6~4863.82×10^-6（平均值=1547.13×10^-6;n=37）逐渐增高。从Sch-Ⅰ→Sch-Ⅱ→Sch-Ⅲ,轻重稀土元素比值（LREE/HREE）13.99~143.90（平均值=53.53）→22.38~70.08（平均值=33.74）→7.44~69.86（平均值=27.54）逐渐降低。桂林郑富钼白钨矿形成于高氧逸度、富F的岩浆热液系统,REE主要以Ca²⁺+Mo⁶⁺=REE³⁺+(1-x) Mo⁵⁺+xNb⁵⁺(0≤x≤1）为主导方式进入富钼白钨矿中。成矿流体中Cl降低、F增高、氧逸度降低等是REE进入富钼白钨矿的有利条件。通过对江南钨矿带代表性矽卡岩型矿床综合对比分析显示,富钼白钨矿床相比贫钼白钨矿床具有更高的REE,说明桂林郑矿床富钼白钨矿在后续开采中具有稀土元素的综合利用前景。