A Review of the Scientific Assessment and Research on Household Carbon Emission

Household consumption represents an important proportion of all energy consumption,and it is an important source of CO₂ emission. But household consumption and carbon emissions are often overlooked in climate change policies and measures. Through literature review, the research status of household consumption and carbon emissions were reviewed. On this basis, the main aspects and directions of the research are summarized and the main research of household carbon emissions should focus on three aspects in the future: ①The impact of income, consumption levels and other factors on household carbon emission; ②The relationship between direct and indirect carbon emissions of household carbon emission; ③The structure and source of household carbon emission. In future research, there are four issues which need in-depth study: ①Index and models study of household carbon emissions;②Impact of demographic change on household carbon emissions; ③The path of how to achieve sustainable and green urban lifestyle;④The relevant policy research of household carbon emissions.     

Low temperature volatile production at the Lost City Hydrothermal Field, evidence from a hydrogen stable isotope geothermometer

Although commonly utilized in continental geothermal work, the water-hydrogen and methane-hydrogen isotope geothermometers have been neglected in hydrothermal studies. Here we report δD-CH₄ and δD-H₂ values from high-temperature, black smoker-type hydrothermal vents and low-temperature carbonate-hosted samples from the recently discovered Lost City Hydrothermal Field. Methane deuterium content is uniform across the dataset at − 120 ± 12‰. Hydrogen δD values vary from − 420‰ to − 330‰ at high-temperature vents to − 700‰ to − 600‰ at Lost City. The application of several geothermometer equations to a suite of hydrothermal vent volatile samples reveals that predicted temperatures are similar to measured vent temperatures at high-temperature vents, and 20-60 °C higher than those measured at the Lost City vents. We conclude that the overestimation of temperature at Lost City reflects 1) that methane and hydrogen are produced by serpentinization at > 110 °C, and 2) that isotopic equilibrium at temperatures < 70 °C is mediated by microbial sulfate reduction. The successful application of hydrogen isotope geothermometers to low-temperature Lost City hydrothermal samples encourages its employment with low-temperature diffuse hydrothermal fluids.     

油气管道穿越黄土冲沟的管线设计参数研究

长输油气管道经过黄土冲沟边坡时常常采用斜井穿越的方式,采用数值强度折减法与实际地形建模结合的方法,以陕西千阳黄土冲沟边坡为例,通过对黄土力学参数的不断折减,以收敛性准则作为边坡是否产生滑动的破坏判据,根据边坡滑动时的位移等值线图确定了边坡潜在滑动面的形状及位置,确定了管线穿越斜井的初始安全设计参数;基于初步设计参数研究了管线斜井开挖过程中井周土体的位移变化规律,并对斜井开挖后黄土冲沟边坡的稳定性安全系数进行了进一步分析计算。分析结果表明,所给出的管线穿越斜井设计参数的确定方法,能在设计阶段有效避开冲沟边坡潜在滑动区,基于这种设计参数使得管道斜井施工对边坡稳定性影响很小,边坡安全系数由1.162变为1.156,变化不大。根据计算结果,对斜井支护区域也提出了合理的建议。     

Impact of Changes in Redox Conditions on Leaching of Some Elements from MSW Fly Ash

Abstract. Oxidation and reduction processes can influence extent of leaching of elements from solid waste. Three samples of municipal solid waste combustion fly ash were subjected to oxidizing and reducing conditions in order to evaluate leaching of elements in the Milli-Q water and fly ash (liquid to solid ratio, 100) mixtures. Although the oxidizing and reducing conditions were applied for 6 hours only, elements like Cs, Li, Mg, Sb, Tl and V leached more under oxidizing condition than under reducing condition in the case of all three ash samples. Cadmium, Pb and Zn leached more from all samples under reducing condition than under oxidizing condition. Leaching of other elements like Al, Ba, Cr, Cu, Ni and Rb was inconsistent with oxidizing or reducing conditions and varied from sample to sample, suggesting that factors other than redox may be more important in controlling leaching of these elements. Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions.     

基于离散元的强度折减法分析岩质边坡稳定性

将通用离散元UDEC与强度折减法结合,对含多结构面的岩质边坡的稳定性进行了分析。通过对节理岩质边坡的UDEC模型中的可变形块体和节理单元的强度参数进行折减,使模型不能再达到平衡状态,此时的折减系数就是边坡的安全系数,另外,由对应的边坡块体的速度矢量可以确定滑动面和边坡的破坏形态。通过与传统的条分法的结果比较,表明基于UDEC的强度折减法是一种可靠、有效的方法,为复杂节理岩质边坡的滑动面确定与安全系数计算开辟了新的途径。     

