对我国西南地区河谷深厚覆盖层成因机理的新认识

近年来,在我国水能资源开发过程中,发现各河流现代河床以下普遍堆积厚达数十米甚至上百米的松散堆积物。河谷深厚覆盖层的存在,不仅严重制约了工程坝址的选择,影响相关流域水电资源的开发利用,也给坝工设计带来巨大的困难。由于深厚覆盖层埋藏于现代河床之下,其形成年代一般先于一二级阶地,有悖于河流发育演化的常理,其成因一直令人费解。首次将河谷深切和深厚堆积事件与全球气候变化、海平面升降运动、地壳运动等有机地联系起来,并提出冰期、间冰期全球海平面大幅度升降,是导致河流深切成谷并形成深厚堆积的主要原因的新观点。在此基础上,引入层序地层学原理,从理论上较好地解释了全球气候变化导致海平面和河流侵蚀基准面大幅变化,并产生河谷深切和深厚堆积的原因和过程。最后,进一步将沿河大型古滑坡的孕育和发生与河谷深切事件相联系,提出沿河大型古滑坡是在河谷深切期因前缘临空较好而形成的新观点,从而对沿河古滑坡前缘剪出口高程往往低于现代河床数十米的原因给出了较合理的解释。     

基于小波变换的单频GPS快速精密定位整周模糊度的解算

对于GPS短基线,载波相位双差观测量已基本消除了卫星轨道误差、钟差、大气折射误差等系统偏差的影响,主要包含距离观测量信息及随机测量误差,其中测量误差是高频的测量噪声,小波变换可将GPS载波相位双差观测量中的观测噪声(高频部分)分解出来。本文利用Coiflets小波基函数对GPS快速定位的原始载波相位双差观测量进行5层分解,通过重构第5层低频系数获得去除噪声的"干净"的载波相位双差观测量,然后利用"干净"的双差观测量进行最小二乘参数估计,以减小测量噪声对GPS快速定位病态方程解的扰动。计算结果表明该方法能够显著提高GPS快速定位中模糊度浮点解的精度,仅利用几个观测历元的数据就可以准确地固定模糊度。     

高放废物处置库天然类比及其有关的地球化学问题

介绍了高放废物处置库天然类比研究的主要内容,重点阐述了类比研究中涉及的地球化学问题,包括核素溶解度和化学形态研究、核素迁移速率研究、核素迁移影响因素研究,并总结相关问题研究取得的成果和认识.     

城区水文循环机制与改善策略分析

在城区化过程中,由于人口快速成长且集中,随之而来的建筑物、道路等不透水面密度增加,导致地下水补给减少及破坏水文循环。为了解土地利用方式改变对长期水文量影响,建立一个适宜的城区水循环模式是非常重要的。选定台湾台北的六馆抽水站集水区进行分析,模式参数经过敏感度分析、率定与验证。采用改变不同透水铺面设置比例的方案,评估其对径流量、入渗量、蒸发散量的改变。并分析设置不同比例屋顶雨水贮集系统对地表径流量及供水量的改变。所建立的城区水循环模式是评估土地利用改变造成水文量的改变的一个有效工具,并可提供决策者做为城区土地利用决策的参考。     

优化配置模型在莱州市水资源规划中的应用

介绍了水资源优化配置模型的原理,并通过模型在莱州水资源规划中的实例分析,得到了莱州现状及不同规划水平年的水量优化供需计算结果,对莱州市水资源规划提供了依据,体现了计算机模拟优化模型的优越性。     

GM（1，1）动态模型在吴江市地下水水位预测中的应用

以吴江市地下水水位预测为例,详细阐述了地下水水位时间序列的GM（1,1）动态模型的原理和建立过程,并根据模型的预测值和实测值,对模型的精度进行了检验,结果表明,模型的预测精度达到了99．27％,等级属于Ⅰ级,具有实际的应用价值,为地下水资源的科学管理提供了依据。     

GALILEO系统局域完备性监测设计与实现

根据GALILEO系统局域完备性概念和网络RTK的基本理论,建立导航系统局域网络完备性监测理论和算法。算法主要包括网络系统完备性算法和用户完备性算法,内容包括网络误差模型的建立、插值算法的选择、误差改正数完备性指标的计算、完备性指标的验证和用户保护水平的计算等。仿真结果表明,采用网络RTK技术和完备性监测算法,飞机的平面保护水平和垂直保护水平均小于完备性告警门限值,可以满足飞机Ⅱ类和Ⅲ类精密进近的完备性要求,为卫星导航系统在民航中的应用提供完备性理论基础。     

