鄂尔多斯盆地苏里格地区奥陶系马家沟组马五段白云岩的地球化学特征

苏里格地区奥陶系马家沟组马五段白云岩是重要的油气储集层.多年来,马家沟组白云岩的成因一直是地质研究者讨论的热点话题.对苏里格地区马家沟组马五段白云岩的微量元素及C、O、Sr同位素地球化学资料的分析表明,微量元素表现为高铁、低锰、低锶、低钠;白云石、白云质角砾和孔洞充填白云岩的δ13C和δ18O值较为近似,且白云岩的δ1...     

Genesis of lithium pegmatites from the leinster granite margin,southeast ireland: Geochemical constraints

Extensive and economically-important lithium pegmatites have been described from the eastern flank of the large S-type peraluminous Leinster Granite batholith in southeast Ireland. This flank area is also the locus of a major dip-slip ductile shear zone which was active during emplacement of the Tullow Lowlands pluton of the batholith. All the known bedrock occurrences of lithium pegmatite are contained within this marginal deformation zone. Most previous studies have suggested derivation of the lithium pegmatites by fractionation from the Leinster Granite itself, though none are conclusive. More recently, an anatectic model has been proposed whereby the pegmatites were derived by melting of Li-rich sediments adjacent to the batholithic contact. Our investigation has been concerned with a detailed study of the Rb-Sr isotope systematics and trace element geochemistry of the pegmatites and their host granitoids in an attempt to resolve the problem of pegmatite genesis. The results suggest a strong geochemical and temporal coherence between the Leinster Granite and the lithium pegmatites. A model is proposed in which Li enrichment in residual magmas may be linked to the development of muscovite instead of biotite in the Leinster Granite itself. The Li excluded from entry to biotite then accumulates in highly mobile, low-viscosity pegmatitic fluids which migrate into the marginal shear zone of the Tullow Lowlands pluton where they crystallize at considerably lower temperatures.     

山西高凡银金矿床黄铁矿的微量元素标型特征及其应用

高凡银金矿床黄铁矿的微量元素研究发现富Au、Ag、Pb、Zn、As、Sb,贫Co、Ni、Se,且S/Se较大,S/As和Fe/(Pb+Zn)较小,As/(Co+Ni)、(Pb+Zn)/(Co+Ni)>10。同时高凡矿田中的滩上铜钼矿化点的黄铁矿则显示相反的特征。总结出一套区分两类矿化黄铁矿微量元素的标型特征,对高凡矿田和五台地区各矿化点的判别和评价中显示了一定的适用性,可作为本区寻找同类金银矿床的找矿标型特征。     

海原-六盘山断裂带现今地震危险性的数值模拟分析

基于正交各向异性理论表征断层的变形行为,将平行断层面的剪切模量和周围介质剪切模量的比值作为反演参数,以海原-六盘山断裂附近现今GPS观测地壳水平运动速度场作为约束,通过构建三维有限元模型,采用遗传算法,反演了海原-六盘山断裂平行断层面的剪切模量分布.结果显示:六盘山断裂中南段平行断层面剪切模量与周围介质接近,且沿断层面...     

重庆玉峡锶矿床中分散元素锶的超常富集机制

重庆玉峡锶矿床位于华蓥山构造带的南段。含矿岩系为下三叠统嘉陵江组二段一亚段的含藻含膏白云岩,含矿层位自下而上有三个矿层。矿层呈似层状、透镜状赋存于西山背斜北段的背斜转折端及相邻两翼的层间虚脱部位。矿石矿物有天青石、菱锶矿、钡天青石,脉石矿物为白云石、...     

吉林省西南部地区花岗岩类微量元素特征研究及成因探讨

本文对吉林省西南部地区花岗岩类的微量元素特征进行了系统的研究,并利用微量元素的某些特征值对区内花岗岩成因进行了探讨。     

贵州地区新元古代—三叠纪沉积岩中稀土元素地球化学特征与地壳演化

摘 要　 通过对贵州地区自新元古界板溪群—三叠系深水相泥质岩系统的稀土元素地球化学 研究‚发现寒武系、泥盆系和上二叠统这3个稀土元素组成明显不同于其他层位和后太古代 页岩稀土元素特征的异常层‚并由此构成了地质历史中3个明显的稀土元素地球化学旋回。 这3个稀土元素地球化学旋回与本区的大地构造旋回具有明显的一致性‚且上述的3个稀土 元素地球化学异常层正好与盆地发育的明显的拉张裂陷时期相对应‚说明在盆地拉张裂陷时 期来自盆下深部物源的加入是造成稀土元素地球化学异常的根本原因。这为我们正确认识本 区的地壳演化提供了强有力的地球化学证据。     

The complex one-sided integrals of Cauchy and Hadamard and application to boundary element method

