矿床保存变化研究的热年代学技术方法

成矿后矿床的保存与变化是矿床地质研究的重要组成部分,但研究程度不高,至今仍属于薄弱环节。矿床的保存与其隆升剥露密切相关,深入细致研究恢复矿区矿床的隆升和剥露历史,是揭示矿床保存变化的一种重要途径。本文重点论述研究矿床保存变化的技术方法,通过综合应用裂变径迹、(U-Th)/He、~(40)Ar-~(39)Ar年代学以及La-ICP-MS、锆石U-Pb定年等多种技术手段,研究成矿期次、构造活动期次以及二者间的联系,定量计算不同矿区、不同矿体、不同部位、不同时间的冷却隆升速率、隆升幅度、剥蚀速率和剥蚀量,探讨矿床保存深度与剥蚀量间的关系,总结不同时代、不同矿区矿床保存-变化过程,建立新的矿床地质-保存环境模型,完善矿床预测的综合示踪标志,最终预测不同矿区、不同地段隐伏矿床可能的产出深度,给出矿床可能已经被剥蚀殆尽的区段或地段,为深部找矿和区域成矿潜力评价提供依据。本文可为地质工作者的相关应用提供借鉴和手段。     

Exhumation of the Mesozoic Guojialing Granodiorite: Implication for the Preservation of Gold Deposits in the Jiaobei Terrane,China

Preservation conditions are very important for mineral systems and a suitable exhumation process is critical for endogenetic deposits, especially for those deposits formed in orogenic settings, where deposits are inclined to erode away due to strong uplift. The G uojialing batholith, intruding into the L inglong granites and the J iaodong G roup right before regional gold mineralization, is one of the most important gold ore‐hosting M esozoic intrusions in the J iaobei terrane. Gold deposits and the intrusion together underwent similar tectonothermal evolutionary processes. Exhumation and denudation process of the G uojialing granodiorite was constrained by biotite geobarometry and apatite fission track (FT ) analysis. Biotite geobarometric data yields an emplacement depth of 3.0 km, while denudation since 110 M a was calculated from the FT data at about 2.7 km. FT inverse modeling revealed a rapid uplift since ca 100 Ma. Compared with the gold ore‐forming depth which is confined between 2.5 and 9.5 km by fluid inclusion studies, great gold potential in the depths is inferred in the J iaobei terrane. Our result is consistent, to some extent, with the hypothesis of a M esozoic paleoplateau in E ast C hina.     

Tectonothermal events in the Olympic IOCG Province constrained by apatite and REE-phosphate geochronology

The Olympic iron oxide–copper–gold province in South Australia contains numerous deposits and prospects, including the Olympic Dam Cu–U–Au–Ag deposit and the Acropolis prospect. The Acropolis prospect comprises massive, coarse-grained magnetite–apatite veins partly replaced by a hematite-stable assemblage. The apatite grains in the veins contain zones with abundant inclusions of other minerals (including monazite and xenotime) and low trace-element concentrations relative to the inclusion-free zones. The inclusion-rich apatite zones are interpreted to be formed from the recrystallisation of the inclusion-free apatite and remobilisation of U, Th and rare earth element (REE) from apatite into monazite and xenotime. Apatite, monazite and xenotime are all established U–Th–Pb geochronometers and offer the potential to constrain the alteration history of the Acropolis prospect. The LA-ICPMS U–Pb age of inclusion-free apatite is within error of the age of the host volcanic units (ca 1.59 Ga). Inclusion-rich apatite yields both near-concordant analyses that are within error of the inclusion-free apatite as well as highly disturbed (discordant) analyses. The most concordant analyses of monazite (Th–Pb) inclusions and xenotime (U–Pb) inclusions and rim grains indicate an alteration event occurred at ca 1.37 Ga and possibly also at ca 500 Ma. The disparity in age of the inclusion-rich apatite and the REE-phosphate inclusions (and rim grains) is suggested to be owing to the apatite being initially recrystallised at ca 1.59 Ga and modified again by a later event that also formed (or coarsened) most of the inclusions. Partial resetting of the majority of the monazite inclusions as well as the presence of significant amounts of common Pb has complicated the interpretation of the monazite results. In contrast, xenotime is a more robust geochronometer in this setting. The ages of the two post-1.59 Ga events that appear to have affected the Acropolis prospect do not correspond to any events known to have occurred in the Gawler Craton. The earlier (ca 1.37 Ga) age instead corresponds best with metamorphic–magmatic–hydrothermal activity in Laurentia, consistent with the proximity of Laurentia and the Gawler Craton inferred from palaeogeographic reconstructions. The later (ca 500 Ma) event corresponds to the Delamerian Orogeny and has been shown by prior studies to have also affected the Olympic Dam deposit.     

