黄铁矿净化水中低浓度磷

以产自安徽铜陵新桥矿的黄铁矿为典型样品,研究黄铁矿对磷的吸附作用。静态实验考察黄铁矿粒度、固液比、pH值、离子强度、温度、吸附时间等因素对黄铁矿去除磷效果的影响,XPS和FE-SEM研究吸附磷后黄铁矿颗粒表面形貌和成分特征。结果表明：黄铁矿粒径越小（50～180目）,去除磷效率越高（9.3%～90.7%）;提高固液比（0.2～2 g/L）,磷的去除率增加（6.5%～97.1%）;在pH值3～9.65范围内黄铁矿对磷都有很好的去除效率（95%以上）;NO3-对磷的去除效果表现为微弱的促进作用,Cl-有微弱的抑制作用,溶液中SO42-、HCO3-对黄铁矿吸附磷表现出较强的抑制作用。温度对黄铁矿吸附效率基本没有影响。黄铁矿对磷吸附动态实验表明除磷效率在16 h后接近最大值。除磷作用机理是黄铁矿表面缓慢氧化产生的三价铁对磷的化学吸附。成果表明黄铁矿用于净化污水中低浓度磷具有很大的潜力。     

铋砷黝铜矿在中国的发现与研究

铋砷黝铜矿产于广东陆丰中低温热液黄铁矿矿床中，呈它形粒状嵌布在黄铁矿内，粒径0．05～0．22mm，与黄铜矿、针硫铋铝矿共生。反射免呈灰色微带蓝色，均质性。显微硬度Hv＝295．5kg／mm2。电子探针成分分析（平均值）为：S24.4％，Cu38．25％，As13．03％，Bi17.人83％，Sb0．48％，Zn2．39％，Fe2.13％，Te1．47％，化学式为：Cu10（Fe0.65Zn0.63Cu0．49）1．77（As2.97Bi1．46Sb0．07）4、50（S12．8Te0.20）13。X射线粉晶衍射强线：2．95（10），2．55（3），1．866（5），1．727（4），1．041（5）。晶胞参数α＝1．0218nm。     

不同类型黄铁矿对金的吸附实验

在稀溶液状态下的Ａｕ的吸附实验，较好地体现了地质热液过程中吸附作用在金矿成矿方面的重要性。黄铁矿与金的硫氢配合物的作用结果截然不同于黄铁矿与金的氯配合物的作用结果。黄铁矿对金的硫氢配合物的吸附是通过表面络合和静电吸附完成的，且不同类型黄铁矿有明显的吸附差异。矿物表面特性及非均匀催化可能在吸附过程中起了重要作用。金矿中常见的Ａｕ、Ａｓ和ｐ型黄铁矿三位一体的现象可能与Ａｓ对吸附作用的影响有较大关系。而     

皖东地区毛山金矿床中石英热发光与黄铁矿热电性标型研究

皖东地区为中国新的金矿资源远景区 ,金矿点分布广泛 ,但开发程度较低。毛山金矿属于中小规模的典型金矿山 ,矿体具有向南侧伏的趋势。烟灰色含矿石英的热发光曲线具有多峰特征 ,并且峰强大、峰位低 ;而乳白色不含矿石英的热发光曲线峰位较高 ,峰强较小。含矿黄铁矿的热电导型以 N型居多 ,热电系数 α绝对值的平均值较大。石英热发光标型和黄铁矿热电性标型均揭示了金矿化具有向矿区南部深部增强的趋势。研究成果不仅为毛山金矿指明了找矿方向 ,还有助于利用石英和黄铁矿标型性特征对皖东地区众多金矿点的矿化远景作出科学评价。     

内蒙古撰山子金矿黄铁矿的热电性特征及其与金成矿作用的关系

研究了撰山子金矿床中金的主要载体矿物黄铁矿的形成世代、黄铁矿热电性的一般特征及黄铁矿的热电性与晶体形态、化学成分及金成矿作用的关系。结果表明：与岩浆作用有关的金矿床中，黄铁矿的导电类型既有n型、p型，又有n—p中间型，并以p型为主；不同成矿阶段的黄铁矿其热电性特征不同；黄铁矿热电性特征在矿体空间上具有一定的规律。     

