Processes controlling cobalt distribution in two temperate estuaries,Sagami Bay and Wakasa Bay,Japan

Concentrations of cobalt (Co) in surface waters from the Sagami River to northern Sagami Bay and from the Yura River to southwestern Wakasa Bay in Japan were determined in order to investigate the factors governing the distribution of this metal during estuarine mixing. Dissolved (<0.2 μm) and particulate (>0.2 μm) Co showed non-conservative mixing behavior with low or mid-salinity maxima within those two estuarine regions, indicating benthic remobilization and/or sewage input apart from riverine input during the estuarine mixing. These results are supported by a suite of complementary measurements of other parameters, such as manganese, phosphate, and suspended particulate matter concentrations. In addition, the concentration ratio of dissolved Co to total Co (dissolved plus particulate) increased along the salinity gradient, implying the potential for desorption of this metal from suspended particulate matter on estuarine mixing.     

砖红壤速效磷3种测定方法的比较

用Ｏｌｓｅｎ、Ｂｒａｙ－１ 和Ｍｅｈｌｉｃｈ－３ 三种方法对不同植被下的砖红壤进行速效磷的测定比较。结果表明：种植橡胶的土壤磷,Ｂｒａｙ－１ 法和Ｍｅｈｌｉｃｈ－３ 法间有较好的一致性,且呈显著相关;种植甘蔗的土壤磷,三种方法间均呈极显著相关;而种植其它植物的土壤磷,方法间的一致性较差,相关也不显著。一般情况下,建议不要用Ｍｅｈｌｉｃｈ－３ 作为砖红壤速效磷的提取剂。     

青岛地区生态足迹的初步估算

以青岛地区2002年的统计资料为依据,对该地区的生态足迹进行了计算和分析.结果表明,该地区2002年人均生态足迹为1.541 5 hm~2,生态承载力为0.375 1 hm~2,生态赤字达到1.166 4 hm~2.这说明青岛地区人类活动所产生的压力已经超出自然界的承受能力.通过分析,该地区的能源消耗高,生态赤字较大,农业和林业基本不存在生态赤字,可持续发展度较高,而近年来对海洋的过度开发及排污,导致青岛沿岸海域的生态足迹迅速增加,生态赤字越来越高.旅游产业虽然对生态系统产生了一定压力,但是给当地带来了较大的经济效益,青岛地区每公顷生态足迹可产生1 720美元的产值,高出了1 106美元/hm~2的世界平均值,是中国内地平均产值的4倍.青岛地区生态效益较高,但仍需采取相应措施提高其可持续发展度.     

主体功能区划可利用土地资源指标项及其算法

测算和评价可利用土地资源(即后备适宜建设用地潜力)是开展主体功能区划的关键基础工作之一。在重点阐述主体功能区划可利用土地资源指标项涵义、功能、重要因素参数选择以及算法和技术流程的基础上,借助GIS空间分析技术,利用数字地形高程图(DEM)、2000年TM遥感影像解译土地利用图、县级行政区划图和国土部门土地利用变更数据,测算和评价了2005年我国可利用土地资源的数量和空间分布特征。研究结果表明:2005年我国可用于建设用地的可利用土地资源面积约28.54×10⁴km²,占全国陆地国土总面积的3.01％;全国人均可利用土地资源面积为0.34亩/人,其空间分布的基本特点是高值区相对集中于东北、华北北部、西北以及黄河中游地区,低值区成片集中于青藏高原和中、东部人口密集地区。     

