藏东纽多黑云母二长花岗岩锆石U-Pb年龄及成因

通过对澜沧江北段卡贡地区出露的纽多黑云母二长花岗岩的岩石学、岩石地球化学及锆石U-Pb年龄的研究,分析了纽多黑云母二长花岗岩的地球化学和原岩特征。黑云母二长花岗岩中的锆石具有明显的振荡环带,较高的Th/U值(普遍大于0.4),属于典型的岩浆成因锆石,用LA-ICP-MS测得锆石~(206)Pb/~(238)U年龄为243.6±1.4Ma(MSWD=1.00,n=15),时代为中三叠世。岩石地球化学特征表明,该黑云母二长花岗岩具有较高的SiO_2、Al_2O_3及高钾富碱的特征,A/CNK值为1.05~1.08,为过铝质高钾钙碱性系列;稀土元素配分模式显示,配分曲线为右倾型,具有明显的负Eu异常和弱负Ce异常,表现为Nb、Ta、P、Zr、Ti等高场强元素相对亏损,相对富集Rb、K、Th、U等大离子亲石元素。岩石地球化学特征表明,纽多黑云母二长花岗岩为S型花岗岩,形成于地壳加厚增温环境下的深熔作用。     

三江北段纳日贡玛黑云母花岗斑岩LA-ICP-MS锆石U-Pb定年及其地质意义

西南三江北段是青海省重要的斑岩型铜钼矿成矿带,纳日贡玛铜钼矿是近年来在三江北段发现的与侵入岩有关的斑岩型铜钼矿。利用锆石U-Pb方法测得纳日贡玛黑云花岗斑岩的形成年龄为41.53Ma ±0.24Ma,属于喜马拉雅早期。纳日贡玛斑岩型铜钼矿的成矿时代主要在40.86~40.80Ma之间。在多期热液叠加、多期成矿作用中,纳日贡玛斑岩型铜钼矿的热液应是纳日贡玛黑云花岗斑岩（41.53Ma ±0.24Ma）和纳日贡玛斜长花岗斑岩（41.00Ma ±0.18Ma）共同提供的。由于该区有较多的中酸性岩体存在,因而确定这些侵入体的形成年龄,对于在该区寻找同时代的斑岩型铜钼矿有重要的理论意义和现实意义。     

Halogen signatures of biotites from the Maher-Abad porphyry copper deposit,Iran: characterization of volatiles in syn- to post-magmatic hydrothermal fluids

Copper and gold mineralization in the Maher-Abad area, eastern Iran, is closely related to multiple episodes of emplacement of a late Eocene granodiorite into a quartz-monzonitic stock and andesitic volcaniclastic rocks. Hypogene and supergene porphyry Cu–Au mineralization occurred within the porphyritic granodiorite and quartz-monzonite host rocks extensively altered into dominantly potassic, propylitic, phyllic, and argillic assemblages. Temperature and pressure estimates using the plagioclase–hornblende thermometer and Al-in-hornblende barometer indicate that the granodiorite intruded at 758 ± 10°C and 1.4 ± 0.2 kbar.

Biotites from the alteration zones have more variable Al^IV than those in the fresh granodiorite, but nearly all are close to the ideal phlogopite composition. Biotite compositions display an increase in Al₂O₃, FeO, TiO₂, and Cl, but a decrease in SiO₂ and F, from the porphyritic granodiorite and potassic to the transitional phyllic alteration zones. Biotite from the potassic zone (X _phl?=?0.63–0.67) possesses a moderate F content (0.53 to 0.82 wt.%) that is significantly higher than that in the phyllic zone (0.22 to 0.38 wt.%), exhibiting a positive correlation with X _Mg and negative correlation with Cl.

With a decrease in the temperature, log (fH₂O/fHF) and log (fH₂O/fHCl) values calculated for fluids equilibrated with biotite increase progressively from the granodiorite through the potassic to the phyllic zones, whereas log (fHF/fHCl) shifts towards more negative values. Fugacity ratio trends in the Maher-Abad porphyry copper deposit are quite similar to those of other porphyry copper systems. The decrease in halogen content of hydrothermal fluids towards outer parts of the deposits reflects an increase in the degree of mixing between magmatic fluid and meteoric water.     

