广西东攀剖面二叠系顶部粘土矿物特征及古气候意义

对广西东攀剖面二叠系顶部20个样品中的粘土矿物进行X射线衍射分析。伊利石结晶度值显示这些样品形成于中晚成岩带的地质环境;伊利石、蒙脱石纵向分布规律和伊利石结晶度与伊利石含量的关系表明伊利石除陆源碎屑来源外,可能有部分为蒙脱石伊利石化而成;伊利石结晶度变化曲线和伊蒙混层类型的变化规律表明,本区粘土矿物组合与含量的变化除受到后期成岩作用的影响外,还明显地受沉积因素的控制;伊利石结晶度、伊利石化学指数、高岭石和伊利石的含量、伊蒙混层类型显示东攀剖面以9、10层界线上方5cm为界,古气候由干冷变为湿暖;水介质由偏碱性向酸性转变。     

自生伊利石同位素年代学在钾盐矿床中的应用展望

伊利石是一种层状硅酸盐矿物,层间主要为钾离子,可利用K-Ar法、Ar-Ar法和Rb-Sr法等相关的测年方法来分析和限定与自生伊利石有关的地质事件的时代,例如盆地演化历史、热液活动、构造活动和油气运移。本文讨论了利用钾盐矿床中自生伊利石进行蒸发岩地层年代学研究的可能性。虽然多数研究表明温度是控制自生伊利石形成的主要控制因素,即自生伊利石一般形成于温度较高的条件下,但一些研究表明在地表温度的盐湖环境中也可形成自生伊利石,此种环境下控制自生伊利石形成的主要因素为流体成分。这构成了利用自生伊利石定年来研究蒸发岩地层时代的理论基础。然而在实际研究过程中仍存在很多问题,需进行进一步的研究。     

平顶山市主要非金属矿产的加工利用

该文论述了平顶山市主要非金属矿产———伊利石矿、高岭石矿、滑石矿的化学成分、矿物成分及工艺性能。依据市场情况,指出了该市上述三种非金属矿的利用方向。     

伊利石结晶度及其在低温变质研究中若干问题的讨论

文中介绍与伊利石结晶度相关的伊利石矿物新的定名方案;讨论了伊利石结晶度的结晶学基础与Scherrer方程式的关系;讨论了三个重要的伊利石结晶度指数Weaver、K櫣bler和Weber指数的关系,并介绍推导的Weaver、K櫣bler和Weber指数的理论关系式;评价了衍射仪测量条件对结晶度数值的影响和三套伊利石结晶度标样的作用以及成岩带、变质带与葡萄石-绿纤石相、沸石相、绿纤石-阳起石亚相对比的依据。建议(1)停用绢云母一词;(2)建立可供各实验室使用的具有晶体结构和晶体化学参数和多型参数的伊利石结晶度标样;(3)建议多开展规范的可进行国际对比的低温变质研究,划分出与国际上一致的成岩带和近变质带,不仅利于低温变质作用理论的研究,而且由于成岩带到近变质转变带是重要的煤气油的生成带,也利于中国煤气油资源的勘探与开发,利于国民经济的长远持续发展。     

Deformation and metamorphism in the Fenes Nappe (southern Apuseni Mountains,Romania)Déformation et métamorphisme dans la nappe de Fenes (monts Apuseni méridionaux,Roumanie)

The Fenes Nappe belongs to the stack of tectonic units cropping out in the southern Apuseni Mts (Romania). It is characterised by a structural history consisting of two folding phases that developed during the time spanning from Early Aptian to Late Maastrichtian. The D1 phase produced west-northwest-verging, isoclinal to very tight folds, associated to a slaty cleavage. The main metamorphic imprint of the Fenes Nappe is linked to this deformation phase; illite and chlorite ‘crystallinity’ values indicate metamorphic conditions of the late diagenesis, close to the diagenetic zone/anchizone boundary. The subsequent D2 phase produced north-northwest-verging, parallel folds, not associated with synkinematic recrystallisation. These phases are interpreted as developed during a structural path, which includes burial at a depth of 8–10 km, followed by exhumation at shallower structural levels. To cite this article: A. Ellero et al., C. R. Geoscience 334 (2002) 347–354.     