大洋富钴结壳研究现状与进展

在研究富钴结壳的地质构造背景时,发现富钴结壳的形成与板内地幔柱活动胡关,并与基岩类型和基岩的风化程度有关。由于现代分析测试技术的进步,对富钴结壳的结构造,矿物组成和地球化学特征的研究正在逐渐深入,特别是各种微区观察测试技术和同位素年代学方法的应用,使富钴结壳的高分辨率部面研究取得长足的发展。以此为基础,生长速率缓慢,在无沉积物时期生长的富钴结壳近年来被尝试用于古海洋学和全球变化的研究,它不但能反映千万年级的环境变化,而且能弥补深海沉积物所不能反映的沉积间断的历史,因此正成为该领域研究中的一个热点。在富钴结壳的成矿物质来源方面,逐渐认识到包括火山,热液和低温水岩反应等在内的内源物质供应的重要性。在结壳的成因机制研究方面发现微生物在结壳的形成过程中起到了主要作用。     

Using caesium‐134 and cobalt‐60 as tracers to assess the remobilization of recently‐deposited overbank‐derived sediment on river floodplains during subsequent inundation events

River floodplains act as sinks for fine‐sediment and sediment‐associated contaminants. Increasing recognition of their environmental importance has necessitated a need for an improved understanding of the fate and residence times of overbank sediment deposits over a broad range of timescales. Most existing investigations have focused on medium‐term accretion rates, which represents net deposition from multiple flood events over several decades. In contrast, the fate of recently‐deposited sediment during subsequent overbank events has received only limited attention. This paper presents a novel tracing‐technique for documenting the remobilization of recent overbank sediment on river floodplains during subsequent inundation events, using the artificial radionuclides, caesium‐134 (¹³⁴Cs) and cobalt‐60 (⁶⁰Co). The investigation was conducted within floodplains of the Rivers Taw and Culm in Devon, UK. Small quantities of fine‐sediment (< 63 µm dia.), pre‐labelled with known activities of either ¹³⁴Cs or ⁶⁰Co, were deposited at 15 locations across each floodplain. Surface inventories, measured before and after three consecutive flood events, were used to estimate sediment loss (in g m^–2). Significant reductions provided evidence of the remobilization of the labelled sediment by inundating floodwaters. Spatial variations in remobilization were related to localized topography. Sediment remobilized during the first two events for the River Taw floodplain were equivalent to 63 · 8% and 11 · 9%, respectively, of the original mass. Equivalent values for the River Culm floodplain were 49 · 6% and 12 · 5%, respectively, of the original mass. Sediment loss during the third event proved too small to be attributed to remobilization by overbank floodwaters. After the third event, a mean of 22 · 5% and 35 · 2% of the original mass remained on the Taw and Culm floodplains, respectively. These results provide evidence of the storage of the remaining sediment. The findings highlight the importance of remobilization of recently‐deposited sediment on river floodplains during subsequent overbank events and demonstrate the potential of the tracing‐technique. Copyright © 2013 John Wiley & Sons, Ltd.     

驼路沟喷气沉积型钴（金）矿床成矿地质背景及矿床成因的地球化学限制

驼路沟矿床是东昆仑南部造山带中新发现的钴(金)矿床,它的含矿岩系是一套浅变质的(绿片岩相)震旦-寒武纪火山-沉积岩系.火山岩是一套中-酸性凝灰岩及熔岩,其元素地球化学特征类似于活动大陆边缘或弧火山岩;沉积岩包括碎屑岩和黑色页岩,它们具有活动大陆边缘沉积岩的元素地球化学极性,部分沉积岩具有现代大陆弧地区沉积岩的元素地球化学特征.岩相学、矿物学及元素地球化学研究证明,作为主岩之一的石英钠长岩是典型的喷气沉积岩,而并非"脉岩",它不但是钴(金)矿体的重要找矿标志,而且也是喷气沉积矿床的重要鉴别标志.钴(金)矿石组构及矿石矿物的世代显示其主要与海底喷气沉积成矿作用有关,在后期的碰撞造山过程中,受到了改造和活化.矿石和喷气沉积岩的痕量元素地球化学特征表明,它们同属喷气-成矿流体较远离喷气中心的海底沉积物.总之,岩(矿)相学及元素地球化学资料证明,驼路沟钴(金)矿床主要属喷气沉积矿床,形成于震旦-寒武纪东昆仑南缘的活动大陆边缘环境.     

