湖南宝山矿床花岗岩类硫-铅同位素和流体包裹体研究及其成因意义

宝山铜铅锌多金属矿床是湖南重要的铅锌生产基地。矿床内矽卡岩型铜(钼)矿化受侏罗纪花岗闪长斑岩的控制,而主要的铅锌矿体则产于远离岩体的碳酸盐地层中,且缺乏可靠的矿化年龄限制。为了查明宝山铅锌矿体与花岗闪长斑岩之间的成因关系,文章对宝山花岗岩类中浸染状黄铁矿的硫同位素和钾长石的铅同位素,以及铅锌矿石萤石脉石的流体包裹体进行了测试和研究,并与前人报道的铅锌硫化物矿石的硫、铅同位素进行了对比,尝试为宝山铅锌矿化的物质来源及成因提供依据。研究表明,花岗闪长斑岩中浸染状黄铁矿的δ34S值为+1.5‰~+3.5‰,与铅锌矿石硫化物(方铅矿、闪锌矿及黄铁矿)相一致;同时,花岗岩类中钾长石的铅同位素组成206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别为18.4789~18.7668、15.6835~15.7220和38.7903~39.1035,具有壳源的特征,且与铅锌矿石硫化物的铅同位素分布范围相吻合。宝山矿床的硫、铅同位素特征表明,花岗闪长斑岩应是铅锌矿化的主要硫源及金属来源。宝山矿床铅锌矿石萤石中的流体包裹体具有低温(130~150℃)、低盐度(8%)的特征,可能是岩浆热液演化到晚期的产物。结合已有的有关资料加以对比和分析,研究认为,宝山铅锌矿床的成矿物质应来源于花岗闪长岩的岩浆期后热液,在热液演化晚期迁移到远端地层中沉淀,形成了宝山的主要铅锌矿体。     

浙江省绍兴市平水金矿体流体包裹体研究 与矿床成因

浙江平水铜矿位于钦杭成矿带北东段浙西北地区,是浙江省最大的铜矿床,前人研究表明其为典型的火山成因块状硫化物矿床（Chen 等, 2015）。平水铜矿体在新元古代形成之后,该地区经历了加里东的变质变形作用,在铜矿体的下盘普遍发育千糜岩带（韧性剪切带）,本项目组在研究过程中认为千糜岩带与铜矿无关,但明确提出本区可能存在造山型金矿,继而老矿山接替资源勘查在平水铜矿布置了10个坑内钻孔,其中9个见矿,成功的在平水深部发现两层金矿体和一层铜矿体。金矿体严格的受韧性剪切带的控制;金矿石有明显的宏观和微观韧性变形结构;矿石矿物主要是自然金和少量的黄铁矿,脉石矿物主要有石英、绢云母、绿泥石、碳酸盐和白云石。本文主要对平水金矿体开展流体包裹体研究,结合矿床地质特征,最终确定金矿体成因类型,为平水地区下一轮深边部找矿勘查提供依据。     

江苏栖霞山矿床铜的来源探讨

江苏栖霞山铅锌银多金属矿床是目前华东地区规模最大的铅锌银多金属矿床,位于长江下游沿江断褶带的宁镇断褶束西端,走向长约8 km,面积约25 km2。矿区自西向东包括西库、甘家巷、北象山、虎爪山、平山头、三茅宫等六个矿段,目前正处于开采阶段的为虎爪山矿段。矿体主要沿纵向断裂带（F2）、不整合面、北西向横断裂、层间错动和层间裂隙、古岩溶构造等呈似层状和不规则状（囊状、脉状和层状）分布。赋矿地层为上泥盆统至下二叠统,其中石炭系黄龙组（C2h）碳酸盐岩地层为最主要的赋矿层位。其矿石矿物主要为方铅矿、闪锌矿和黄铁矿,次为菱锰矿、黄铜矿、磁铁矿等。自实施危机矿山接替资源找矿和老矿山找矿工作以来,矿山找矿效果明显,新增资源量达到中型以上规模,除主攻矿种铅锌矿以外,新发现矿体伴生的有益组分Au、Ag和Cu含量较高,伴生Cu金属量达到1.53万吨,且向深部有明显升高的趋势。在找矿勘查布设的42勘探线和46勘探线可独立圈出1层Au矿体、2层Cu-Ag矿体、3层Ag矿体和1层Cu矿体,Au品位普遍在0.2 g以上,Ag品位多大于10 g/t,Cu品位多大于0.2%。因此,矿区深部具有寻找铜、金、银的前景。本文通过搜集前人研究的基础资料和矿区钻孔取样分析数据,对铜的来源作初步的分析,试图厘清栖霞山矿床铜的物质来源,对于指导深部Cu等伴生有益组分的进一步找矿提供一些科学的依据。     