西藏米林县片麻状黑云花岗闪长岩地球化学特征、锆石U-Pb定年及Pb-Sr-Nd同位素组成

喜马拉雅是印度与欧亚板块俯冲碰撞作用形成的全球最年轻、规模最大和正在活跃的造山带。利用LA-ICP-MS锆石U-Pb测年技术对位于东喜马拉雅构造结侵入南迦巴瓦岩群的片麻状黑云花岗闪长岩进行了测年,获得岩浆结晶年龄为515.5±2.3 Ma(早寒武世),提供了泛非构造-岩浆事件在东喜马拉雅构造结的记录。岩石地球化学分析表明,SiO2含量为66.47%~72.42%,A/CNK指数为0.98~1.08,平均1.03,在A/NK-A/CNK指数图解中样品大部分落入过铝质区,里特曼指数σ为1.53~3.08,为钙碱性系列,在SiO2-K2O图解上大部分样品投入高钾钙碱性系列区,在Harker图解中所有样品中的TiO2、MgO、FeOT、MnO、K2O随着SiO2含量的变化增加而减少,Na2O随着SiO2含量的增加而增加,均呈较好的线性关系。稀土元素配分模式为轻稀土元素富集的右倾曲线,(La/Yb)N为19.1~63.8,出现弱Eu负异常(δEu=0.24~0.88);微量元素表现出Ba、Nb、Ta、Sr、Zr亏损,而大离子亲石元素Rb、Th和U相对富集的特征。Sr、Nd同位素组成表明,丹娘乡片麻状黑云花岗闪长岩具有负εNd(t)值(-8.67~-10.57)和较老的Nd模式年龄(tDM=1.84~3.42),说明其来源可能是上地壳物质,结合87Sr/86Sr初始比值特征,推断丹娘乡片麻状黑云花岗闪长岩是在高温环境下经部分熔融形成的。通过构造环境判别图及岩石地球化学研究认为丹娘乡准铝质-弱过铝质片麻状黑云花岗闪长岩形成于后碰撞造山环境,结合新得到的513 Ma同位素年龄,认为泛非碰撞造山事件早寒武世在东喜马拉雅构造结一带可能结束,进入后碰撞造山的构造演化阶段。     

内蒙古那仁乌拉埃达克质花岗岩的发现、成因、锆石U-Pb年龄及其构造意义

在中亚造山带东段华北克拉通北缘,识别出一套晚古生代那仁乌拉黑云母花岗岩。其LA-ICP-MS锆石U-Pb年龄为267.2Ma±1.4 Ma(MSWD=1.3,n=21)和捕获锆石年龄为296.3Ma～296.1Ma、278.8Ma～277.4 Ma;岩石为低钾(拉斑)到高钾钙碱性,弱准铝质到过铝质I型;ΣREE较低,轻重稀土分馏较强(LaN/YbN:15.59～32.36)。在稀土元素配分模式图上,都表现为轻稀土富集,重稀土亏损的右倾散开式。弱到正的铕负异常(δEu:0.79～1.08);在微量元素蛛网图上,相对富集LREE(La,Ce),LILE(K,Rb)和HFSE(Zr,Hf),元素Nb,Ta,P,Ti,Y,Yb,Lu亏损程度较大,元素U,Th,Sr由相对亏损到富集。岩石整体具有埃达克质岩的亲合性,形成于弧向同碰撞过渡的构造环境;锆石εHf(t)值(0.95～4.05)显示具有弱亏损的幔源组分特性,与主量元素、微量元素及REE一致,变化范围都较大,共同暗示其源岩的壳幔混源性。较年轻的锆石Hf模式年龄(1 030.9Ma～1 226.8Ma)与兴蒙造山带范围一致;那仁乌拉花岗岩与西部乌拉特中旗克布岩体,东部吉林大玉山岩体共同组成一条华北克拉通北缘埃达克质岩浆带,其都为与古亚洲洋俯冲碰撞引起的具有弧岩浆性质的年轻的基性玄武质下地壳部分熔融有关的C型埃达克岩。这条埃达克质岩浆带与稍晚期的华北克拉通北缘碱性岩浆带相对应,都具有西部形成早于东部的特征,可能暗示古亚洲洋自西向东逐渐闭合的规律。     

