发射光谱载体蒸馏法测定地质样品中微量硼铍锡银

选择了适合的缓冲剂,利用载体蒸馏法将被测元素与基体元素分离,使Be转变为易挥发的氟化物与B、Sn、Ag同时蒸发;降低了谱线背景及元素检出限;加入内标元素Au、Bi,提高了方法的准确度和精密度;采用普通 3mm×3mm×0.7mm杯型电极,装样量少,操作简单。方法检出限(wB/10-6)分别可达B1.5、Be0.3、Sn0.8、Ag0.02;准确度(Δlog C)基本在-0.05～0.05,精密度(RSD,n=8)为2.9%～17%。     

河北兴隆洞子沟银-铜矿床地质特征及成因探讨

根据矿床地质特征、成矿温度、成矿时代及成矿物质来源等方面的研究，认为本矿床成矿流体来源于地慢岩浆水，并有海水混入。成矿物质主要来源于深部地壳和地慢，通过同生断裂喷气—喷流作用，在有利的地层和物理化学条件下沉淀成矿。矿床成因属于同生断裂喷流热液层控矿床。     

Polymetallic Mineralization at the Suttsu Vein-type Deposit, Southwestern Hokkaido, Japan

Abstract. The Suttsu polymetallic vein-type deposit, hosted by tuff, tuff breccia and shale of the Miocene Kunnui Formation and propylitized hornblende-augite andesite, is located in southwestern Hokkaido, Japan. It has been exploited and explored for Cu, Pb, Zn and Ag until 1962.
In this study, we examined K-Ar ages, ore mineralogical characteristics and fluid inclusions to obtain new data for the deposit.
The K-Ar ages on sericite indicate that the polymetallic mineralization occurred in Late Miocene (8.1–5.7 Ma). The polymetallic banded ore from the Ohkubo vein is characterized by an abundance of Au, Ag, Sn, Bi, in, Se and Te. These metals are mainly ascribed to electrum (30.3–37.8 atom% Ag), Se-bearing pavonite (8.5–9.5 wt% Se), gustavite-lillianite solid solution, Se-bearing bismuthinite (5.0–5.3 wt% Se), kawazulite, cassiterite, Sn-bearing chalcopyrite (3.3–4.2 wt% Sn), In-bearing stannite, stannite-chalcopyrite solid solution, and In- and Sn-bearing sphalerite (2.6–8.4 wt% In and 1.8–4.3 wt% Sn), occurring in narrow bands of the ore. The In- and Sn-bearing sphalerite likely forms a sphalerite-roquesite-stannite solid solution with the contents of roquesite and stannite being about 2–9 and 2-A mole%, respectively. Temperatures and salinities (in wt% NaCl equiv.) of the ore fluids are estimated to be 180-250C and 3–4 wt%, respectively. The Sn-bearing chalcopyrite therefore probably precipitated metastably. The geologic and mineralogical features suggest that pre-Tertiary basement rocks rich in organic material underlie the Miocene Kunnui Formation nearby the deposit and that they contributed to local and temporary reduction of magnetite-series magmas favorable for the early stage tin-polymetallic mineralization.     

The mechanisms of paragenesis and separation of silver, lead and zinc in hydrothermal solutions

On the basis of an experimental study and thermodynamic calculation, the mechanisms of paragenesis and separation of silver, lead and zinc in the hydrothermal system have been studied. At acidic to nearly neutral pH, their chloride complexes are stable, and among them the chloride complexes of zinc are most stable. And the sulfide complexes are the dominant species at nearly neutral to alkaline pH,while the sulfide complexes of silver are most stable. With decreasing temperature, [ Cl^-] ,fO2, and increasing pH, the solubilities of silver, lead and zinc will decrease, leading to their deposition and separation. For sulfide complexes, the concentrations of reduced sulfur and pH are two important factors affecting their stabilities. Complexes of different forms and stabilities respond to the variation of conditions to different extents, which gave rise to the paragenesis and separation of silver, lead and zinc in the whole ore-forming process of dissolution, transport and deposition.     

吉林白山刘家堡子狼洞沟金银矿床地球化学特征及成因探讨

通过对刘家堡子-狼洞沟金银矿床地质、成矿元素和同位素地球化学特征的分析和研究,发现矿区内近EW向和NE向断裂构造是主要容矿构造;最佳找矿元素前缘晕组合为As-Sb-Zn,矿上晕元素组合为Au-Ag-Pb-Hg,尾晕元素组合为Ni-Cu-Co;成矿作用中,古老基底中元古宙老岭群变质岩系为成矿提供了丰富的物质来源,而燕山期构造岩浆活动在提供成矿物质的同时还提供了热动力。刘家堡子-狼洞沟金银矿床应划属为与燕山晚期超浅成中酸性岩浆岩有关的中低温热液构造裂隙充填型金银矿床。     

Tracking temporal palynofloral changes close to Cretaceous-Paleogene boundary in Deccan volcanic associated sediments of eastern part of central Deccan volcanic province