The Relationship between Jurassic Coal Measures and Sandstone-type Uranium Deposits in the Northeastern Ordos Basin, China

Outcrop and drill hole data show that the Jurassic coal measures in the northeastern Ordos Basin are composed mainly of the Yan'an Formation and the lowstand system tract of the Zhiluo Formation,and there is a regional unconformity between them. The Dongsheng uranium deposit is associated with the Jurassic coal measures. Research data indicate that the Jurassic coal measures in the study area have a certain hydrocarbon-generating capacity,although the metamorphic grade is low(Ro=0.40%–0.58%). In the Dongsheng region alone,the accumulative amount of generated coalbed methane(CBM) is about 2028.29 × 108 –2218.72 × 108 m~3; the residual amount is about 50.92 × 108 m~3,and the lost amount is about 1977 × 108 m~3. Analysis of the burial history of the host rocks and the evolutionary history of the Dongsheng uranium deposit suggests that the Jurassic coal measures generated hydrocarbon mainly from Middle Jurassic to Early Crataceous,which is the main mineralization phase of the Dongsheng uranium deposit. By the Late Cretaceous,a mass of CBM dissipated due to the strong tectonic uplift,and the Dongsheng uranium deposit stepped into the preservation phase. Therefore,the low-mature hydrocarbon-containing fluid in the Jurassic coal measures not only served as a reducing agent for the formation of sandstone-type uranium deposits,but also rendered the second reduction of paleo-interlayer oxidation zone and become the primary reducing agent for ore conservation. Regional strata correlation reveals that the sandstone-type uranium reservoir at the bottom of the Zhiluo Formation is in contact with the underlying industrial coal seams in the Yan'an Formation through incision or in the form of an unconformity surface. In the Dongsheng region with poorly developed fault systems,the unconformity surface and scour surface served as the main migration pathways for low-mature hydrocarbon-containing fluid migrating to the uranium reservoir.     

鄂尔多斯盆地北部砂岩型铀矿铀矿物地质地球化学特征及其成因意义

鄂尔多斯盆地北部已发现系列砂岩型铀矿,由东往西依次有东胜铀矿、杭锦旗(纳岭沟)铀矿、大营铀矿等大型、特大型矿床,成为我国目前砂岩型铀矿发现规模最大、最具远景的地区。研究表明,它们具有相似的矿床地质特征和形成环境。在矿床成矿作用研究中,铀的存在形式及铀矿物特征对砂岩铀矿来说是一项重要的内容,其认识对铀的地浸开采可提供重要依据,也是了解砂岩型铀矿形成机制或矿床形成环境及成因的重要信息。本文主要从三个方面对鄂尔多斯盆地北部大营铀矿、纳岭沟铀矿等主要砂岩型铀矿中铀矿物地质地球化学特征和成因进行了研究和探讨。通过电子探针测试,高分辨率扫描电镜观察等手段,认为盆地北部铀矿的铀矿物类型主要为铀石,含少量的沥青铀矿、钛铀矿、水硅铀石、钍铀石等;铀矿物常与黄铁矿、有机质(煤屑)及方解石相伴生。采用逐级化学提取等方法定量地分析了铀矿物占矿石中铀配分的比例关系,认为其中铀矿物和吸附态约各占铀存在形式的50%。首次对砂岩型铀矿的铀矿物进行微区原位LA-ICP-MS稀土元素分析,认为ΣREE在铀矿物铀石中高度富集,是矿石中稀土元素的主要载体;稀土元素是铀矿石中可综合利用的有益组份,其标准化曲线表现为明显的右倾型,轻稀土富集,轻重稀土分馏强烈,δEu和δCe具较弱的负异常,说明总体上铀矿化形成于外生后成环境。从上述铀矿物特征,初步探讨了铀矿化形成的环境与成因,认为铀矿化形成经历了至少为低温流体作用的环境;铀矿化形成于浅部地壳即外生后成环境而与深源作用无关。     

内蒙古准苏吉花斑岩型钼矿及外围反射地震探测

内蒙古准苏吉花斑岩型钼矿床是一个中型金属矿床,目前勘查区内还没有较深的钻孔资料。为探测深部隐伏金属矿和控矿构造及深部地质结构,在内蒙古准苏吉花钼矿区及其外围开展了高精度反射地震测量。该反射地震采用2台套大功率可控震源激发,5 m道间距,960道接收,80次覆盖的工作方法,获得了能清晰反映深部地质结构和构造的高精度反射地震剖面。在该剖面上,能够清楚地解释测区导矿和控矿构造及隐伏岩体分布及燕山期与华力西期岩体的交切关系,并据此讨论了地壳深部流体运移的路径和动力过程,为在该区寻找深部隐伏金属矿指明了新的找矿靶区。     