邻苯二酚螯合树脂的合成及水样中铝的测定

合成并表征了新螯合树脂———邻苯二酚螯合树脂(XAD-2-Catechol),研究了XAD-2-Catechol吸附铝的特性和茜素红-铝的显色反应,在pH4.5的HAc-NaAc缓冲介质中,茜素红和铝(Ⅲ)反应生成红色络合物,λm ax=500 nm,铝的含量在0-50μg/25 mL内符合比耳定律。建立了邻苯二酚螯合树脂分离/富集-茜素红分光光度法测定天然水样中铝的新方法,对水样中铝形态进行测定,结果满意。     

大洋粘土制备白炭黑后的铝回收实验研究

为了回收大洋粘土制备白炭黑后残液中的Al3 ,并获得氧化铝超细粉体,实验选用NH3.H2O为沉淀剂,在常温下采用沉淀法使残液中Al3 以氢氧化铝形式沉淀并去除其它杂质离子,然后将得到的沉淀在1200℃灼烧,保温1h。利用IR和XRD测试了产物的物相组成和结构,证实实验可以获得纯度较高的α-Al2O3;而SEM和粒度分析结果显示产物粒度细小,部分颗粒可以达到纳米级;BET结果显示Al2O3的比表面积可达32m2/g。根据氧化铝结构和性能等优选的实验条件为大洋粘土的进一步开发利用提供了参考依据。     

层状岩质边坡遍布节理模型的三维稳定性分析

采用遍布节理模型（ubiquitous-joint模型）描述层状岩体的各向异性特征,并探讨ubiquitous-joint准则中安全系数的计算方法,利用FLAC3D分析层理倾角、倾向与边坡稳定性之间的关系,结果表明：（1）对于顺层边坡,当岩层倾向与坡面倾向的夹角 较小时,边坡的安全系数随层理倾角 的增大呈现先减小后增大再减小的趋势; 20°～30°时,安全系数得到最小值, 60°时安全系数得到最大值;不同破坏型式导致安全系数变化规律之间的差异;当 较大时,曲线从先减小后增大的趋势转变为不断增大的趋势;根据 的大小将顺层边坡分为两类：当 45°时,为严格顺层边坡;当45° 90°时,为斜向层状边坡。（2）对于逆层边坡,当 45°时,曲线呈现先增大再减小然后又增大的趋势,各曲线随 的变化程度基本相同;但减小过程中,随着 的增大,曲线的斜率逐渐减小,边坡稳定性的各向异性程度减小;当 45°时,曲线随 的增大呈现非线性单调递增的趋势。（3）安全系数与 之间的关系表明,对于顺层坡,随着 的增大,边坡安全系数逐渐增大;对于逆层坡,当 较小时( 150°),边坡安全系数随 的增大而逐渐减小;随着 的增大( 120°),边坡安全系数与 呈现递增关系。     

边坡稳定临界破坏状态的动力学评判方法

针对目前用有限单元法分析边坡稳定时,对临界状态判别存在的一些问题和不足,提出了边坡稳定临界破坏状态的动力学评判方法。该方法以加速度是否为零作为边坡是否稳定的判据,同静力方法相比,具有物理意义明确,计算易收敛等优点。在分析滑动本质的基础上,提出通过搜索剪应变最大的点以确定临界滑裂面的方法。算例证明了临界状态动力学评判方法的可靠性。     

Diagenetic paths in the margin of a Triassic Basin: NW zone of the Iberian Chain, Spain

Buntsandstein deposits generated in a slowly subsiding basin on the western margin of the Iberian Chain are represented by a stratigraphic succession of fluvial deposits less than 100 m thick (conglomerates, sandstones, and shales). Diagenetic processes in sandstones can be grouped as eodiagenetic, mesodiagenetic, and telodiagenetic. Eodiagenesis can be associated with Muschelkalk, Keuper, and probably early Jurassic times. Mesodiagenesis is probably related to Jurassic times. Diagenetic chemical reactions suggest a maximum burial less than 1.5 km and low temperatures (<120°C). Patterns of porosity reduction by compaction and cementation suggest four diagenetic stages: (1) Loss of primary porosity by early mechanical compaction; (2) early cementation (K-feldspar and dolomite); (3) dissolution of cements; and (4) framework collapse by re-compaction. These stages are manifested by the presence of two types of sandstone. Type I sandstones present high intergranular volume (mean, 30%). Type II sandstones are characterized by high compactional porosity loss and exhibit low values of intergranular volume (mean, 16.9%). Type II sandstones are associated with the dissolution of cement and later re-compaction of type I sandstones. An intermediate telodiagenetic phase is deduced and related to the sharp unconformity between Lower Cretaceous sediments and the underlying sediments. This suggests that a mechanically unstable framework collapsed during the Cretaceous, generating type II sandstones. The analyzed diagenetic paths have a wide applicability on similar marginal areas of rift basins.