Chemical composition of upper crust in eastern China

In an area of 3.3×10⁶ km² within eastern China, 28 253 rock samples were collected systematically and combined into 2718 composite samples which were analyzed by 15 reliable methods using national preliminary certified reference materials (CRMs) for data quality monitoring. The average chemical compositions of the exposed crust, the sedimentary cover and the exposed basement as well as the upper crust for 76 chemical elements in eastern China are given. A key basic geology projcct supported by Ministry of Geology and Mineral Resources of China.     

Crystal morphologies in pillow basalts: implications for mid-ocean ridge processes

We present the results of a detailed petrological study of a sparsely phyric basalt (MAPCO CH98-DR11) dredged along the Mid-Atlantic Ridge (30°41′N). The sample contains microphenocrysts of olivine that display four different rapid-growth morphologies. Comparison of these morphologies with those obtained in dynamic crystallization experiments allows us to constrain the thermal history of the sample. The dendritic morphology (swallowtail, chain and lattice olivine) is directly related to the final quenching during magma–seawater interaction. In contrast, the three other morphologies, namely the complex polyhedral crystal, the closed hopper and the complex swallowtail morphology result from several cycles of cooling–heating (corresponding to a maximum degree of undercooling of 20–25°C) during crystal growth. These thermal variations occurred before eruption and are interpreted to be the result of turbulent convection in a small magmatic body beneath the ridge. The results suggest that the Mid-Atlantic Ridge is underlain by a mush zone that releases batches of liquid during tectonic segregation. Aphyric basalts are emitted during eruptions controlled by the tectonic activity, whereas phyric basalts correspond to small fractions of magma from the mush zone mobilized by reinjections of primitive magmas.     

Magmatic effects of the lunar late heavy bombardment

Large volumes of mare basalts are present on the surface of the moon, located preferentially in large impact basins. Mechanisms relating impact basins and mare basalt eruptions have previously been suggested: lunar impacts removed low-density material that may have inhibited eruption, and created cracks for fluid flow [Icarus 139 (1999) 246], and lunar basins have long been described as catchments for magma (e.g., [Rev. Geophys. Space Phys. 18 (1980) 107] and references therein). We present a new model for melt creation under near side lunar basins that is triggered by the impacts themselves. Magma can be produced in two stages. First, crater excavation depressurizes underlying material such that it may melt in-situ. Second, the cratered lithosphere rises isostatically, warping isotherms at the lithosphere-asthenosphere boundary which may initiate convection, in which adiabatic melting can occur. The first stage produces by far the largest volume of melt, but convective melting can continue for up to 350 Ma. We propose that giant impacts account for a large portion of the volume and longevity of mare basalt volcanism, as well as for several compositional groups, including high alumina, high titanium, KREEP-rich, and picritic magmas.     

峨嵋玄武岩流体包裹体中铂钯的测定方法研究

峨嵋玄武岩同生流体包裹体在800℃爆裂后，2．0g／L NH4Cl溶液提取流体中Pt、Pd，C-410树脂富集-电感耦合等离子体质谱测定，方法相对误差小于25％。激光拉曼光谱与四级质谱测定包裹体的气液成分结果表明：流体中存在一定量的有机组分，这对Pt、Pd以有机螯合态形式进入流体提供了可能。     

High-Ti type N-MORB parentage of basalts from the south Andaman ophiolite suite,India

A complete dismembered sequence of ophiolite is well exposed in the south Andaman region that mainly comprises ultramafic cumulates, serpentinite mafic plutonic and dyke rocks, pillow lava, radiolarian chert, and plagiogranite. Pillow lavas of basaltic composition occupy a major part of the Andaman ophiolite suite (AOS). These basalts are well exposed all along the east coast of southern part of the south AOS. Although these basalts are altered due to low-grade metamorphism and late hydrothermal processes, their igneous textures are still preserved. These basalts are mostly either aphyric or phyric in nature. Aphyric type exhibits intersertal or variolitic textures, whereas phyric variety shows porphyritic or sub-ophitic textures. The content of alkalies and silica classify these basalts as sub-alkaline basalts and alkaline basalts. A few samples show basaltic andesite, trachy-basalt, or basanitic chemical composition. High-field strength element (HFSE) geochemistry suggests that studied basalt samples are probably derived from similar parental magmas. Al₂O₃/TiO₂ and CaO/TiO₂ ratios classify these basalts as high-Ti type basalt. On the basis of these ratios and many discriminant functions and diagrams, it is suggested that the studied basalts, associated with Andaman ophiolite suite, were derived from magma similar to N-MORB and emplaced in the mid-oceanic ridge tectonic setting.     

Geochemistry and petrogenesis of anorogenic basic volcanic-plutonic rocks of the Kundal area,Malani Igneous Suite,western Rajasthan,India

The Kundal area of Malani Igneous Suite consists of volcano-plutonic rocks. Basalt flows and gabbro intrusives are associated with rhyolite. Both the basic rocks consist of similar mineralogy of plagioclase, clinopyroxene as essential and Fe-Ti oxides as accessories. Basalt displays sub-ophitic and glomeroporphyritic textures whereas gabbro exhibits sub-ophitic, porphyritic and intergrannular textures. They show comparable chemistry and are enriched in Fe, Ti and incompatible elements as compared to MORB/CFB. Samples are enriched in LREE and slightly depleted HREE patterns with least significant positive Eu anomalies. Petrographical study and petrogenetic modeling of [Mg]-[Fe], trace and REE suggest cogenetic origin of these basic rocks and they probably derived from Fe-enriched source with higher Fe/Mg ratio than primitive mantle source. Thus, it is concluded that the basic volcano-plutonic rocks of Kundal area are the result of a low to moderate degree (< 30%) partial melting of source similar to picrite/komatiitic composition. Within plate, anorogenic setting for the basic rocks of Kundal area is suggested, which is in conformity with the similar setting for Malani Igneous Suite.     