沉积地层中伊/蒙混层粘土矿物的晶体结构晶体化学研究

不规则伊／蒙混层粘土矿物在沉积地层中广泛存在，通过对１７例伊／蒙混层粘土矿物样品进行系统研究得出：（１）沉积地层中的部分有序型伊／蒙混层矿物的晶层连接概率介于完全随机混层与机械混和物的连接概率之间；（２）伊／蒙混层中的蒙皂石晶层向伊利石的转化分两步完成：两层水蒙皂石单层水蒙皂石伊利石；（３）随着成岩作用的进行（埋藏深度增加），Ｉ／Ｓ中的Ｉ晶层含量增加，在此同时，Ｉ／Ｓ晶体结构中四面体片的类质同相代换增加，四面体电荷及总层电荷亦增加，匹配该增加部分电荷的是层间域Ｋ的含量明显增加；（４）在沉积地层中的Ｉ／Ｓ混层矿物中，Ｉ晶层具有白云母的成分特点，层电荷为０．７５左右；Ｓ晶层则具有纳蒙脱石的成分特点，层电荷为０．３０左右     

Ore-forming fluid constraints on illite crystallinity (IC) at Dexing porphyry copper deposit, Jiangxi Province

Illite, a distinctive kind of clay minerals of potassium alteration within the hydrothermal alteration zone, frequently occurs at the Tongchang porphyry copper deposit ore field. The illite crystallinity (IC) value and expandability are mainly affected by water/rock ratio or fluid flux. It was formed by illitization of plagioclase and micas during hydrothermal fluid-rock interaction within the porphyry body and near the contact zone with wall rocks. Moreover, the negative correlation between illite index (IC) and copper grade indicates that within the alteration zone, the smaller the illite crystallinity value, the higher the alteration degree, and the higher the copper grade due to higher water/rock ratio. At lower levels of the porphyry body, however, the illite crystallinity (IC) values are mainly controlled by temperature and time duration.     

镇江下蜀土中的黏土矿物及其古环境意义

镇江大港砖瓦厂下蜀黄土剖面30个样品的X衍射分析和半定量结果表明,该剖面黏土矿物组合为伊利石-蛭石-高岭石型,其中以伊利石（52.8%～70%）和蛭石（20.6%～38.5%）为主;古土壤层的伊利石相对含量高于黄土层,蛭石的变化与之相反,二者互为消长.高岭石含量为6.0%～11.1%,在古土壤中的含量略高于黄土层.从剖面底部（S4）至顶部（S1）, 伊利石相对含量略呈增加趋势,蛭石和高岭石则略呈减少趋势.镇江下蜀黄土中的黏土矿物组合类型与北方黄土明显不同,伊利石的结晶度总体上也较北方黄土差,反映下蜀黄土堆积区相对温暖、湿润,风化淋滤作用相对较强.从黏土矿物组合和含量来看,下蜀黄土经历了中等强度的风化作用.     

Microstructure characteristics of illite from Chuanlinggou Formation of Changcheng System in Jixian County, Tianjin City

The microstructure charateristics of illite from the Chuanlinggou Formation of Changcheng System (Chch) in Jixian County, Tianjin City has been studied by means of high-resolution transmission electron microscopy (HRTEM), selected-area electron diffraction (SAED), X-ray energy dispersive spectrum (EDS) and X-ray powder diffraction (XRD). The Kübler index of "illite crystallinity" is 0.505°△2θ, which indicates that the host rock is in a middle diagenetic stage. The chemical analyses of EDS for illite studied indicate a heavily absent in interlayer cation and an average chemical formula of K0.57(Al1.80Mg0.42Fe2 0.12)Σ=2.34 (Si2.92Al1.08)Σ=4O10(OH)2. It is found, from one-dimensional lattice images, that the layers of illite not only stack in a flat way but also in a curving way. A "matting fabric" illite structure results from stacking faults. Combined with SAED analysis the illite studied can be affirmed as 1M illite. The two-dimensional lattice images are obtained from [100] and [110] incidences, whose lattice images have the same d-values but different intersecting angles. The two-dimensional lattice image with [100] incidence is orthogonal to each other, whilst that with [110] incidence is oblique. This paper provides some important structure information of authigenic clay minerals for the well-known mesoproterozoic section of Jixian County.     

金山金矿K—Ar年龄及其对赣东北构造演化的指示意义

金山金矿位于我国著名的德兴铜金矿集区内，是一个与韧性剪切带有关的金矿床。成矿流体作用过程的水－岩反应产物伊利石K－Ar年龄的测试结果表明，金山金矿地区存在着明显的晚古生代构造热事件，金山金矿的成矿作用与这次热事件活动有关，成矿年龄为269．9－317．9Ma；燕山期岩浆活动对金山金矿的影响不太明显。结合前人的研究成果，认为赣东北地区甚至整个华南地区在海西期不仅有明显的岩浆活动，而且海西期也是一次重要的金矿成矿期。