低温条件下长石溶解模拟实验研究

为了研究有机酸和无机酸对长石的溶解能力以及不同有机酸对长石溶解能力的差异,笔者等在80℃条件下,在不同pH值（4、6和8）的分别含有盐酸、乙酸和草酸的溶液中,对碱性长石和斜长石进行了溶解模拟实验研究。实验结果表明：酸性(pH=4)和弱酸性(pH=6)条件下,乙酸对两种长石的溶解能力大于草酸,碱性条件(pH=8)下草酸的溶解能力最大,无论在酸性或碱性条件下,有机酸对长石的溶解能力均高于无机酸,酸性(pH=4)条件下,斜长石与碱性长石溶解量差别不大,在弱酸性(pH=6)和碱性(pH=8) 条件下,斜长石的溶解量高于碱性长石。     

江苏省东海县片麻状碱性花岗岩的成因及年代学研究

江苏省东海地区位于苏鲁造山带的西南缘,区内广泛出露片麻状碱性花岗岩.本文对东海地区磨山、虎山和房山片麻状碱性花岗岩的产状、岩石结构构造、碱性铁镁矿物、元素地球化学和锆石成因及SHRIMP定年等综合研究结果表明：该类岩石具有高硅、富碱、富铁贫镁和含碱性铁镁矿物等特征,说明其为碱性花岗岩;岩体还保留有沉积岩特有的层理（走向北东、倾向南东等一致的产状）,长石等造岩矿物显示在固相条件下结晶的特征,以及继承锫石大部分是不同时代的岩浆或变质锆石碎屑等,均证实其原岩是沉积岩.SHRIMP定年对变质锆石的边部获得两组₂₀₆Pb-₂₃₈U加权平均年龄,分别为224.7±9.4 Ma和209.4±2.5～212±3.5Ma,反映了东海片麻状碱性花岗岩成岩时间属于印支期,相当于晚三叠世,变质锆石的核部₂₀₆Pb-₂₃₈U年龄变化于866～248 Ma,反映原岩时代不会早于晚古生代.     

内蒙古敖汉旗早三叠世正长花岗岩锆石U-Pb年代学、地球化学特征

正近些年研究显示华北地台北缘存在一条近东西向展布的早三叠世后造山的花岗岩带,在吉林东部,内蒙古中部及西部地区具有发现,但在赤峰敖汉旗地区还未见报道。本次工作在敖汉旗区域地质调查过程中,从原来侏罗纪岩体中重新厘定出一套正长花岗岩,本文对其年代学及地球化学进行介绍,以探讨华北地台北缘中段-东段过渡带的古亚洲洋闭合时限。     

Ordovician Granitoids and Silurian Mafic Dikes in the Western Kunlun Orogen, Northwest China: Implications for Evolution of the Proto-Tethys

The western Kunlun orogen in the northwest Tibet Plateau is related to subduction and collision of Proto-and Paleo-Tethys from early Paleozoic to early Mesozoic. This paper presents new LA-ICPMS zircon U-Pb ages and Lu-Hf isotopes, whole-rock major and trace elements, and Sr–Nd isotopes of two Ordovician granitoid plutons(466–455 Ma) and their Silurian mafic dikes(～436 Ma) in the western Kunlun orogen. These granitoids show peraluminous high-K calcalkaline characteristics, with(⁸⁷Sr/⁸⁶Sr)_i value of 0.7129–0.7224, ε_Nd(t) values of -9.3 to -7.0 and zircon ε_Hf(t) values of -17.3 to -0.2, indicating that they were formed by partial melting of ancient lower-crust(metaigneous rocks mixed with metasedimentary rocks) with some mantle materials in response to subduction of the Proto-Tethyan Ocean and following collision. The Silurian mafic dikes were considered to have been derived from a low degree of partial melting of primary mafic magma. These mafic dikes show initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7101–0.7152 and ε_Nd(t) values of -3.8 to -3.4 and zircon ε_Hf(t) values of -8.8 to -4.9, indicating that they were derived from enriched mantle in response to post-collisional slab break-off. Combined with regional geology, our new data provide valuable insight into late evolution of the Proto-Tethys.     