Evolution of cool skin and direct air-sea gas transfer coefficient during daytime

Absorption of solar radiation within the thermal molecular sublayer of the ocean can modify the temperature difference across the cool skin as well as the air-sea gas transfer. Our model of renewal type is based on the assumption that the thermal and diffusive molecular sublayers below the ocean surface undergo cyclic growth and destruction, the heat and gas transfer between the successive burst events are performed by molecular diffusion. The model has been upgraded to include heating due to solar radiation. The renewal time is parameterized as a function of the surface Richardson number and the Keulegan number. A Rayleigh number criterion characterizes the convective instability of the cool skin under solar heating. Under low wind speed conditions, the solar heating can damp the convective instability, strongly increasing the renewal time and correspondingly decreasing the interfacial gas exchange. In the ocean, an additional convective instability caused by salinity flux due to evaporation becomes of importance in such cases. The new parameterization is compared with the cool skin data obtained in the western equatorial Pacific during the Tropical Ocean Global Atmosphere Coupled Ocean Atmosphere Response Experiment in February 1993. In combination with a model of the diurnal thermocline it describes main features of the field data both in nighttime and daytime. Under low wind speed conditions (< 5 m s^-1) diurnal variations of the sea surface temperature due to the formation of a diurnal thermocline were substantially larger than those across the cool skin. Under wind speeds > 5 m s^-1, diurnal variations of the surface temperature due to the variations of the thermal molecular sublayer become more important.     

Rate constants for the reactions of the NO3 radical with HCOOH/HCOO− and CH3COOH/CH3COO− in aqueous solution between 278 and 328 K

The kinetics of the aqueous phase reactions of NO₃ radicals with HCOOH/HCOO^– and CH₃COOH/CH₃COO^– have been investigated using a laser photolysis/long-path laser absorption technique. NO₃ was produced via excimer laser photolysis of peroxodisulfate anions (S₂O ₈ ^2– ) at 351 nm followed by the reactions of sulfate radicals (SO ₄ ^– ) with excess nitrate. The time-resolved detection of NO₃ was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO₃ with formic acid (1) and formate (2) rate coefficients ofk ₁=(3.3±1.0)×10⁵ l mol^–1 s^–1 andk ₂=(5.0±0.4)×10⁷ l mol^–1 s^–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k ₁(T)=(3.4±0.3)×10¹⁰ exp[–(3400±600)/T] l mol^–1 s^–1 andk ₂(T)=(8.2±0.8)×10¹⁰ exp[–(2200±700)/T] l mol^–1 s^–1. The rate coefficients for the reactions of NO₃ with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k ₃=(1.3±0.3)×10⁴ l mol^–1 s^–1 andk ₄=(2.3±0.4)×10⁶ l mol^–1 s^–1. The temperature dependences for these reactions are described by:k ₃(T)=(4.9±0.5)×10⁹ exp[–(3800±700)/T] l mol^–1 s^–1 andk ₄(T)=(1.0±0.2)×10¹² exp[–(3800±1200)/T] l mol^–1 s^–1. The differences in reactivity of the anions HCOO^– and CH₃COO^– compared to their corresponding acids HCOOH and CH₃COOH are explained by the higher reactivity of NO₃ in charge transfer processes compared to H atom abstraction. From a comparison of NO₃ reactions with various droplets constituents it is concluded that the reaction of NO₃ with HCOO^– may present a dominant loss reaction of NO₃ in atmospheric droplets.     

鲁23井“动水位”观测的分析

本文介绍了鲁23井“动水位”观测情况。提出了一个分析有泄流的“动水位”的新方法,即把流量换算成水位,以等效静水位来表示“动水位”与流量。由于把“动水位”与流量用一个量来计算,从而为“动水位”观测定量的、统一的分析研究提供了新的方法。这对提高“动水位”井的监测预报地震能力起一定的作用。 本文还以鲁23井“动水位”观测资料为例,利用新方法进行处理的观测分析结果与理论研究结果是一致的。