Distributions of dissolved vitamin B12 and Co in coastal and open-ocean environments

Distributions of dissolved vitamin B₁₂ and total dissolved Co were measured to gain an understanding of the cycling of these interdependent micronutrients in six marine settings including; an upwelling location, a semi-enclosed bay, two urban coastal systems, and two open ocean locations. Along the coast of Baja California, Mexico, concentrations of B₁₂ and dissolved Co varied from 0.2 to 11 pM and 180 to 990 pM, respectively. At a nearby upwelling station, vitamin B₁₂ and Co concentrations ranged from 0.3 to 7.0 pM and 22 to 145 pM, and concentrations did not correlate with upwelling intensity. Concentrations of B₁₂ were highest within Todos Santos Bay, a semi-enclosed bay off the coast of Baja California, Mexico, during a dinoflagellate bloom, ranging from 2 to 61 pM, while Co concentrations varied between 61 and 194 pM. In the anthropogenically impacted Long Island Sound, NY, U.S.A., B₁₂ levels were between 0.1 and 23 pM and Co concentrations varied from 60 to 1900 pM. However, anthropogenic inputs were not evident in B₁₂ levels in the San Pedro Basin, located outside Los Angeles, Ca, U.S.A., where concentrations of B₁₂ were 0.2–1.8 pM, approximating observed open ocean B₁₂ concentrations. In the Southern Ocean and North Atlantic Ocean, B₁₂ levels were 0.4–4 pM and 0.2–2 pM, respectively. Total Co concentrations in the Southern Ocean and North Atlantic tended to be low; measuring 26–59 pM and 15–80 pM, respectively. These low Co concentrations may limit B₁₂ synthesis and its availability to B₁₂-requiring phytoplankton because the total dissolved Co pool is not necessarily entirely bioavailable.     

宁阳县城区地下水应急后备水源地研究

开展城市应急后备水源地调查研究,对于提高加强城市地下水资源储备,提高城市在特枯年或连续干旱年及污染事件突发时的供水能力,提高饮用水安全保证程度,构建水资源战略储备及保障体系,保障城市供水安全具有重要现实意义。着重研究分析宁阳县地下水富水地段,充分挖掘现有地下水水源地的资源潜力,提出应急供水水源地位置及概算了可供水量。     

兰坪盆地白秧坪铜钴多金属矿床中钴的成矿地球化学

白秧坪铜钴多金属矿床产于下白垩统景星组陆相红色碎屑岩中，呈似层状、脉状分布于断裂带内，蚀变分带明显。研究表明：在原生矿石中钴主要赋存于独立矿物．辉砷钴矿中，同时钴可以类质同象赋存于砷黝铜矿及少量含钴黄铁矿中；在氧化矿石中，以钴华存在于矿石的表面。辉砷钴矿的成分和Co／Ni比值揭示钴的成矿作用与基性．超基性岩浆有关。矿床褪色蚀变岩、碳酸盐化蚀变岩矿石和正常岩石具有类似的稀土元素配分模式，即富集轻稀土而重稀土相对亏损、铈异常不明显而铕异常显著，但稀土元素总量、分异程度存在明显的差异。这可能与流体中带入稀土元素的方式、带入稀土的矿物类型和流体性质的差异等因素造成，反映成矿物质来源存在差异。相对正常岩石的微量元素含量，元素Cu、Co、As、Sb、Bi、Ag等在褪色蚀变岩、碳酸盐化蚀变岩和矿石中均相对富集，但在在褪色蚀变岩以亲石元素富集最明显，而在碳酸盐化蚀变岩和矿石中以显著富集亲硫元素(成矿元素)为主特征，表明在蚀变过程中，赋矿围岩本身没有为成矿作用提供主成矿元素，主成矿元素源自幔源的基性岩浆。由此认为钴的成矿作用可能主要与喜马拉雅期幔源的基性岩浆活动有关。