幔源CO_2释出机理、脱气模式及成藏机制研究进展

针对幔源CO2如何从地幔岩浆中脱出并进入沉积地层中形成CO2气藏聚集这一关键问题,总结了国内外研究进展和前缘方向。研究表明,地幔深部的碱性玄武岩浆和碱性岩浆才是深部流体和CO2等挥发份大量赋存、渗滤和释出的场所。浅成侵入岩、次火山岩和火山通道等是CO2释放和聚集的有利位置,岩浆期后和岩浆衰弱期的热液活动阶段是CO2大量释放和聚集的有利时期。幔源CO2进入沉积盆地中具有3种脱气模式,即沿岩石圈断裂直接脱气模式、热流底辟体脱气模式和壳内岩浆房-基底断裂组合脱气模式。CO2的固有物化性质决定其运移相态多样,具有运移和聚集过程同步的特征。只有在满足大量的化学消耗及地层水或原油的溶解和耗散之后才能形成CO2有效聚集。幔源CO2成藏和分布主要受岩浆气源体和气源断裂体系的控制。今后,在超临界CO2及其对油气运移聚集的作用、CO2与深大断裂及火山岩的关系、CO2脱气运移机制、CO与常规烃类油气的耦合差异成藏机制等方面仍需要进一步的研究和探索。     

松辽盆地宋芳屯油田扶杨油层孔隙结构及其影响因素

通过镜下观察,宋芳屯油田扶杨油层孔隙类型较多,以粒间孔为主。细管压力曲线上看,曲线较陡,分选差,孔隙结构特征参数总体上较差,与孔隙度、渗透率有一定的关系,大的孔隙对渗透率的贡献最大。扶杨油层的孔隙结构较复杂主要由于成岩作用影响,压实作用使孔隙空间显著缩小,胶结作用和自生粘土矿物生长使孔隙进一步缩小和复杂化,后期的溶蚀作用使孔隙空间增加。     

Multi-Scale Texture Modeling

Patterns of crystallographic preferred orientation are referred to as texture. The specific subject of texture analysis is the experimental determination and interpretation of the statistical distribution of orientations of crystals within a specimen of polycrystalline material, which could be metals or rocks. The objective is to relate an observed pattern of preferred orientation to its generating processes and vice versa. In geosciences, texture of minerals in rocks is used to infer constraints on their tectono-metamorphic history. Since most physical properties of crystals, such as elastic moduli, the coefficients of thermal expansion, or chemical resistance to etching depends on crystal symmetry and orientation, the presence of texture imparts directional properties to the polycrystalline material. A major issue of mathematical texture analysis is the resolution of the inverse problem to determine a reasonable orientation density function on SO(3) from measured pole intensities on , which relates to the inverse of the totally geodesic Radon transform. This communication introduces a wavelet approach into mathematical texture analysis. Wavelets on the two-dimensional sphere and on the rotational group SO(3) are discussed, and an algorithms for a wavelet decomposition on both domains following the ideas of Ta-Hsin Li is given. The relationship of these wavelets on both domains with respect to the totally geodesic Radon transform is investigated. In particular, it is shown that the Radon transform of these wavelets on SO(3) are again wavelets on . A novel algorithm for the inversion of experimental pole intensities to an orientation density function based on this relationship is developed.     

Upper Cretaceous carbonate hosted zinc–lead–barite deposits in Northern Thrust Zone, northern Iraq: petrography and geochemistry

Zinc–lead–barite deposits located in Lefan and Lower Banik localities of about 25 km northeast of Zakho City, Northern Iraq consist of a group of strata-bound sulfides hosted in Upper Cretaceous (Upper Campanian–Maastrichtian) dolomitic limestone. Carbonate-hosted ores contain 3.77% Zn, 2% Pb, and 5% Fe, while in lower Banik, they contain 1.5% Zn, 0.37% Pb, and 1.4% Fe. Diagenetic processes, such as dolomitization and recrystalization in addition to the type of microfacies, provided appropriate physical and chemical conditions that permitted the passage of ore-bearing fluids and participated in precipitation and ore localization. These deposits are precipitated in a platform and developed within the Foreland Thrust Belt. Ore precipitated as infill of intergranular dolomite porosity with replaced dolomite and rudist shells forming disseminated crystals that occupy intergranular pore spaces around dolomite and calcite and as infill of dissolution spaces and fractures.     