内蒙古扎鲁特旗巴尔哲超大型矿床控矿因素分析

内蒙古巴尔哲矿床不仅是超大型的REE-Zr-Nb-Ta-Be多金属矿床,同时也是大型的U-Th矿床。通过野外地质观察、地面伽玛能谱测量、岩矿鉴定和室内数据处理等,发现铀、钍主要以类质同像的形式存在于矿石矿物中;铍和稀土元素的独立矿物以羟硅铍钇铈矿和独居石为主;铌、钽、锆主要赋存在铌铁矿、烧绿石和锆石中。另外,从构造、岩性及蚀变特征三方面,对巴尔哲矿床的控矿因素进行了详细解剖,研究表明,巴尔哲矿床的铀钍矿化与稀有稀土矿化密切共生,均赋存于强蚀变钠闪石花岗岩中,蚀变主要为钠长石化和硅化。该矿床主要受构造和碱性花岗岩体的控制,是构造和碱性花岗质岩浆演化的耦合产物。      

Inland saline lakes of Wadi El Natrun depression, Egypt

The morphology and geochemistry of saline lakes in the Wadi El Natrun depression were studied. All lakes had pH values of 8.5--9.5 and a salinity from 283 to 540 g/L. The main ionic components were sulphate, chloride, carbonate and sodium. Traces of magnesium were also present. The water of the lakes is of the Cl^– to SO ₄ ^2– -Cl^– type. Increased Cl^– in Wadi El Natrun brines can increase metal solubility due to the formation of soluble chloro-complexes of trace elements. The metal concentrations decrease in the order: Pb > Cu > Cd > Ni > Zn > Fe > Mn. The characteristics of Wadi El Natrun saline lakes are compared with those from other saline lakes.     

河北省赤城县赵家沟金矿成矿地质条件及找矿方向初探

该矿床产于尚义-赤城深断裂南侧之水泉沟正长岩外接触带中。区内主要地层为桑于群第二岩段,原岩为一套中基一中酸性火山熔岩,含金量平均为46×10^-9。矿体主要受控于东西向断裂带中,该带既为导矿构又是容矿构造。矿体具垂直分带特点。即地表为石英脉型,往深部渐变为蚀变岩型。区内赵家沟正长岩属于印支期水泉沟碱性杂岩体东延部分,含金量平均为22.2×10^-9;赵家沟金矿床形成与该岩体密切相关,岩体外接触带是本区找矿的有利地段。     

Triassic alkaline intrusives in the Yanliao-Yinshan area: their chronology, Sr, Nd and Pb isotopic characteristics and their implication

Dated isotopic ages for 15 alkaline intrusives in the Yanliao-Yinshan area, ranging from 268 to 190 Ma, ten of which are from 250 to 208 Ma, indicate that most of them were formed in the Triassic Epoch. All the E_Nd(t) ratios from - 17.19 to -3.21 averaging -7.09, the E_Sr(t) ratios fmm 11.7 to71.5 averaging 36.63, and the I_sr(t) ratios from 0.705 0 to 0.709 3 averaging 0.706 8, show their characteristics of enrichment. On the E_Nd (t) virus E_Sr(t) correlation diagram, the samples from these intmsives were plotted within the enriched mantle trend lines and just outside, demonstrating their close connection to materials from the enriched mantle reservoir, taking into account the same Pb isotopic composition as that of the mantle.     

免疫多糖对栉孔扇贝酸性磷酸酶、碱性磷酸酶和超氧化物歧化酶活性的影响

在栉孔扇贝的血清、血细胞和肝脏提取液中均发现有酸性磷酸酶（ＡＣＰ）、碱性磷酸酶（ＡＬＰ）和超氧化物歧化酶（ＳＯＤ）活性,其中,ＡＣＰ和ＡＬＰ在肝脏中的活性最高。采用１．０％的虫草多糖或海藻多糖作为免疫药物,对栉孔扇贝进行注射刺激后,发现血清中的ＡＣＰ、ＡＬＰ和ＳＯＤ活性有显著提高,血细胞中的ＡＣＰ和ＳＯＤ活性也有所增加,而肝脏提取液的这三种酶活性的变化不很明显。研究认为这两种多糖具有增强栉孔扇贝免疫活性的作用,在水产养殖业中有一定的开发价值。     

华北克拉通西部临县紫金山碱性岩体地球化学特征及地质意义

山西吕梁地区出露的紫金山岩体为我国著名的碱性岩体之一。为了探讨紫金山碱性岩体的物质来源及地质意义,对该岩体主要岩石进行了岩相学及岩石地球化学研究。结果表明: 紫金山岩体各期次岩石具有低硅、富碱、高钾的特点,属钾质碱性岩石; 岩石轻重稀土元素分馏较强烈,具有轻稀土相对富集、重稀土相对亏损、无明显Eu异常的特征; 微量元素总体表现为大离子亲石元素(Rb、Ba、K、Sr等)明显富集、高场强元素(Th、Nb、Ta、La、Ce、Nd、P、Ti等)亏损的特征。紫金山岩体岩浆来源较深,与富集地幔关系密切,岩浆演化机制以部分熔融作用为主且存在陆壳物质混染。结合山西境内多处同时期的碱性、偏碱性岩体特征,推断华北中部早白垩世碱性岩浆活动与古太平洋板块俯冲背景下华北克拉通破坏作用关系密切。