鄂尔多斯盆地东部深部煤层气井压裂工艺及实践

鄂尔多斯盆地东部深部煤层气（埋深大于1 200 m）资源丰富,是下步煤层气勘探、开发的重点。与浅部煤层压裂相比,深部煤层压裂存在诸多挑战（地应力、闭合应力、破裂压力高,岩石力学参数复杂等）。通过对比现有煤层压裂工艺,以鄂尔多斯盆地东部深部煤层（埋深约2 000 m）为例,探索了采用油管+循环滑套+封隔器+喇叭口施工管柱和低浓度线性胶压裂液体系对深部煤层进行压裂作业,施工比较顺利,见气快,产气效果比较理想（产气量大于800 m³/d）。通过2口井的现场作业实践,证明了该工艺技术简单、易行、有效,为后续深部煤层气的勘探开发提供可借鉴的工艺技术。     

兰坪盆地三类主要铜银多金属矿床的稳定同位素地球化学

通过对兰坪盆地内三种主要成因类型（沉积-热液改造型、热水沉积-热液改造型和热液脉型）的铜银多金属矿床硫、碳、氢、氧同位素的研究,揭示了成矿作用过程的某些重要信息：矿石中的硫主要来自细菌还原的海水硫酸盐,但在沉积-热液改造型矿床中可能还有部分有机生物硫和深源火山硫的贡献;碳主要来自不同比值水/岩反应体系中碳酸盐岩地层的溶解结果,但在沉积-热液改造型矿床中还可能有深部地幔去气作用带来的CO2.成矿流体系以大气降水为主要补给源的盆地建造水,盆地建造水的运移成矿过程中可能伴有较为明显的蒸发作用.     

康滇地轴南段江川盆地澄江砂岩微量元素地球化学特征及其地质意义

主要阐述了江川盆地澄江砂岩（Zac）的紫色砂岩与灰色砂岩、铀矿化蚀变岩微量元素及稀土元素地球化学特征。通过判别与对比,澄江砂岩（Zac）物质来源于活动大陆边缘,虽然铀矿化主要分布在灰色砂岩中,但灰色砂岩并不是控制铀矿化的主要因素,在铀矿化时有深部流体物质的影响。微量元素地球化学特征对探索该区砂岩型铀矿化以及寻找不整合面型铀矿床提供了可能,具有重要的指示意义。     

Northern Adriatic phytoplankton response to short Po River discharge pulses during summer stratified conditions

A 275‐km‐long transversel Northern Adriatic profile from the mouth of the Po River (Italian Adriatic coast) to the Kvarner region (Croatian coastal island area) was investigated in three successive case studies in August 2008, 2009 and 2010. The short Po River pulses in August result in the surface advection of riverine water, nutrients and phytoplankton from the western to the eastern side of the Adriatic. This surface spreading exhibits inter‐annual variability depending on the riverine discharge in the preceding period. The Po River discharge pulse in August 2010 in particular resulted in an extraordinary tongue‐like advection of riverine water, nutrients, and phytoplankton towards the Eastern Adriatic coast. The phenomenon was detected using both satellite imagery and classical oceanographic measurements. In the advective water, toxic dinoflagellates were most abundant in August 2010, when the influence of the Po was greatest.     

3D architecture of Quaternary sediment along the NW Atlantic Moroccan Rharb continental shelf: A stratal pattern under the dual control of tectonics and climatic variations

This study focuses on the evolution of the Atlantic NW Moroccan Rharb continental shelf during the Neogene and Quaternary. This region is part of a foreland basin bounded by the Rif mountain belt and thus provides an interesting geological setting to study the interactions between eustasy and tectonics and the driving mechanisms controlling stratigraphic patterns. The results are supported by an interpretation of new data including high-resolution seismic lines coupled with an interpretation of industrial seismic lines and detailed logs of industrial wells completed by micropaleontologic analysis of cuttings. The stratigraphy reveals a succession of three mega sequences related to the transition from an underfilled to an overfilled stage reflecting the long-term evolution of the foreland system. Moreover, evidence of cyclical sea-level changes are visible in the upper megasequence composed of three depositional sequences assumed to be fourth-order sequences generated in response to the most recent 100-ka glacio–eustatic cycles. This study also shows the peripheral deformation of the Rharb shelf responsible for changes in the geometry of the deposits and thicknesses of the sedimentary fill during the Pliocene and Pleistocene. The most important change was triggered by the uplift of the Lallah Zahra Ridge corresponding to a major Quaternary kinematic boundary and the broad uplift of the southern shelf interpreted as a flexural uplift of the forebulge domain. The deformation-controlled sediment dispersal pattern consists of a progressive growth of the shelf accompanied with a progressive shift of depocenters from the North East to the South West and a general progradation to the North West along the southern border. This progressive filling has led to the confinement of the Rharb paleo-valley across the continental shelf. The complete filling of the palaeo-valley was followed by the development of a more than 70-m thick prodeltaic lobe at the front of the Oued Sebou river mouth during the Holocene.     

