极谱催化波测定天然水中微量锗的研究

系统研究了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４－Ｖ体系报道极谱催化波的影响因素，测定了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４三元配合物的配合比为１：２：１。实验初步证明了该体系催化波为具有吸附性质的平行催化波。本法检出限为０．１４ｍｇ．ｍＬ＾－１，相对标准偏差小于９．８９％，标准回收率为９３．７０％－１０９．０％，０－５０ｍｇ．ｍＬ＾－１的锗具有良好的线性关系。     

应力波与可滑移岩石界面间的相互作用研究

研究了应力波与用节理刚度系数描述的线性滑移岩石界面间的相互作用，给出了其透、反射波幅的一般表达式。通过应力波垂直人射界面时的具体分析，反映出岩石界面的节理刚度对应力波传播的重要影响，并揭示了岩石界面对应力波的高频滤波作用。     

Effects of geology and human activity on the dynamics of salt-water intrusion in three coastal aquifers in southern Spain

 Mathematical modelling of salt-water intrusion processes in three aquifers on the southern coast of Spain (Río Verde, Río Vélez and Castell de Ferro) reveals that, although all three systems are subject to the same climate and seasonal over-exploitation, geological and human factors have very different effects on the dynamics of contamination. In the Río Verde aquifer, the most important influence is the high volume of extractions occurring during the dry season; in Río Vélez, the intrusion is strongly controlled by infiltration of water from the river to the aquifer, and, in the Castell de Ferro system, an intensely karstified carbonate massif lying in contact with both the sea water and the detrital aquifer represents the main entrance point for influx of sea water and subsequent washing of the aquifer. We have undertaken a mathematical simulation of various possible measures to counteract intrusion, according to the specific characteristics of the process in each aquifer. These measures include artificial recharge, use of natural recharge from the river as a hydraulic barrier, and the construction of a low-permeability barrier. Received: 5 December 1995 · Accepted: 12 April 1996     

Barotropic local instability and severe storm process

By means of barotropic model, the characteristic and initial value problems are investigated to reveal the local two-dimensional barotropic instability of the nonuniform current to the dynamic mechanism of the formation of the Yangtze-Huaihe River severe storm in July 1991. Analytical theory and numerical experiment show that (i) the unstable developing modes are chiefly the two periods of about 44 d and 10 d, which are fundamentally consistent with that of the precipitation change of the Yangtze-Huaihe River. (ii) The growth rate of the local perturbation is dominated by the meridional wave numbern = 1–5 and zonal wave numberk = 1–12, i.e. the severe storm over the Yangtze-Huaihe River results from the interaction of the systems at different latitudes and waves of different scales, (iii) The perturbation over the Yangtze-Huaihe River possesses the property of local intensification, which slowly migrates westward over the lower and middle reaches of the Yangtze-Huaihe River. (iv) The growth rate of the instability, especially the propagation velocity of the perturbation, is sensitive to the external parameters ū and α. Project supported by the National Natural Science Foundation of China.     

Properties of wave velocity for two types of granitoids at high pressure and temperature and their geological meaning

The wave velocity for two types of granitoids was measured using the analytic method of full-wave vibration at high pressure and high temperature. The laws of velocity changes for them differ with the pressure boost and temperature rise, and the velocity change of S-type is more violent than that of I-type. The “softening point” of compressional wave velocity (V μ) is also revealed during the measurement for two types of granitoids imitating the pressure and temperature at a certain depth. But the depth of “softening”, V_p after “softening” and the percentage of V_p’s drop around the “sofrening point” for two types of granitoids are obviously different. The depth of “softening” is 15 km approximately and V_p after “softening” is 5.62 km/s for S-type granitoid. But for I-type granitoid the depth of “softening” is 26 km approximately and V_p after “softening” is 6. 08 km/s. Through careful analysis of rock slices after the experiment, it was found that the “softening” of elastic-wave velocity is caused by the partial melting of granite. Combined with the results of geophysical prospecting, these results suggest that the low-velocity layers developing in the interior of Earth crust are related to thc partial melting of different types of granitoids. The formation of the low-velocity layer in the upper-middle Earth crust is closely related to the development of S-type granitoid, but that in the lower Earth crust is closely related to the development of I-type granitoid.     