Particularités de la contamination crustale des phonolites : exemple du Velay oriental (Massif central)

Sr and Nd isotopic compositions of one trachyte, eight phonolites and five basalts have been measured. The isotopic characteristics of the trachyte can be explained by a combined assimilation–fractional crystallization process within an upper crustal magmatic chamber. Some phonolites display isotopic signatures identical to basalts, suggesting that they have been protected against any crustal assimilation during their formation. Some others have low Sr contents, whereas they are enriched in radiogenic Sr (0.70451<⁸⁷Sr/⁸⁶Sr_i<0.71192), and display basaltic ¹⁴³Nd/¹⁴⁴Nd ratios. Both observations could be explained by very strong alkali feldspar fractionation and by subsequent very low assimilation of surrounding rocks (between 0.3 and 4%) during intrusion. To cite this article: J.-M. Dautria et al., C. R. Geoscience 336 (2004).     

Changes in soil organic carbon and other physical soil properties along adjacent Mediterranean forest, grassland, and cropland ecosystems in Turkey

Cultivation, overgrazing, and overharvesting are seriously degrading forest and grassland ecosystems in the Taurus Mountains of the southern Mediterranean region of Turkey. This study investigated the effects of changes on soil organic carbon (SOC) content and other physical soil properties over a 12-year period in three adjacent ecosystems in a Mediterranean plateau. The ecosystems were cropland (converted from grasslands in 1990), open forest, and grassland. Soil samples from two depths, 0–10 and 10–20 cm, were collected for chemical and physical analyses at each of cropland, open forest, and grassland ecosystems. SOC pools at the 0–20 cm depth of cropland, forest, and grassland ecosystems were estimated at 32,636, 56,480, and 57,317 kg ha⁻¹, respectively. Conversion of grassland into cropland during the 12-year period increased the bulk density by 10.5% and soil erodibility by 46.2%; it decreased SOM by 48.8%, SOC content by 43%, available water capacity (AWC) by 30.5%, and total porosity by 9.1% for the 0–20 cm soil depth (p<0.001). The correlation matrix revealed that SOC content was positively correlated with AWC, total porosity, mean weight diameter (MWD), forest, and grassland, and negatively with bulk density, pH, soil erodibility factor, and cropland. The multiple regression (MLR) models indicated that any two of the three ecosystems and one of the two soil depths accounted for 86.5% of variation in mean SOC values ((p<0.001).     

Modeling Spatially and Temporally Complex Land‐Cover Change: The Case of Western Honduras*

This article presents an econometric analysis of land‐cover change in western Honduras. Ground‐truthed satellite image analysis indicates that between 1987 and 1996 net reforestation occurred in the 1,015‐km² study region. While some reforestation can be attributed to a 1987 ban on logging, the area of reforestation greatly exceeds that of previously clear‐cut areas. Further, new area was also deforested between 1987 and 1996. Thus, the observed land‐cover changes represent a complex mosaic of changing land‐use patterns across time and space. The analysis contributes to the literature on land‐cover change modeling in that: (1) it compares two econometric approaches to capture complex and often bidirectional changes in land cover from 1987 to 1996 as a function of agricultural suitability and transportation costs, and (2) it addresses techniques to identify and correct for spatial autocorrelation in a categorical regression framework.     

Partial melting controls on the northwest Kyushu basalts from Saga-Futagoyama

Abstract   The major element and compatible trace element compositions of the northwest Kyushu basalts (NWKBs) collected from Saga-Futagoyama were analyzed to examine the petrogenesis of these basalts. Although nepheline-normative alkaline basalts are not found in the basalts from Saga-Futagoyama, the Saga-Futagoyama basalts almost cover the major element variations of NWKBs. The basalts can be chemically divided into two groups: an Fe-poor group (IPG) and an Fe-rich group (IRG). The compositional variation of IPG basalts is essentially controlled by the partial melting of the source as suggested by the following: (i) bulk rock MgO, FeO and NiO compositions indicate that some IPG samples were equilibrated with mantle olivine; and (ii) correlations between Al₂O₃, CaO and MgO are consistent with those of experimental partial melts of peridotites. The inconsistent behaviors of the elements compatible with clinopyroxene (Cpx), such as V (Sc and Cu), preclude the significant role of the fractional crystallization of Cpx and spinel in IPG variation. IPG basalts have low Al and high Fe concentrations compared to the products of melting experiments involving peridotites and pyroxenites, suggesting that the IPG source would have a lithology and bulk rock composition different from those of typical peridotites and pyroxenites. IRG basalts have negative correlations between Fe₂O₃* and MgO, and between V and Fe₂O₃*/MgO, indicating that IRG basalts would have fractionated Cpx. However, the anomalously Fe-rich feature of IRG basalts compared with NWKBs collected from other areas suggests that the role of Cpx fractionation in NWKBs is minor. Relatively low melting temperatures would have principally caused the large chemical variation of NWKBs.