The definitions of complex integrals of Cauchy and Hadamard with the singular point coinciding with the end point of the integration curve are proposed. It is shown that the new integrals satisfy most of the properties of the regular ones, including the change of variables. It is also shown that the Cauchy principal value (CPV) and Hadamard finite-part (HFP) integrals can be considered as a sum of the new type integrals. The application to numerical solution by the boundary element method (BEM) and the complex hypersingular integral equation (CHSIE) for the multiregions of interacting elastic bodies and bodies with cracks and holes is discussed. The different ways to place the collocation points are considered. The numerical results for the problems of circular hole and circular elastic inclusion in infinite plate indicated that the appropriate choice of the approximating functions leads to a high accuracy of the calculation. Applications of the new technique to geomechanics problems are discussed. © 1998 John Wiley & Sons, Ltd.     

Elemental mobility in subduction metamorphism: insight from metamorphic rocks of the Franciscan Complex and the Feather River ultramafic belt,California

The degree of element mobility in subduction metamorphism has generated much debate; some workers advocate considerable mobility during metamorphism, whereas others postulate minimal mobility. We assess this issue by examination of major and trace element concentrations and Pb-, Nd-isotopic data for 39 mafic metavolcanic rocks from the Franciscan subduction complex, related units of coastal California, and the Feather River ultramafic belt of the northern Sierra Nevada, California; these samples span a wide range of metamorphic grade. We conclude that these rocks, despite their metamorphism up to eclogite facies, preserve protolith major and trace elemental compositions and isotopic ratios, with the exception of some mobile large ion lithophile elements such as Ba, Pb, and to a smaller extent La, U, and Sr. Thus subduction metamorphism of these metabasalts occurred in a largely closed system. Lack of light rare earth element enrichment in the rocks demonstrates lack of chemical exchange with subducted metasediments. Relatively low SiO₂ content (<48 wt.%) of many of the metamorphic rocks and the lack of correspondence between silica depletion and metamorphic grade suggests that the silica depletion resulted from seafloor hydrothermal alteration before subduction. In spite of demonstrated mobility of Pb, and possible mobility of Nd, isotopic ratios of Pb and Nd were not modified during subduction metamorphism. In contrast to our results from metabasaltic rocks, our analysis of actinolite-rich rinds from high-grade Franciscan mélange blocks suggests some chemical exchange between metachert and the overlying mantle. The increasing enrichment in Ba and Pb with increasing metamorphic grade suggests that Ba- and Pb-rich fluids interacted more intensely with metabasalt at the higher grades of metamorphism. Comparison of these results with studies of the active Mariana forearc suggests that fluids interacting with the mantle wedge up-dip of the region of magma genesis are derived from subducting sediments overlying the down-going plate.     

Salinity reflux and dolomitization of southern Australian slope sediments: the importance of low carbonate saturation levels

Anomalously saline waters in Ocean Drilling Program Holes 1127, 1129, 1130, 1131 and 1132, which penetrate southern Australian slope sediments, and isotopic analyses of large benthic foraminifera from southern Australian continental shelf sediments, indicate that Pleistocene–Holocene meso‐haline salinity reflux is occurring along the southern Australian margin. Ongoing dolomite formation is observed in slope sediments associated with marine waters commonly exceeding 50‰ salinity. A well‐flushed zone at the top of all holes contains pore waters with normal marine trace element contents, alkalinities and pH values. Dolomite precipitation occurs directly below the well‐flushed zone in two phases. Phase 1 is a nucleation stage associated with waters of relatively low pH (ca 7) caused by oxidation of H₂S diffusing upward from below. This dolomite precipitates in sediments < 80 m below the sea floor and has δ¹³C values consistent with having formed from normal sea water (? 1‰ to + 1‰ Vienna Pee Dee Belemnite). The Sr content of Phase 1 dolomite indicates that precipitation can occur prior to substantial metastable carbonate dissolution (< 300 ppm in Holes 1129 and 1127). Dolomite nucleation is interpreted to occur because the system is undersaturated with respect to the less stable minerals aragonite and Mg‐calcite, which form more readily in normal ocean water. Phase 2 is a growth stage associated with the dissolution of metastable carbonate in the acidified sea water. Analysis of large dolomite rhombs demonstrates that at depths > 80 m below the sea floor, Phase 2 dolomite grows on dolomite cores precipitated during Phase 1. Phase 2 dolomite has δ¹³C values similar to those of the surrounding bulk carbonate and high Sr values relative to Phase 1 dolomite, consistent with having formed in waters affected by aragonite and calcite dissolution. The nucleation stage in this model (Phase 1) challenges the more commonly accepted paradigm that inhibition of dolomitization by sea water is overcome by effectively increasing the saturation state of dolomite in sea water.