Reactive transport impacts on recovered freshwater quality during multiple partially penetrating wells (MPPW-)ASR in a brackish heterogeneous aquifer

The use of multiple partially penetrating wells (MPPW) during aquifer storage and recovery (ASR) in brackish aquifers can significantly improve the recovery efficiency (RE) of unmixed injected water. The water quality changes by reactive transport processes in a field MPPW-ASR system and their impact on RE were analyzed. The oxic freshwater injected in the deepest of four wells was continuously enriched with sodium (Na⁺) and other dominant cations from the brackish groundwater due to cation exchange by repeating cycles of ‘freshening’. During recovery periods, the breakthrough of Na⁺ was retarded in the deeper and central parts of the aquifer by ‘salinization’. Cation exchange can therefore either increase or decrease the RE of MPPW-ASR compared to the RE based on conservative Cl⁻, depending on the maximum limits set for Na⁺, the aquifer’s cation exchange capacity, and the native groundwater and injected water composition. Dissolution of Fe and Mn-containing carbonates was stimulated by acidifying oxidation reactions, involving adsorbed Fe²⁺ and Mn²⁺ and pyrite in the pyrite-rich deeper aquifer sections. Fe²⁺ and Mn²⁺ remained mobile in anoxic water upon approaching the recovery proximal zone, where Fe²⁺ precipitated via MnO₂ reduction, resulting in a dominating Mn²⁺ contamination. Recovery of Mn²⁺ and Fe²⁺ was counteracted by frequent injections of oxygen-rich water via the recovering well to form Fe and Mn-precipitates and increase sorption. The MPPW-ASR strategy exposes a much larger part of the injected water to the deeper geochemical units first, which may therefore control the mobilization of undesired elements during MPPW-ASR, rather than the average geochemical composition of the target aquifer.     

围填海对海洋水动力与生态环境的影响

近10年来,中国海岸带围填海活动呈现出规模大、速度快的发展态势。围填海能带来显著的经济效益,但对海洋环境与生态的负面影响也不可忽视。针对围填海对海洋环境和生态的影响及作用机制,分别从水动力和生态系统两个方面进行了概述。围填海改变了海洋的自然几何属性(原始岸线、地形地貌、海湾面积),引起水动力环境的变化(潮汐系统和海湾水交换能力),进而影响了海湾的环境容量;围填海破坏了生物栖息地、导致生物多样性的丧失,影响到生态系统结构与功能的稳定性;水动力与生物多样性的变化可显著影响到生物地球化学过程,加速富营养化进程,恶化水质,增加生态灾害风险。目前,围填海后的生态修复策略主要有增加生物量、建设自然保护区、退陆还海3种方式;而生态补偿策略则多基于“生态系统服务功能与生境面积的大小为线性关系”,通过对其经济价值的量化后进行生态补偿与实施相关政策。国际上,生态系统服务功能的量化参数逐步纳入实际管理,并在线性关系研究的基础上,逐步纳入一些非线性的理念,使生态补偿机制更为合理化;而我国对于围填海生态效应的定量化研究及科学理论在管理政策中的实际应用仍亟待提高。整体而言,全面、准确地评估围填海对海洋环境与生态的影响离不开自然科学与社会科学的交叉与融合。     

Very high CO2 exchange fluxes at the peak of the rainy season in a West African grazed semi-arid savanna ecosystem

Africa is a sink of carbon, but there are large gaps in our knowledge regarding the CO₂ exchange fluxes for many African ecosystems. Here, we analyse multi-annual eddy covariance data of CO₂ exchange fluxes for a grazed Sahelian semi-arid savanna ecosystem in Senegal, West Africa. The aim of the study is to investigate the high CO₂ exchange fluxes measured at the peak of the rainy season at the Dahra field site: gross primary productivity and ecosystem respiration peaked at values up to ?48 μmol CO₂ m^?2 s^?1 and 20 μmol CO₂ m^?2 s^?1, respectively. Possible explanations for such high fluxes include a combination of moderately dense herbaceous C4 ground vegetation, high soil nutrient availability and a grazing pressure increasing the fluxes. Even though the peak net CO₂ uptake was high, the annual budget of ?229 ± 7 ± 49 g C m^?2 y^?1 (±random errors ± systematic errors) is comparable to that of other semi-arid savanna sites due the short length of the rainy season. An inter-comparison between the open-path and a closed-path infrared sensor indicated no systematic errors related to the instrumentation. An uncertainty analysis of long-term NEE budgets indicated that corrections for air density fluctuations were the largest error source (11.3% out of 24.3% uncertainty). Soil organic carbon data indicated a substantial increase in the soil organic carbon pool for the uppermost .20 m. These findings have large implications for the perception of the carbon sink/source of Sahelian ecosystems and its response to climate change.     