Lacustrine basin unconventional resource plays: Key differences

There has been a revival in hydrocarbon source rock characterization and development associated with growing interest in unconventional resources, where these fine-grained organic-rich rocks act as both source and reservoir. To-date, the exploration focus on shale reservoirs has been largely on marine systems. Lacustrine source rocks for conventional resources are geographically important, dominating regions such as China, Indonesia, and Brazil's resource-base. However, they have been generally untested for unconventional resources.There are a number of key differences in the nature of these hydrocarbon systems that should be considered when assessing whether lacustrine systems may represent future unconventional opportunities in areas where the conventional resource-base is dominated by lacustrine-sourced oil. Among the key differences between these depositional systems is the greater sensitivity to high frequency climatic variability within lacustrine systems. Lacustrine systems are highly sensitive to changes in the balance between precipitation and evaporation, which may lead to rapid changes in lake level, potentially exceeding 600 m. These changes in depositional conditions are geologically rapid and may occur over periods of thousands of years. Such changes can reduce the areal extent of potentially thick source rock intervals to only those portions of a basin where a permanent deep lake was present. Thus the core unconventional target area may be geographically limited compared with their marine counterpart. Although potentially areally limited, a review of many lacustrine source rocks suggests that their thicknesses are often significantly greater than marine source rocks. An examination of the more distal portions of lacustrine systems, where better source rock potential is present reveals that there is generally limited connectivity between source and conventional reservoir. In these settings, such as the Wind River basin (Waltman Shale), the hydrocarbons remain trapped within the shales, potentially leading to over-pressured hydrocarbon charged systems. Such conditions suggest that although areally limited, viable unconventional targets may exist, if suitable reservoir conditions are present. Finally, the character of the oils produced is different in these settings, with lacustrine oils being waxy and displaying different hydrocarbon generation and cracking kinetics. High wax oils display distinct flow characteristics, being more viscous, and may offer different production challenges than their non-waxy marine equivalents. Additionally, differences in their cracking kinetics may indicate that the timing of gas generation for shale gas plays may differ significantly from marine systems.     

Organic geochemistry of marine source rocks and pyrobitumen-containing reservoir rocks of the Sichuan Basin and neighbouring areas,SW China

Three bitumen fractions were obtained and systematically analysed for the terpane and sterane composition from 30 Paleozoic source rocks and 64 bitumen-containing reservoir rocks within the Upper Sinian, Lower Cambrian, Lower Silurian, Middle Carboniferous, Upper Permian and Lower Triassic strata in the Sichuan Basin and neighbouring areas, China. These bitumen fractions include extractable oils (bitumen I), oil-bearing fluid inclusions and/or closely associated components with the kerogen or pyrobitumen/mineral matrix, released during kerogen or pyrobitumen isolation and demineralization (bitumen II), and bound compounds within the kerogen or pyrobitumen released by confined pyrolysis (bitumen III). In addition, atomic H/C and O/C ratios and carbon isotopic compositions of kerogen and pyrobitumen from some of the samples were measured. Geochemical results and geological information suggest that: (1) in the Central Sichuan Basin, hydrocarbon gases in reservoirs within the fourth section of the Upper Sinian Dengying Formation were derived from both the Lower Cambrian and Upper Sinian source rocks; and (2) in the Eastern Sichuan Basin, hydrocarbon gases in Middle Carboniferous Huanglong Formation reservoirs were mainly derived from Lower Silurian source rocks, while those in Upper Permian and Lower Triassic reservoirs were mainly derived from both Upper Permian and Lower Silurian marine source rocks. For both the source and reservoir rocks, bitumen III fractions generally show relatively lower maturity near the peak oil generation stage, while the other two bitumen fractions show very high maturities based on terpane and sterane distributions. Tricyclic terpanes evolved from the distribution pattern C₂₀ < C₂₁ < C₂₃, through C₂₀ < C₂₁ > C₂₃, finally to C₂₀ > C₂₁ > C₂₃ during severe thermal stress. The concentration of C₃₀ diahopane in bitumen III (the bound components released from confined pyrolysis) is substantially lower than in the other two bitumen fractions for four terrigenous Upper Permian source rocks, demonstrating that this compound originated from free hopanoid precursors, rather than hopanoids bound to the kerogen.     