含金黄铁矿的模拟合成实验及热液作用中金富集机制

热液矿床中金主要以包体金和裂隙金两种赋存状态产出,裂隙金构成富矿石。金的两种析出形式,分别为热液演化过程中金的两组成矿化学反应的结果。同时,金的活化和沉淀作用与热液流体中铁的活动有密切关系。为阐明热液富金矿石形成的机理,进行了含金黄铁矿的模拟合成实验。实验是在自紧式冷封高压釜（石英管衬套）中完成的。实验的物理化学条件模拟胶东玲珑等金矿的实测成矿参数ｔ＝４００～２００℃;ｐ＝５０～１０ＭＰａ;ｃ（ＮａＣｌ＋Ｎａ２Ｓ）＝０５～１ｍｏｌ／Ｌ;ｐＨ＝２～６５。装填物料为Ｆｅ２Ｏ３＋６Ｓ＋ＡｕＣｌ３·ＨＣｌ·４Ｈ２Ｏ或金粉。恒温时间为７～１２ｄ。合成黄铁矿具有完好的立方体或五角十二面体晶形。盐酸分步提取法实验证明,在黄铁矿晶体的核心部分含９０×１０－６～６０×１０－６的分散包体金,而黄铁矿边缘部分及以外的残余Ｆｅ２Ｏ３中仍含有大量的反应残余金粒。实验结果证明,在合成反应体系中只有少量的金与黄铁矿同时析出;而更多的金在残余溶液中富集,在自然热液成矿过程中这部分金可形成晚期裂隙金。实验结果与在胶东等地区热液金矿床观察到的事实吻合。     

辽东裂谷白云金矿载金黄铁矿Re-Os定年及其地质意义

白云金矿是辽东裂谷区内重要的大型金矿之一,长期以来缺少直接的年代学数据。本次对白云金矿不同矿石类型中的8件载金黄铁矿进行了Re-Os同位素定年,获得其等时线年龄为225.3±7.0 Ma(MSWD=5.8),187Os/188Os初始值为2.1±2.8。结合前人的研究成果及本次年代学研究得出:白云金矿形成于印支期,其成矿物质主要为壳源,白云金矿是与印支期岩浆活动有关的热液矿床;其形成构造背景可能为受蒙古–鄂霍次克大洋向南北两侧俯冲之后的陆内后碰撞造山环境。本次研究也为今后在辽东裂谷区寻找与印支期岩浆活动有关的矿床提供了依据。     

江西茅排金矿矿物学找矿标志

黄铁矿和石英是主要的载金矿物。黄铁矿形态标型、成分标型、热电性标型和石英红外光谱标型特征具有指导找矿意义。江西茅排金矿区270m中段47勘探线及37～33勘探线的矿物标型特征为：黄铁矿形态见有八面体和五角十二面体，五角十二面体和八面体等聚形；出现空穴心型导电和混合型导电黄铁矿，若为电子心型导电黄铁矿，其热电动势和热电系数的绝对值相对较大；黄铁矿成分中检测出Cu；石英相对吸光度（37～33勘探线）DH2O 0.940 3, DCO2 0.1961, DCO2/DH2O0.259 1,略低于矿区研究样品的平均值（DH2O1.3267,DCO20.3090,DCO2/DH2O0.3382）.表明该处应位于矿体的中上部，矿体向下有一定的延伸。     

Pyrite-hydrocarbon Interaction under Hydrothermal Conditions: an Alternative Origin of H2S and Organic Sulfur Compounds in Sedimentary Environments

Sulfate rocks and organic sulfur from sedimentary organic matter are conventionally assumed as the original sulfur sources for hydrogen sulfide(H_2S) in oil and gas reservoirs. However,a few recent experiments preliminarily indicate that the association of pyrite and hydrocarbons may also have implications for H_2S generation,in which water effects and natural controls on the evolution of pyrite sulfur into OSCs and H_2S have not been evaluated. In this study,laboratory experiments were conducted from 200 to 450° C to investigate chemical interactions between pyrite and hydrocarbons under hydrothermal conditions. Based on the experimental results,preliminary mechanism and geochemical implications were tentatively discussed. Results of the experiments showed that decomposition of pyrite produced H_2S and thiophenes at as low as 330°C in the presence of water and n-pentane. High concentrations of H_2S were generated above 450°C under closed pyrolysis conditions no matter whether there is water in the designed experiments. However,much more organic sulfur compounds(OSCs) were formed in the hydrous pyrolysis than in anhydrous pyrolysis. Generally,most of sulfur liberated from pyrite at elevated temperatures was converted to H_2S. Water was beneficial to breakdown of pyrite and to decomposition of alkanes into olefins but not essential to formation of large amounts of H_2S,given the main hydrogen source derived from hydrocarbons. In addition,cracking of pyrite in the presence of 1-octene under hydrous conditions was found to proceed at 200°C,producing thiols and alkyl sulfides. Unsaturated hydrocarbons would be more reactive intermediates involved in the breakdown of pyrite than alkanes. The geochemistry of OSCs is actually controlled by various geochemical factors such as thermal maturity and the carbon chain length of the alkanes. This study indicates that the scale of H_2S gas generated in deep buried carbonate reservoirs via interactions between pyrite and natural gas should be much smaller than that of thermochemical sulfate reduction(TSR) due to the scarcity of pyrite in carbonate reservoirs and the limited amount of long-chained hydrocarbons in natural gas. Nevertheless,in some cases,OSCs and/or low contents of H_2S found in deep buried reservoirs may be associated with the deposited pyrite-bearing rock and organic matters(hydrocarbons),which still needs further investigation.