用化石天长计算地球年龄的方法及意义——如何理解地球年龄

天长（一天时长）是地球自转速度的直接反映。古生代-中生代化石记录的天长数据表明,古生代-中生代期间的天长随时间呈线性增加。根据角动量守恒定律,这意味着同时段地球自转速度呈线性衰减。如果把这个趋势应用于地球历史的全过程,计算结果为4.519～4.495 Ga,与目前公认的地球绝对年龄4.54 Ga一致。这意味着,从这个时间点起,地球有一种自转速度衰减的总趋势。地球自转速度衰减年龄等值于地球年龄说明：1）所测量的陨石样本生成的时间（表征地球年龄）与地球受月球吸引形成自转减速的时间几乎相同。这意味着地-月体系形成之前的地球比该陨石表征的地球年龄更为古老。2）地球、月球、自转速度衰减时长,三者的年龄呈现等值状态,因而此结果与月球起源于大碰撞的假说可以匹配。     

Early growth fault activity: new evidence for extension in the upper Cambrian Owen Group,Proprietary Peak,western Tasmania,Australia

The coarse-grained, upper Cambrian Owen Group of western and northern Tasmania is a prominent feature of the Tasmanian landscape and regional map series. The group has previously been divided into four informal formations (Lower Owen Conglomerate, Middle Owen Sandstone, Middle Owen Conglomerate and Upper Owen Sandstone) that have been correlated across the state over tens to hundreds of kilometres. The deposition of these sediments is largely believed to have occurred during extensional tectonics, but some authors continue to argue a compressional tectonic regime. Detailed mapping and sedimentological work around Proprietary Peak on the Mount Jukes massif, 10 km south of Queenstown, Tasmania, has identified significant depositional variations controlled by early growth faulting and paleotopography. Discontinuity of stratigraphic units (L6–L13) across two growth faults on the north face of Proprietary Peak shows the strong effect on sediment deposition in the area. Paleotopography is also evident with most stratigraphic units (L8–L13 and U1) gradually onlapping basement during their deposition. Significant paleotopography has also been identified on East Jukes Peak, where lower Owen Group sedimentary units onlap basement volcanics, with no evidence for tectonically controlled deposition. Field evidence strongly supports the deposition of the Owen Group during extensional tectonics, after a period of prolonged erosion of the underlying Mount Read Volcanics. The distinct variation in vertical and lateral extent of stratigraphic units within the Owen Group in the Proprietary Peak area suggests that widespread lithostratigraphic correlation of older Owen Group sedimentary units across Tasmania may not be feasible.     

水库运行对漫湾库区洲滩水热交换影响

以澜沧江漫湾水库库区洲滩为研究对象,依据水库运行导致的水位波动特征,同步监测洲滩内部水位、水温变化过程,核算洲滩侧向潜流交换量,建立水温与水位之间的响应关系,分析潜流交换水流路径上溶解氧、溶解性碳素变化。结果表明:水库运行引起洲滩水位周期性波动,侧向潜流交换加强,洲滩水位最大变幅达2.2 m,水库一次蓄泄过程进出洲滩的水量达3 956 m^3,洲滩边缘区潜流交换量为中心区的4~5倍;在涨水过程中,洲滩水温下降,中底层温度梯度较大,而在落水过程中,洲滩水温上升,中表层温度梯度较大;溶解氧、溶解性有机碳和无机碳在河流至洲滩潜流交换路径上同步递减,分别从3.27 mg/L、7.3 mg/L和66.0 mg/L下降至0.17 mg/L、2.4mg/L和40.6 mg/L。水库运行导致的水位波动加强了库区洲滩潜流交换,对河流物质循环产生潜在影响。     