Evaluating the mechanical compaction of quartzarenites: The importance of sorting (Llanos foreland basin,Colombia)

Mechanical compaction is the main porosity-reducing process in sandstones, including high-reservoir-quality rigid-grain sandstones. For such sandstones, the extrapolation of theoretical or experimental compaction algorithms needs calibration with rocks having well constrained burial histories. Evaluating the compaction of these rocks is achieved by comparing current intergranular volume (IGV) with depositional IGV, which is strongly dependent on sorting. However, because sandstone sorting is difficult to measure accurately, its impact on depositional porosity and compaction state is largely underestimated. We use the quartzarenites of the Oligocene Carbonera Formation in the subsurface of the hydrostatically-pressured Llanos basin to illustrate the importance of sorting when evaluating the compaction of rigid-grain sandstones. IGV and sorting were measured in core samples using a combination of transmitted-light and cathodoluminescence images, resulting in improved accuracy over standard procedures. The compaction state of clean quartzarenites at given depths is best described using IGV-versus-sorting plots, which are used to derive compaction curves for specified sorting values. The IGV-versus-sorting trends are displaced to lower IGV values with increasing burial depth. The differences in IGV caused by differences in sorting exceed the differences in IGV resulting from 1000 m of burial, illustrating the high impact of sorting when evaluating compaction. Contrasting with published experimental results, the compaction of the Llanos basin ductile-grain-poor quartzarenites is independent of grain size, and grain rearrangement is the main compaction mechanism during the first ∼1.6 km of burial. Based on the Llanos data, we have generated IGV-versus-depth curves for clean pure quartzarenites of specific sorting, which can be used to predict their maximum primary porosity up to moderate burial depths. Differences with other published burial curves are probably related to unaccounted variations in sorting, ductile-grain content and framework-strengthening cements. However, the Llanos basin quartzarenites contain virtually no cements, explaining their high degree of compaction relative to other rigid-grain sandstones, and making them ideal to isolate the effects of compaction on the IGV of quartzarenites. The Llanos basin data suggest that, below ∼2.5 km of depth, clean well- to moderately well sorted quartzarenites continue reducing their IGV by mechanical compaction below the 26% limit, which should apply only to extremely well sorted, rigid grain, uncemented sandstones.     

Molecular and isotopic compositions of bitumens in Silurian tar sands from the Tarim Basin,NW China: Characterizing biodegradation and hydrocarbon charging in an old composite basin

Biodegradation and oil mixing in Silurian sandstone reservoirs of the Tarim Basin, one of the largest composite basins in China, were investigated by analyzing the molecular characteristics and stable carbon isotopic signatures of low-molecular-weight (LMW) saturated hydrocarbons and high-molecular-weight (HMW) asphaltenes. Detection of 25-norhopanes and 17-nortricyclic terpanes in most Silurian tar sands from the Tabei Uplift in the Tarim Basin suggests a much greater degree of biodegradation here than in the Tazhong Uplift. This explains the relatively more abundant tricyclic terpanes, gammacerane, pregnane and diasteranes in tar sands from the Tabei Uplift than in those from the Tazhong Uplift. Hence, care must be taken when assigning oil source correlations using biomarkers in tar sands because of the biodegradation and mixing of oils derived from multiple sources in such an old composite basin. Asphaltenes in the tar sands seem to be part of the oil charge before biodegradation, depending on the relative anti-biodegradation characteristics of asphaltenes, the similarity in carbon isotopic signatures for asphaltenes and their pyrolysates, and the consistent product distribution for flash pyrolysis and for regular steranes in asphaltene pyrolysates, regardless of whether the tar sands were charged with fresh oil. According to the relative distributions of regular steranes and the relatively abundant 1,2,3,4-tetramethylbenzene significantly enriched in ¹³C, the oil sources for asphaltenes in the tar sands might be related to lower Paleozoic marine source rocks formed in euxinic conditions. Nevertheless, the relatively low abundance of gammacerane and C₂₈ regular steranes observed in asphaltene pyrolysates and residual hydrocarbons, within limited samples investigated in this work, made a direct correlation of oils originally charged into Silurian tar sands with those Cambrian source rocks, reported so far, seem not to be possible. Comparison of carbon isotopic signatures of n-alkanes in asphaltene pyrolysates with those of LMW saturated hydrocarbons is helpful in determining if the abundant n-alkanes in tar sands are derived from fresh oil charges after biodegradation. The limited carbon isotopic data for n-alkanes in LMW saturated hydrocarbons from the tar sands can be used to classify oils charged after biodegradation in the composite basin into four distinct groups.     

A control-volume finite-element method for three-dimensional multiphase basin modeling

In this paper we describe a 3D control-volume finite-element method to solve numerically the coupled partial differential equations (PDEs) governing geological processes involved in the evolution of sedimentary basins. These processes include sediment deposition and deformation, hydrocarbon generation, multiphase fluid flow, and heat transfer in deforming porous media.