Early Palaeozoic biotite Rb‐Sr dates in the Yilgarn Craton near Harvey,Western Australia

Biotite from granite and gneiss in the southwestern part of the Yilgarn Craton near Perth has been dated by the Rb‐Sr technique at about 430–500 Ma in a belt at the western edge of the craton. The belt widens southward from 30 km near Perth to 55 km east of Harvey. The eastern boundary of the belt passes along the east margin of the Saddleback greenstone belt. A transition zone 15–40 km wide separates the belt of young dates from an eastern chronological plateau where biotite dates, mainly 2300–2600 Ma, are marginally younger than regional Rb‐Sr whole rock dates which average about 2550 Ma. In contrast to biotite dates, whole rock dates greater than 2500 Ma persist to the western edge of the craton. The 430–500 Ma dates probably represent resetting during uplift in the Early Palaeozoic.     

新疆阿尔泰成矿带可可塔勒花岗岩体锆石LA-ICP-MSU-Pb年龄及其地质意义

新疆阿尔泰成矿带花岗岩发育,其中很多花岗岩与成矿作用有着密切的联系,特别是400Ma左右的岩浆活动是阿尔泰地区一次重要的岩浆成矿活动,阿尔泰许多金属矿床与这一时期的岩浆构造作用有关。本次研究的出露于可可塔勒铅锌矿区的黑云母花岗岩体,其锆石LA-ICPMSU-Pb年龄为（401．8士1．5）Ma,表明可可塔勒花岗岩是阿尔泰成矿带400Ma左右发生的一次重要岩浆构造作用的产物,该黑云母花岗岩体侵入于矿区下泥盆统康布铁堡组火山岩地层中,岩体与围岩接触带附近的围岩蚀变明显,该黑云母花岗岩的侵入以及其后期的岩浆热液活动可能对区内成矿物质的活化、迁移、富集、成矿具有一定的贡献。     

Zircon U–Pb ages of plutonic rocks in the southern Abukuma Mountains: Implications for Cretaceous geotectonic evolution of the Abukuma Belt

Plutonic rocks in the southern Abukuma Mountains include gabbro and diorite, fine‐grained diorite, hornblende–biotite granodiorite (Ishikawa, Samegawa, main part of Miyamoto and Tabito, Kamikimita and Irishiken Plutons), biotite granodiorite (the main part of Hanawa Pluton and the Torisone Pluton), medium‐ to coarse‐grained biotite granodiorite and leucogranite, based on the lithologies and geological relations. Zircon U–Pb ages of gabbroic rocks are 112.4 ±1.0 Ma (hornblende gabbro, Miyamoto Pluton), 109.0 ±1.1 Ma (hornblende gabbro, the Hanawa Pluton), 102.7 ±0.8 Ma (gabbronorite, Tabito Pluton) and 101.0 ±0.6 Ma (fine‐grained diorite). As for the hornblende–biotite granodiorite, zircon U–Pb ages are 104.2 ±0.7 Ma (Ishikawa Pluton), 112.6 ±1.0 Ma (Tabito Pluton), 105.2 ±0.8 Ma (Kamikimita Pluton) and 105.3±0.8 Ma (Irishiken Pluton). Also for the medium‐ to fine‐grained biotite granodiorite, zircon U–Pb ages are 106.5±0.9 Ma (Miyamoto Pluton), 105.1 ±1.0 Ma (Hanawa Pluton) and the medium‐ to coarse‐grained biotite granodiorite has zircon U–Pb age of 104.5 ±0.8 Ma. In the case of the leucogranite, U–Pb age of zircon is 100.6 ±0.9 Ma. These data indicate that the intrusion ages of gabbroic rocks and surrounding granitic rocks ranges from 113 to 101 Ma. Furthermore, K–Ar ages of biotite and or hornblende in the same rock samples were dated. Accordingly, it is clear that these rocks cooled down rapidly to 300 °C (Ar blocking temperature of biotite for K–Ar system) after their intrusion. These chronological data suggest that the Abukuma plutonic rocks in the southern Abukuma Mountains region uplifted rapidly around 107 to 100 Ma after their intrusion.     

