南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.     

广东省典型矿区生态复绿遥感调查研究

以多期遥感数据为数据源,采用人机交互解译方法提取了广东省大宝山多金属矿、云浮硫铁矿、石菉铜矿3个典型矿区生态复绿的位置、面积、变化趋势,结合野外实地调查,查明了矿区生态复绿现状,结果表明:大宝山多金属矿共有3个生态复绿区,生态复绿面积总计约10.08万m~2;云浮硫铁矿生态复绿区主要位于东南部采场,面积总计约65.21万m~2;石菉铜矿总计有生态复绿区25.4万m~2,其中已复绿区15.4万m~2,正在复绿区10.0万m~2,还有大片区域急需复绿。最后总结了3个矿区生态复绿措施和效果,并提出值得借鉴的地方和存在的不足。该文采用的技术方法能够为其他矿区特别是大范围矿区生态复绿的快速提取提供有益的参考。     

华南型块状硫化物矿床中的胶黄铁矿及其退火作用

华南型块状硫化物矿床中胶黄铁矿的退火过程从早到晚可分成三个阶段:原始晶化变胶体阶段、不等粒变晶生长阶段和颗粒界面调整阶段。不同阶段的矿石各具特征性的结构,反映了燕山期侵入活动对于先存胶黄铁矿的不同程度热效应。     

原始黄铁矿莓体的发现与研究

用扫描电子显微镜研究晋东南太原组下部黄铁矿矿石和煤岩中的黄铁矿,发现许多原始莓体保留着形成时的特征。这些特征反映出原始莓体大多数为硫磺细菌化石,少数由胶体形成。本文对莓体的成因、特征、形成环境等进行了论述。     

广东云浮硫铁矿床的成矿大地构造背景及其成矿特征

研究了云浮硫铁矿床的成矿特征及大地构造演化史,认为赋存于变质岩学中的该矿床,其特征非单一成因所能解释,与火山喷发有关的沉积成矿,井受到后期变质和热液的叠加、富化、改造,成矿物质的多来源、多成矿方式和多大地构造阶段成矿是其多因复成成矿的主要成矿模式.     

红外光谱方法在找金中的应用综述

从四个方面介绍了红外光谱在金矿普查评价中的应用：石英薄片中气液包裹体与金的关系研究；石英中杂质阳离子与金的关系研究；黄铁矿与金的关系研究；金矿区氧化带和矿带共生组合矿物研究。     

胶东乳山金矿双山子矿区黄铁矿环带结构研究

胶东乳山金矿双山子矿区黄铁绢英岩中的粗粒黄铁矿发育规则环带结构。本文通过黄铁矿单晶发育过程中形态、热电性和化学成分特征的研究，阐明了黄铁矿多阶段生长的历史；揭示了成矿溶液中S、Fe过饱和度和黄铁矿形成温度变化的韵律性或多旋回性；探讨了黄铁矿中微量组分与其导电类型之间、黄铁矿形态与其热电性和含金性之间的有机联系；进一步肯定了黄铁矿{21I}、{211}习性晶、P导型、As、Sb、Se、Te杂质的金矿示矿功能。     

Pressure Solution of Sulphides in Some Massive Sulphide Zinc—lead Deposits of Western Canada：Its Significance in Mobilization of Ore—forming Materials

Pressure solution is a common phenomenon in massive sulphide zinc-lead deposits of western Canada and may have been an important factor leading to the mobilization of ore-forming materials during diagenesis, deformation and metamorphism of sedimentary ores.The control of ductile shear zones over gold mineralization could be explained in view of pressure solution of gold-bearing miner-als under shearing stress and the tesultant mobilization of this metal.     

北祁连铜厂沟金矿含金黄铁矿热电性分析与找矿标志研究

根据铜厂沟金矿的矿区地质特征、含金黄铁矿热电性与微量元素分析等的研究,认为铜厂沟矿区自东向西黄铁矿热电性主要为N型电子导型,且有高负值→低正值→低负值→高负值变化趋势,提出Ag、As、Sb元素高浓度特征是金矿富集的有利部位,高硫黄铁矿与低硫黄铁矿混生或P、N导型黄铁矿混生是金矿富集的标志,含黄铁矿硫化物石英脉是有利的找矿标志.     

电感耦合等离子体原子发射光谱法测定黄铁矿中微量元素

采用电感耦合等离子体原子发射光谱法检测了黄铁矿中Cd,Co,Cu,Mn,Pb,Zn和Ni。用干扰系数校正法消除黄铁矿中铁对上述元素的干扰，采用HCl-HNO3体系溶解矿样，不需化学分离，直接测定。方法已应用于国家标准物质GBW07267的测定。结果与标准值相符，相对标准偏差（n=8)为1.5%-7.3%。