渤海湾盆地济阳坳陷碎屑锆石裂变径迹年龄记录的构造抬升事件

对采自渤海湾盆地东南部济阳坳陷的碎屑岩进行测年研究,目的是通过碎屑锆石裂变径迹年龄揭示源区及其抬升剥露史和构造热事件,为华北克拉通构造演化特别是元古宙构造演化提供新的热年代学约束。14件上白垩统-上新统砂岩/粉砂岩岩心样品测年结果显示,锆石裂变径迹年龄分布在308±35Ma~145±19Ma之间,且所有单颗粒锆石径迹年龄均大于其沉积年龄,表明这些锆石为碎屑锆石。除1件样品外,其余13件样品的单颗粒年龄的,可以用来识别源区及其构造抬升。未通过χ2检验的锆石二项式最佳拟合峰值年龄集中分为9组:P1(1187Ma)、P2(720~548Ma)、P3(526Ma)、P4(330~319Ma)、P5(296~274Ma)、P6(213~201Ma)、P7(195~177Ma、162Ma)、P8(134~102Ma)和P9(94Ma),加上通过χ2检验的三叠纪(230Ma),指示源区中元古代-晚白垩世经历的9期构造抬升/岩浆活动。它们分别是发生在中元古代的芹峪运动、新元古代的构造抬升(约720~575Ma)、~548Ma的蓟县运动;古生代~526Ma早寒武世末构造运动、海西期构造抬升;晚三叠世印支期挤压构造抬升、早-中侏罗世印支期弱挤压抬升、早白垩世燕山期强烈岩浆活动及晚白垩世燕山晚期的抬升。华北克拉通北缘、克拉通内部古陆和盆地内部是渤海湾盆地上白垩统-上新统的主要物源区,古生代以来剥露速率逐渐增大,古生代、三叠纪、早-中侏罗世和白垩纪分别为0.020~0.033mm/y,0.033~0.042mm/y,0.034~0.049mm/y和0.041~0.097mm/y,反映源区白垩纪构造/岩浆活动最强烈。锆石裂变径迹年龄记录的中元古代-晚白垩世构造运动对探讨华北克拉通的构造演化特别是元古宙的演化提供了年代学证据,综合分析推断华北克拉通可能参与了Rodinia超大陆的形成与裂解。     

Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.     

Integration of zircon and apatite U–Pb geochronology and geochemical mapping of the Wude basalts(Emeishan large igneous province):A tool for a better understanding of the tectonothermal and geodynamic evolution of the Emeishan LIP

Radiogenic isotopic dating and Lu–Hf isotopic composition using laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS)of the Wude basalt in Yunnan province from the Emeishan large igneous province(ELIP)yielded timing of formation and post-eruption tectonothermal event.Holistic lithogeochemistry and elements mapping of basaltic rocks were further reevaluated to provide insights into crustal contamination and formation of the ELIP.A zircon U–Pb age of 251.3±2.0 Ma of the Wude basalt recorded the youngest volcanic eruption event and was consistent with the age span of 251-263 Ma for the emplacement of the ELIP.Such zircons hadε_Hf(t)values ranging from7.3 to+2.2,identical to those of magmatic zircons from the intrusive rocks of the ELIP,suggesting that crust-mantle interaction occurred during magmatic emplacement,or crust-mantle mixing existed in the deep source region prior to deep melting.The apatite U–Pb age at 53.6±3.4 Ma recorded an early Eocene magmatic superimposition of a regional tectonothermal event,corresponding to the Indian–Eurasian plate collision.Negative Nb,Ta,Ti and P anomalies of the Emeishan basalt may reflect crustal contamination.The uneven Nb/La and Th/Ta values distribution throughout the ELIP supported a mantle plume model origin.Therefore,the ELIP was formed as a result of a mantle plume which was later superimposed by a regional tectonothermal event attributed to the Indian–Eurasian plate collision during early Eocene.     