Deccan volcanic sequences( DVS) in the central Deccan volcanic province( CDVP) are designated as Sahyadri Group having ~ 500 m thick lava pile associated with multiple sedimentary beds at different stratigraphic levels. In the eastern part of CDVP between the latitude 19 °55 '--20 °25 ' N and the longitudes 78 °15 '--78 °30 ' E,palynological investigation of the intertrappean sedimentary beds at five stratigraphic levels was carried out. The study was basically aimed for tracking the floral and environmental changes across the Deccan transition. The resulting finds indicate that the intertrappean sediments at the lowest stratigraphic level between the earliest lava flows are characterized by presence of marker Maastrichtian palynomorphs- Gabonisporis vigourouxii,Aquilapollenites bengalensis,Azolla cretacea and Farabeipollis associated with triporate and tricolpate pollen grains,phytoliths of Oryzeae of Poaceae family and peridinoid dinoflagellate cysts. The increasing volcanism deteriorated the existing flora as evident by absence of pollen-spores and presence of only structured biodegraded organic matter,fungal spores,acritarchs and algal( Botryococcus) remains in the sediments of higher-up in the sequence. For chronostratigraphic constraints on the lava flows magnetic polarity of the flows bracketing the intertrappean beds was investigated. The results indicated presence of N-R-N-R magnetic polarity in the basal lava pile that are interpreted as representing the magnetochron C30 N to C28 R( Maastrichtian-Paleogene). The floral change begins with the onset of volcanism in the chron C30 N and floral deterioration is observed in C29 N with increasing volcanism and it is only in the chron C28 R( Danian) that some evidence of recovery of flora is recorded. The current study shows that in eastern part of CDVP the post Cretaceous-Paleogene boundary eruptions represent the main phase of eruptions that triggered deterioration of the flora.     

物探技术在布敦乌拉隐伏矿产勘查中的应用效果

内蒙古西乌珠穆沁旗布敦乌拉矿区多为第四系覆盖。在该矿区多金属勘查中,依据土壤地球化学圈定的矿化异常布置激电中梯测量,圈定1处激发极化率异常区,长度约890m,宽度约520m,位于已知断层F 1与推断断层F 2之间。采用可控源音频大地电磁测深剖面对该激电异常进行探测,解释视充电率多峰异常与反演电阻率高低跳跃对应区域为矿致异常区。通过钻探验证,发现银多金属矿床资源储量523.93万t,取得了良好的地质找矿效果。     

用卫星热红外信息研究关联断层活动的时空变化--以南北地震构造带为例

断层活动不是孤立的,一条断层的活动可能影响其他断层,并引起这些断层的活动,这些相互作用的断层称为关联断层.本文利用卫星热红外信息以南北地震构造带为例,分析了关联断层活动的时空变化,所使用的信息是经过处理的地表亮温残差低频分量TLOW.结果表明,在一定时段内研究区一些断层间除地震活动表现出相互呼应关系外,其地表亮温残差低频分量TLOW曲线相似,相关系数高,说明热红外信息与地震信息共同反映一个地区断层的关联活动.此外,也存在单独由地表亮温残差低频分量TLOW相关表现断层关联活动的情形,即断层间无地震活动的呼应关系,但也存在TLOW曲线的相关性,同样显示关联断层的相互作用.对TLOW的时空过程分析表明,关联活动组合可随时间发生变化.例如,1988～1994年间红河断裂与澜沧-耿马断裂、金沙江断裂等构成关联活动组合,1994～1998年又与小金河断裂、安宁河-小江断裂构成关联活动组合,这样的时空变化过程可能是地壳应力场重新分配的反映.本文的研究结果证明,卫星热红外信息有望成为研究断层相互作用的一个新的独立物理量,并将对地震动力学和构造物理学的发展有重要意义.     

菲与纳米银对胶州湾表层沉积物反硝化作用的复合毒性效应评价

多环芳烃(PAHs)与纳米材料污染已对沉积物生态系统和人类生存环境构成严重威胁,其复合污染的毒性效应环境危害可能更大。为了深入探讨PAHs与纳米材料对近岸表层沉积物反硝化作用的复合毒性效应,本文选取位于胶州湾(JZB)的大沽河河口区(DRE)E站和湾内S站,分别以菲和纳米银代表PAHs和纳米材料,通过测定不同剂量单一及复合污染下沉积物反硝化潜势(PDA)的变化,结合浓度相加模型(CA)、独立作用模型(IA)和中效/联合指数等效图法(CI)三种复合毒性评价方法,评价菲和纳米银对沉积物反硝化潜势的复合毒性效应,并对评价方法进行了优选。结果表明,两种污染物浓度越高,对研究区域反硝化潜势的抑制作用越大。菲、纳米银单一及复合作用下对河口区沉积物反硝化潜势的EC50值分别为44.62、112.49和64.86 mg·kg-1,对湾内分别为61.79、147.05和96.18 mg·kg-1。菲单一作用对反硝化潜势的抑制效应强于纳米银,但复合污染的抑制效应更强。两种污染物对河口区的沉积物反硝化潜势抑制效应强于湾内,可能与河口区具有较高Eh和沉积物颗粒度及较低的pH、盐度和有机质含量有关。三种毒性效应评价方法的结果表明,菲和纳米银的复合污染对2个站位反硝化潜势的毒性效应均为协同作用,且对大沽河河口区的协同作用更强。此外,CI法对复合效应的预测结果比CA和IA法更为接近实际观测值,且CI不需要考虑污染物作用模式的限制,因此认为CI法更适用于评价混合污染对沉积物反硝化作用复合影响的效果。本研究结果表明,菲和纳米银会增强彼此对反硝化菌及反硝化功能的毒性效应,由此推断,PAHs和纳米材料在环境中同时存在时比其单独存在对沉积环境的危害更大。     

新探明的玻利维亚银沙(Silver Sand)超大型银矿床地质特征和找矿评价

银沙银矿(Silver Sand silver deposit)是玻利维亚锡矿带内新探明的一个超大型中硫型浅成低温热液银矿床,已探明银金属资源量约1万t,平均银品位约120 g/t,并伴有少量铅、锌、铟、镓.银矿化与中新世中酸性侵入岩和次火山岩有关.矿体赋存于白垩系蚀变褪色石英砂岩中的密集构造裂隙带内.成矿作用可以划分...