张广才岭东侧英城子金矿区早古生代花岗岩锆石U-Pb年龄及地质意义

本文首次对佳木斯地块西缘、张广才岭东侧英城子金矿区出露的大面积黑云母碱长花岗岩,进行了锆石LA-ICP MS U-Pb年代学精细研究。实验共获得四组单颗粒锆石U-Pb谐和年龄,它们分别为612±4Ma、495.2±2.7Ma、476.8±5.5Ma和431±3Ma;其中612±4Ma具有指示晚元古代增生地壳过程形成的花岗岩锆石特征,495.2±2.7Ma的U-Pb年龄与区域内麻山群的变质作用时间相吻合,431±3Ma的年龄与早古生代晚期的区域变质作用时间吻合,而476.8±5.5Ma的锆石年龄则代表黑云母碱长花岗岩的真实结晶年龄。这项成果记录了该地区在中一新元古代时期曾发生过重要的地壳增生事件,增生后的地壳被打开形成大洋;至早古生代早期,两侧的地体发生拼贴,引起区域麻山群发生麻粒岩相的变质作用、形成花岗质片麻岩;在早古生代晚期,佳木斯地块西缘的陆间洋最终闭合,形成具有壳源特征同碰撞花岗岩,之后的韧性变形作用可能为金矿床的形成提供了有利条件。     

新疆拜城县波孜果尔碱性花岗岩体中角闪石与黑云母地球化学特征及其对成岩成矿的记录

角闪石和黑云母是含稀有稀土金属矿物的高分异碱性花岗岩中常见的暗色矿物。角闪石和黑云母对不同元素(尤其是Nb、Ta、Zr、REE等稀有稀土金属元素)的相容性特点使它们的主微量元素特征成为岩浆演化的"日志",对构建含矿岩浆的成岩成矿模型具有一定意义。本文针对新疆拜城波孜果尔碱性花岗岩体中的角闪石和黑云母,利用电子探针(EPMA)和激光剥蚀电感耦合等离子体质谱仪(LA-ICP-MS)等分析技术,开展精细的矿物学研究,综合厘定Nb、Ta等元素在岩浆结晶过程中的富集和分配过程。波孜果尔岩体中的角闪石均为亚铁钠闪石,总体表现为较高的Na和Fe含量,而相对贫Ca(0.15 apfu)、Mg(0.06 apfu)和Ti(0.07 apfu),成分的均一性以及轻稀土元素的亏损特征暗示了角闪石较晚结晶且角闪石结晶前大量富轻稀土元素矿物结晶分离。根据共生关系黑云母可分为A、B两类,它们显示出不同的化学成分。A类黑云母具有相对较高的F含量(A类为3.81%～4.82%,B类为1.68%～3.65%)和SiO_2含量(A类为41.5%～43.3%,B类为35.9%～38.5%),相对较低的TFeO含量(A类为28.0%～31.4%,B类为32.2%～35.7%)和Al_2O_3含量(A类为6.45%～7.62%,B类为9.70%～11.00%)。黑云母与角闪石中氟的含量变化指示了氟在结晶过程中的富集、饱和过程以及氟饱和引起的稀有稀土金属矿物大量结晶现象。由于在主要矿物中的不相容性,成矿元素Nb、Ta在熔体中含量逐渐上升,但主要矿物及大部分副矿物中均高于全岩的Nb/Ta值产生了"Ta丢失"现象。结合前人研究,本文认为气热相带出与锆石的结晶分离两种机制共同作用导致Ta从熔体中分离。