Large-Eddy Simulation of Turbulent Flow Over a Rough Surface

A family of wall models is proposed that exhibits moresatisfactory performance than previousmodels for the large-eddy simulation (LES) of the turbulentboundary layer over a rough surface.The time and horizontally averaged statistics such asmean vertical profiles of windvelocity, Reynolds stress, turbulent intensities, turbulentkinetic energy and alsospectra are compared with wind-tunnel experimental data.The purpose of the present study is to obtain simulatedturbulent flows that are comparable with wind-tunnelmeasurements for use as the wind environment for thenumerical prediction by LES of source dispersion in theneutral atmospheric boundary layer.     

Turbulent Pressure Statistics in the Atmospheric Boundary Layer from Large-Eddy Simulation

We use large-eddy simulation (LES) to study the turbulent pressure field in atmospheric boundary layers with free convection, forced convection, and stable stratification. We use the Poisson equation for pressure to represent the pressure field as the sum of mean-shear, turbulence–turbulence, subfilter-scale, Coriolis, and buoyancy contributions. We isolate these contributions and study them separately. We find that in the energy-containing range in the free-convection case the turbulence–turbulence pressure dominates over the entire boundary layer. That part dominates also up to midlayer in the forced-convection case; above that the mean-shear pressure dominates. In the stable case the mean-shear pressure dominates over the entire boundary layer.We find evidence of an inertial subrange in the pressure spectrum in the free and forced-convection cases; it is dominated by the turbulence–turbulence pressure and has a three-dimensional spectral constant of about 4.0. This agrees well with quasi-Gaussian predictions but is a factor of 2 less than recent results from direct numerical simulations at moderate Reynolds numbers. Measurements of the inertial subrange pressure spectral constant at high Reynolds numbers, which might now be possible, would be most useful.     

Geometric form of Haiyuan fault zone in the crustal interior and dynamics implications

The deep seismic reflection data on profile HY2 are reprocessed by the method of simultaneous inversion of velocity distribution and interface position. By the travel-time inversion with the data of the diving wave Pg and fault plane reflection wave, we determine the geometric form and velocity of Haiyuan fault zone interior and surrounding rock down to 10 km depth. The measured data show that the amplitudes have strong attenuation in the range of stake number 37–39 km, suggesting the fault zone has considerable width in the crustal interior. The results of this paper indicate that to the north of the fault zone the crystalline basement interface upheaves gradually from southwest to northeast and becomes shallow gradually towards northeast, and that to the south of the fault zone, within the basin between Xihua and Nanhua mountains, the folded basement becomes shallow gradually towards southwest. The obliquity of the fault zone is about 70° above the 3 km depth, about 60° in the range of the 3–10 km depths. From the results of this paper and other various citations, we believe that Haiyuan fault zone is in steep state from the Earth’s surface to the depth of 10 km. Foundation item: Joint Seismological Science Foundation of China (201001) and State Key Basic Research Development and Programming Project (95-13-02-02). Contribution No. RCEG200308, Exploration Geophysical Center, China Earthquake Administration.     

Simulation of oasis breeze circulation in the arid region of the Northwestern China

In this paper, the process of oasis-desert circulation (ODC) is simulated by MM5V3.5 model through designing an ideal oasis-desert scheme and assuming that initial atmosphere is at rest (V = 0). The findings showed that the key of forming special oasis boundary structure is the difference of energy and water between oasis and desert. The evaporation of oasis surface consumes heat energy, and the low temperature of oasis causes an oasis breeze circulation (OBC), which drives an ODC with a downdraft over the oasis and an updraft over the desert. Later, the cold, dry and stable boundary over oasis is gradually formed, on the contrary,the atmospheric boundary over desert on the edge of oasis is hot, humid and unstable and its height is about 600 hPa. The updraft over the desert forms a wet ring that acts as a vertical wall weakening the low-level moisture exchange between the oasis and desert. The downdraft of OBC increases the atmospheric stability that reduces the oasis evaporation. The low-level outflow from the oasis (into the desert) prevents the dry, hot air flowing from the desert into the oasis.Thus an oasis self-preservation mechanism may be formed due to OBC. The horizontal area influenced by oasis is twice as oasis area and the vertical range is four times as oasis. The ODC is strong in the daytime and reaches the strongest at 17:00, and the influenced area is the largest at 20:00.