Pressurised Extraction Using Dilute Ammonia: A Simple Method for Determination of Iodine in Soil, Sediment and Biological Samples by Inductively Coupled Plasma-Mass Spectrometry

A simple sample treatment method for the accurate and precise determination of iodine in soil, sediment and biological samples by inductively coupled plasma-mass spectrometry (ICP-MS) is described. Iodine in samples was extracted in screw top PTFE-lined stainless steel bombs using a 10% v/v ammonia solution at 185 C for 18 hours (overnight), after which the extract was introduced into the ICP-MS for direct measurement. ¹²⁶Te was employed as the internal standard to compensate for matrix effects and instrument drift. The limit of detection (LOD, three times the standard deviation of the procedural blank solution, expressed as the concentration in the sample solution) was 0.003 ng ml-^-1. The limit of quantitation (LOQ, ten times the standard deviation of the procedural blank solution, expressed as the concentration in the solid samples, dilution factor DF = 100) was 0.01 μg g-^-1 (dry mass). The accuracy and precision of the method were demonstrated by analysing different Chinese geological certified reference materials (soils, stream sediments and a hair sample). The measured concentrations were in a good agreement with the certified values indicating that bias in the method was not significant. The precision (n = 10) for different concentrations ranged from 1.82% to 4.32% RSD. Comparison of the ammonia extraction procedure with a "sintering" method indicated that there was no significant difference in results obtained with the two methods for geological soil and stream sediment samples. However, for biological samples, such as hair, kelp, tea etc., the results obtained by the sintering method were far below those of the ammonia extraction method. The ammonia extraction has advantages, as it is simpler than the "sintering" method, and has a lower procedural blank, better detection limits and reproducibility. Due to the simplicity of the method, a high rate of sample throughput is possible.     

Towards a lower mantle reference temperature and composition

We aim to constrain the lower mantle geotherm and average composition from 1D seismic models and experimental mineralogy data, explicitly accounting for possible sources of uncertainty. We employ an isentropic third-order Birch-Murnaghan equation of state, which is in excellent agreement with recent ab initio calculations of density and bulk modulus for Mg-perovskite. Furthermore, ab initio and experimental data are reasonably consistent with each other. Modelling the shear modulus is not as straightforward, but is needed because density and the bulk modulus alone do not sufficiently constrain temperature and composition. To correctly predict ab initio calculations for the shear modulus of Mg-perovskite, we needed to prescribe a cross-derivative at zero pressure, which we determined by trial and errors. Unless this ad hoc cross-derivative is confirmed by further experimental results, there seems to be an inconsistency between ab initio and experimental data. Purely experimental data most likely require a non-adiabatic temperature profile, but it is difficult to infer the number and location(s) of the non-adiabatic increase(s). If ab initio data are used, at least one thermal boundary layer seems reasonable, but its location depends on the modelling of the iron content. A strong chemical density contrast in the mid-mantle (≥2%) is not supported by ab initio data, but is possible with experimental data. Other major sources of uncertainty are the trade-off between thermal and compositional effects, the possible influence of aluminium perovskite, and poorly understood frequency effects.     

双星姿态测量的算法及双值问题

给出了双星姿态测量的两种算法，并从几何和代数两个方面证实其存在双值问题；探讨了双值问题与精度衰减因子(DOP)之间的关系，并提出了双值问题的解决方案。     

辽河断陷古潜山古生界的厘定及其地质意义

辽河断陷以碳酸盐岩和砂页岩为主的古潜山地层一直全部划归中、新元古界。由于在该套地层的部分岩石薄片中发现交代残余的动物化石碎片，因此提出辽河断陷有古生界存在的新观点。通过牙形石、微古植物、动物化石和岩性组合的研究，对这套地层进行了重新厘定，建立了古生代寒武纪、奥陶纪、石炭纪和二叠纪地层层序。研究成果表明，辽河断陷存在古生界储层，古生代潜山并非单斜．而是由被断裂改造的褶皱组成的断块。这一成果为重新认识潜山的内幕构造特征和油气储层分布规律奠定了基础。     

A study on the preparation of fine and low soda alumina

A simple process to produce fine and low soda α-alumina (α-Al₂O₃) from a commercial grade aluminium trihydroxide (gibbsite, Al(OH)₃) produced by KC Corporation Ltd was developed. There are two options for this process with the first one producing low soda α-alumina (< 0.05% Na₂O) having a mean particle size of 50 μm. The second option yields a fine product with a mean size of less than 10 μm. In the first option, a plant aluminium trihydroxide containing 0.20% Na₂O was first fluidized with nitrogen at 400–600 °C to yield an amorphous activated alumina. This intermediate product was then treated with acetic or oxalic acid, washed with water and heated to 1200 °C to form calcined α-alumina, having a Na₂O content of less than 0.05%. A 20 min leaching using 0.2 M acetic or oxalic acid could yield an alumina product containing 0.04% Na₂O. In the second option, a new technique for the preparation of fine and low soda α-alumina was evaluated using an attrition mill working also as a leaching vessel at 80 °C. Fine (< 10 μm in mean particle size) and low soda (< 0.04% Na₂O) alumina was produced by a 20 min leaching step with 0.2 M acetic acid and concurrent attrition milling.     

百色机场大型地接地电阻测试经验与总结

对百色机场大型地网接地电阻进行了认真的测试，通过分析比较，选出正确的测试方法和仪器，确保测试结果的准确，并作了经验总结。     

VLBI在GEO卫星精密定轨中的应用

影响GEO轨道确定精度的原因主要有两方面:一是高轨卫星的几何跟踪条件受到局部测轨网的限制;二是卫星相对于地面的动力学约束信息较弱。利用一个针对GEO卫星的简化动力法定轨的协方差分析模型,研究了联合测距跟踪网和甚长基线干涉测量(VLBI)对定轨精度的改善情况。指出测距系统的校正误差是常规测距跟踪网定轨精度的主要误差源;当附加一条东西向VLBI基线时,仅利用不定期的少量VLBI高精度数据就能够显著改善测距偏差对轨道的影响,从而保证了卫星的整体位置解算精度。     

额济纳旗胡杨根区水分运动参数的确定--利用Richard方程和气象资料推算

利用Richard方程和气象资料相结合的办法,确定了中国典型的干旱内陆河流──黑河下游额济纳旗地区主要成林的干旱荒漠天然乔木树种──胡杨林地的水分运动参数,主要有导水系数K、比水容量C和水分扩散率D。     

河北地区地震类型的地理分布及其在首都圈工程应急系统中的应用

对河北地区（含京、津）历史地震类型的地理分布特征进行了初步分析,在首都圈防震减灾示范区系统工程“地震应急快速响应系统”建设中,根据历史地震类型的区域分布特征,充分利用计算机与网络技术的优势,实现了当前地震类型的准实时快速判定与上网发布,为抗震求灾和进一步分析研究提供一个及时的参考意见。