CONDITIONAL NONLINEAR OPTIMAL PERTURBATIONS: APPLICATION IN TROPICAL CYCLONE FORECASTS

Considering the feature of tropical cyclones (TCs) that strong positive vorticity exists in the lower layers of troposphere, this study proposed to use vorticity at 850 hPa as cost function to find the conditional nonlinear optimal perturbation (CNOP), which was largely different from those previous studies using total energy of perturbed forecast variables. The CNOP was obtained by an ensemble-based approach. All of the sensitive areas determined by CNOP with vorticity at 850 hPa as cost function for the three cases were located over the TC core region and its vicinity. The impact of the CNOP-based adaptive observations on TC forecasts was evaluated with three cases via observational system simulation experiments (OSSEs). Results showed obvious improvements in TC intensity or track forecasts due to the CNOP-based adaptive observations, which were related to the main error source of the verification area, i.e., intensity error or location error.     

冬季北半球风暴轴的多尺度能量变化特征及其可能机制

基于1971—2016年NCEP/NCAR(美国环境预报中心和国家大气研究中心)的逐日再分析资料及NCPC(美国国家海洋和大气管理局气候预报中心)的海温、大气环流及海洋指数等资料通过多尺度能量分析(MS-EVA)等方法,把冬季北半球风暴轴看做一整体,分析了风暴轴区域多尺度的能量变化特征及其可能机制。主要结论概括如下:(1)多年气候平均状态下,风暴轴的动能来源主要表现为在风暴轴中上游先由低频尺度向天气尺度输送有效位能,随后在风暴轴主体区再由天气尺度有效位能转换为天气尺度动能,其中风暴轴西端可直接由低频尺度向天气尺度输送动能。(2)北半球三大风暴轴联合EOF结果表明:第一模态下,主要体现了北西伯利亚风暴轴与北太平洋风暴轴强度的减弱(增强),同时伴随着北大西洋风暴轴位置北抬(南压);第二模态下,主要体现了北西伯利亚风暴轴强度减弱(增强),同时北太平洋风暴轴位置北抬(南压)中东部强度增强(减弱),而北大西洋风暴轴位置南压(北抬)。(3)回归分析表明:北半球风暴轴异常在不同模态下与低频尺度环流联系密切。低频尺度波动可通过海温及西风急流等异常变化先影响风暴轴区域多尺度间的能量转换,进而影响风暴轴整体的异常变化。     

CCSD主孔榴辉岩中磷灰石的矿物化学特征及对榴辉岩中F、Cl、Sr等元素地球化学行为的影响

为探讨榴辉岩中磷灰石的矿物化学特征及榴辉岩中某些相关元素的地球化学行为,对中国大陆科学钻探(CCSD)主孔500~540m深度的榴辉岩样品进行了岩石化学及磷灰石的矿物化学分析。这些榴辉岩具有不同的矿物组成和化学成分,并可据此分为上下两段,上段500~530m为正常榴辉岩,下段530~540m为高Ti榴辉岩和高Ti-Fe榴辉岩,其原岩可能为类似于辉长质和苦橄质的基性—超基性岩石。其中的磷灰石成分没有明显差别,均为氟—磷灰石,其富F贫Cl的特征可能是造成榴辉岩中高盐度流体包裹体和全岩高F低Cl的主要原因。磷灰石普遍含有一定的Sr、S、Fe元素,多数还含有Cu、Pb、Zn等元素。榴辉岩中P2O5含量与其F、Cl、Sr、S元素的相关程度表明,磷灰石是榴辉岩中F元素的最主要储存库,也是Sr元素的重要储存库之一,而对于Cl元素则只是部分控制,与S元素则没有相关性。榴辉岩中F、Sr及Cl元素的地球化学行为主要受控于磷灰石,因此,在榴辉岩从进变质—退变质过程中,这些元素的活动性直接受控于磷灰石的稳定性。     

内插法布设无碴轨道铺轨控制测量网方法

针对勘测设计阶段测量精度要求较低,而无碴轨道施工测量精度要求很高的情况。提出在勘测设计控制网中内插高精度施工控制网的方法。导出保持线路控制网两端切线(直线)实地位置不变,布设高精度施工控制网的办法。