桩端后注浆对大直径灌注桩影响的现场对比试验研究

基于郑州三环快速路工程开展的6个场地19根大直径灌注桩现场足尺试验,通过对比分析后注浆桩与未注浆桩实测结果,研究桩端后注浆对大直径灌注桩承载变形性状、荷载传递规律、桩端承载特性及桩侧摩阻力发挥性状的影响。结果表明,桩端后注浆条件下大直径灌注桩承载变形性能明显提高,且提高幅度受注浆龄期影响较为显著;在黄河中下游以中密～密实粉土、粉细砂及可塑～硬塑粉质黏土为主要冲积地层中桩长40 m左右的大直径灌注桩表现为摩擦型桩,但相比于未注浆桩,桩端后注浆桩传递至桩身下部及桩端的荷载更小;桩端后注浆在桩端下形成水泥沉渣坚硬固结体,有效地处理了桩端沉渣问题,且通过渗透劈裂作用,形成深度可达1 m的网状分布的水泥胶结体,加之对桩端土层的压密效应,显著提高了桩端支承性能与承载刚度;桩端后注浆显著提高大直径灌注桩桩侧极限摩阻力发挥水平,并降低了桩侧极限摩阻力对应的桩土相对位移,使得大直径灌注桩在较小的沉降下表现出较高的承载能力。     

豫陕交界地区钾长石矿产地质特征及开发前景

本文研究证明区内有南、北两条钾长石成矿带,其产出形态、矿化特征、矿石类型均有差异,且导致了它们在工业应用上的不同。区内矿体以岩脉或岩株产出,有红色、浅红色、白色3种矿石。白色矿石富钾低铁,达到国标一级品,其余矿石为二级以下品级,均具有一定的销售市场。从全国的供需形势分析,今后钾长石矿产品市场前景广阔,而区内钾长石资源进一步找矿的潜力仍然很大。     

镇旬矿田泥盆系和志留系铅锌矿的成矿地质条件分析

对镇（安）旬（阳）矿田泥盆系、志留系铅锌矿的成矿地质条件分析表明，本区泥盆系、志留系铅锌矿总体属层控矿床类型。铅锌矿赋存于下志留统悔子垭组、中志留统双河镇组及中泥盆统大枫沟组、上泥盆统南羊山组；控矿构造为断裂、褶皱，容矿构造为顺层断裂带、剪切带，含矿岩石为含碳砂岩、千枚岩及灰岩、生物灰岩、白云岩；沉积环境为浅水陆棚相、台地边缘及泻湖、潮坪、台地浅海。以旬阳泗人沟为代表的志留系铅锌矿属细碎屑岩沉积强改造型铅锌矿床；以旬阳大岭、赵家庄为代表的泥盆系铅锌矿属碳酸盐岩沉积弱改造型铅锌矿床；以镇安锡铜沟、月西为代表的泥盆系铅锌矿属碳酸盐岩沉积强改造型铅锌矿床。     

Hydrothermal Fluid Sources of the Fengjia Barite–fluorite Deposit in Southeast Sichuan,China: Evidence from Fluid Inclusions and Hydrogen and Oxygen Isotopes

The Fengjia barite–fluorite deposit in southeast Sichuan is a stratabound ore deposit which occurs mainly in Lower Ordovician carbonate rocks. Here we present results from fluid inclusion and oxygen and hydrogen isotope studies to determine the nature and origin of the hydrothermal fluids that generated the deposit. The temperature of the ore‐forming fluid shows a range of 86 to 302 °C. Our detailed microthermometric data show that the temperature during mineralization of the fluorite and barite in the early ore‐forming stage was higher than that during the formation of the calcite in the late ore‐forming stage. The salinity varied substantially from 0.18% to 21.19% NaCl eqv., whereas the density was around 1.00 g/cm³. The fluid composition was mainly H₂O (>91.33%), followed by CO₂, CH₄ and traces of C₂H₆, CO, Ar, and H₂S. The dominant cation was Na⁺ and the dominant anion Cl^‐, followed by Ca²⁺, SO₄^2‐, K⁺, and Mg²⁺, indicating a mid–low‐temperature, mid‐low‐salinity, low‐density NaCl–H₂O system. Our results demonstrate that the temperature decreased during the ore‐forming process and the fluid system changed from a closed reducing environment to an open oxidizing environment. The hydrogen and oxygen isotope data demonstrate that the hydrothermal fluids in the study area had multiple sources, primarily formation water, as well as meteoric water and metamorphic water. Combined with the geological setting and mineralization features we infer that the stratabound barite–fluorite deposits originated from mid–low‐temperature hydrothermal fluids and formed vein filling in the fault zone.