热液成矿作用的地质地球化学动力学——以胶东牟平-乳山金矿带为例

通过对胶东牟平—乳山热液脉状金,铅锌矿床成矿动力学控制规律的研究,说明了建立热液成矿反应体系的方法,并得出以下认识:（1）区域断裂构造活动,通过影响成矿反应体系的热力学性质和条件,控制元素的富集和分散。（2）热液成矿过程中容矿断裂活动可划分为两种作用方式:脆性破裂和韧—脆性张开,构成热液成矿的两种构造动力学环境。（3）热液成矿反应体系是一种开放的动态的热力学体系。断裂的脆性破裂阶段,使体系处于强烈的过饱和状态,矿质在远离平衡状态下快速结晶,加剧物质分异;在脆—韧性张开阶段,矿质在接近平衡态体系中缓慢晶出。（4）热液演化晚期,金在残余溶液中富集;当断裂再次发生构造脉动震颤时,早期形成的块状黄铁矿矿石碎裂,富金溶液充填其中,形成含裂隙金和晶隙金的富矿石。成矿体系热力学演化与构造动力学条件有利的匹配控制着富矿石的形成。     

Variation in the composition of Lake Bonneville marl: a potential key to lake-level fluctuations and paleoclimate

Lake Bonneville marl provides a stratigraphic record of lake history preserved in its carbonate minerals and stable isotopes. We have analyzed the marl in shallow cores taken at three localities in the Bonneville basin. Chronology for the cores is provided by dated volcanic ashes, ostracode biostratigraphy, and a distinctive lithologic unit believed to have been deposited during and immediately after the Bonneville Flood.A core taken at Monument Point at the north shore of Great Salt Lake encompasses virtually the entire Bonneville lake cycle, including the 26.5 ka Thiokol basaltic ash at the base and deposits representing the overflowing stage at the Provo shoreline at the top of the core. Two cores from the Old River Bed area near the threshold between the Sevier basin and the Great Salt Lake basin (the main body of Lake Bonneville) represent deposition from the end of the Stansbury oscillation ( 20 ka) to post-Provo time ( 13 ka), and one core from near Sunstone Knoll in the Sevier basin provides a nearly complete record of the period when Lake Bonneville flooded the Sevier basin (20–13 ka).In all cores, percent calcium carbonate, the aragonite to calcite ratio, and percent sand were measured at approximately 2-cm intervals, and ¹⁸O and ¹³C were determined in one core from the Old River Bed area. The transgressive period from about 20 ka to 15 ka is represented in all cores, but the general trends and the details of the records are different, probably as a result of water chemistry and water balance differences between the main body and the Sevier basin because they were fed by different rivers and had different hypsometries. The Old River Bed marl sections are intermediate in position and composition between the Monument Point and Sunstone Knoll sections. Variations in marl composition at the Old River Bed, which are correlated with lake-level changes, were probably caused by changes in the relative proportions of water from the two basins, which were caused by shifts in water balance in the lake.This is the second paper in a series of papers published in this issue on Climatic and Tectonic Rhythms in Lake Deposits.     

铁砚磨穿指蘸墨 不用扬鞭自奋蹄——志《山西地震》创刊20周年

回顾了《山西地震》创刊20年的历史,叙述了《山西地震》.编辑部在自身建设、执行科技期刊编排标准、为防震减灾事业默默奉献的情况,总结了经验、教训,指出了今后努力的方向.     

Brønsted reactions on oxide mineral surfaces and the temperature-dependence of their dissolution rates

The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO ^–), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge.     

大别杂岩中混合岩的矿物空间分布研究

介绍了矿物空间分布研究的基本原理及两种统计方法(接触频数法和线切法)。作者对混合岩矿物空间分布的研究表明:(1)前人提出的统计方法存在方法上的缺陷和应用上的局限性,作者推导出矿物接触类型的概率公式;(2)部分浅色体中矿物显示聚集分布的特征,而绝大部分的浅色体中矿物具有分散分布的特点。结合质量平衡和地球化学研究认为:大别杂岩中主体混合岩成因机制是重熔和交代作用。     

杠杆点评估及设计空间抗差

本分析了杠杆点的几何含义和统计特征,从杠杆点的保差性,矩阵的摄动和参数估值可靠性的观点出发讨论了杠杆点的不利和有利的两个方面,提出了一个全面的设计空间抗差方案。