一次攀西地区飑线天气过程形成机制分析

利用地面气象常规观测资料、区域自动站观测资料、雷达及卫星资料和NCEP 1°×1°的逐6h再分析资料,对2018年5月13日攀西地区南部的飑线天气过程的形成机制进行分析。结果表明:飑线发生在高空槽前,高空槽逐渐东移推动冷性气流沿背风坡东移,然后与前方低层暖空气汇合抬升形成对流;露点锋触发了飑线天气过程的形成;产生飑线天气区域的大气具有上干下湿、不稳定能量高、垂直风切变强、高层风速大和形成之前存在逆温层的特点;高空急流和动量下传对飑线的发生和加强具有促进作用;地形对飑线的形成和天气现象的分布有影响。     

一次强飑线过程极端大风的中尺度分析

利用常规气象观测资料、区域自动气象站加密观测资料和GFS 0.25°×0.25°逐6 h的分析场数据以及多普勒雷达、风廓线等资料,通过背景形势场分析、物理量诊断分析和中尺度分析,对2018年3月4日发生在华东地区的强飑线天气过程进行了诊断分析。结果表明,这次过程具有发生时间(季节)早、移速快、范围广、致灾强等特点,是一次比较少见的早春(冬末)十分强烈的飑线天气过程,是在高空急流辐散区、低空西南急流轴前端、低涡南侧的暖区中发展起来的。飑线过程的地面要素变化十分剧烈,地面有强冷池,与飑线前暖空气之间构成了强的水平温度梯度,致使飑线强度更强;飑线经过时气压涌升所形成的雷暴高压、强气压梯度以及飑线的快速移动均有利于地面极端大风的出现。飑线发展过程中观测到弓形回波、超级单体等强天气系统。中高层动量下传和光滑湖面、喇叭口、狭管效应等特殊地形对于大风的增强效应比较显著,这些因素也加剧了地面极端大风的形成。      

Comparison of ecophysiological characteristics between introduced and indigenous mangrove species in China

Due to its rapid growth, the introduced mangrove species Sonneratia apetala from Bangladesh has been widely used in mangrove restoration in southeastern China since 1985. As an indigenous mangrove species in Hainan, China, Sonneratia caseolaris was also planted in Guangdong Province for afforestation purposes. Both species have developed well in their new habitats, but their ecophysiological differences with the native mangrove species have not been studied. In this study, leaf gas exchange, water and nitrogen use efficiencies of two Sonneratia species were compared with those of selected native mangrove species (Avicennia marina, Aegiceras corniculatum, Kandelia candel, and Excoecaria agallocha) in Hainan and Shenzhen. The introduced S. apetala maintained lower carbon assimilation rate (A) and photosynthetic nitrogen use efficiency (PNUE) than the indigenous S. caseolaris. In Shenzhen, the two introduced Sonneratia had comparable photosynthetic rates and water use efficiency (WUE) with the native mangrove species, except that PNUE in S. caseolaris was significantly higher than in the native mangrove species. The two Sonneratia species showed significant overlap in PNUE and long-term WUE. Photosynthetic parameters derived from leaf photosynthetic light–response curves and A–C_i curves also suggested lower carbon assimilation capacities for the introduced Sonneratia than for the native mangrove species in both study sites. The lower light compensation point (LCP) of two introduced Sonneratia in both study sites also indicated a better adaptation to a low light regime than the native mangrove species. The results of photosynthetic capacities indicated that the introduced mangrove species have little competitive advantage over local native mangrove species in their respective new habitats.     

pCO2 and carbon fluxes across sea-air interface in the Changjiang Estuary and Hangzhou Bay

Partial pressure of CO2(pCO2) was investigated in the Changjiang(Yangtze River) Estuary,Hangzhou Bay and their adjacent areas during a cruise in August 2004,China.The data show that pCO2 in surface waters of the studied area was higher than that in the atmosphere with only exception of a patch east of Zhoushan Archipelago.The pCO2 varied from 168 to 2 264 μatm,which fell in the low range compared with those of other estuaries in the world.The calculated sea-air CO2 fluxes decreased offshore and varied from -10.0 to 88.1 mmol m-2 d-1 in average of 24.4 ± 16.5 mmol m-2 d-1.Although the area studied was estimated only 2 × 104 km2,it emitted(5.9 ± 4.0) × 103 tons of carbon to the atmosphere every day.The estuaries and their plumes must be further studied for better understanding the role of coastal seas playing in the global oceanic carbon cycle.