中国大陆科学钻探工程主孔（734～933m）榴辉岩和片麻岩元素及Sr-Nd同位素地球化学研究

对中国大陆科学钻探工程主孔两段榴辉岩与片麻岩互层的岩芯样品(Ⅰ:734.21-737.16m和Ⅱ:929.67-932.86m)分别进行了主要元素和微量元素以及Sr-Nd同位素分析。结果表明:(1)榴辉岩具有较大的成分变化范围(SiO2含量为46.8%-59.8%),表现出平坦或轻稀土(LREE)富集的分布模式和大离子亲石元素(LILE)富集或亏损以及Nb、Ta负异常特征。部分榴辉岩样品具有明显低的活动性元素(Rb、Ba和K)含量,指示了板块俯冲过程中的脱水变质效应;(2)两段岩芯中的片麻岩具有明显不同的主量和微量元素组成,其中第Ⅰ段具有相对较低的SiO2含量(61.3%～66.2%)和高的重稀土(HREE)含量,而第Ⅱ段具有明显偏高的SiO2含量(73.8%～74.1%)和低的HREE含量。但两段均表现出LREE富集和Eu负异常以及LILE富集和高场强元素(Nb、Ta、Ti)负异常特征;(3)榴辉岩和第Ⅰ段岩芯中的片麻岩具有相近的且偏高的εNd(750Ma)值(-3.6- 0.5),而第Ⅱ段岩芯中的片麻岩具有明显偏低的εNd(750Ma)值(-8.7)。部分片麻岩样品表现出较高的87Sr/86Sr比值(0.7070)和非常低的Rb/Sr比值(0.008),指示岩石Rb-Sr同位素体系受到了变质扰动。非活动性元素如Zr、Hf、Nb、Ta、Ti、Y、REE和Ti在脱水变质过程中没有受到明显扰动,因此可用于恢复榴辉岩和片麻岩的原岩性质及其形成的大地构造背景。根据分析样品的元素和Nd同位素特点,推测榴辉岩原岩具有板内玄武岩性质,第Ⅰ段岩芯中的片麻岩原岩为玄武质岩浆上升过程中同化地壳物质形成的中性岩,而第Ⅱ段岩芯中的片麻岩原岩为地壳物质重熔形成的酸性岩。因此,深钻榴辉岩和片麻岩原岩为新元古代华南陆块北缘裂谷构造带双峰式岩浆活动的产物,在岩浆侵位过程中经历了高温大气降水热液蚀变。     

西准噶尔蛇绿混杂岩中洋岛玄武岩研究新进展

洋岛玄武岩(OIB)起源研究是当代固体地球岩石学及地球化学最基本问题之一,通常被认为源于地幔柱。西准噶尔位于中亚造山带的西南缘,该地区发育多条蛇绿混杂岩带,主要包括唐巴勒、玛依勒、达尔布特及克拉玛依蛇绿混杂岩带,它们组成相似,主要为蛇纹岩、蛇纹石化方辉橄榄岩、二辉橄榄岩、纯橄岩、铬铁矿、辉石岩、辉长岩、辉绿岩、玄武岩(拉斑质和碱性)、硅质岩及斜长花岗岩。随着研究的不断深入,在西准噶尔蛇绿混杂岩带中不断有不同时代OIB被识别。这些玄武岩属于碱性玄武岩系列,具有高TiO2和FeOt,低MgO,强烈富集轻稀土元素特征,没有明显Nb、Ta负异常,与日喀则及夏威夷洋岛玄武岩地球化学特征极为相似,可能形成于大洋板内的海山或洋底高原,认为其成因与地幔柱相关,表明在西准噶尔(洋)的演化过程中,不仅是洋内俯冲系统,还伴有地幔柱活动。结合前人研究,认为中亚造山带可能是洋内俯冲+地幔柱复合的演化模型。同时,对中亚造山带中的OIB及OIB型玄武岩形成时代进行系统总结发现,它们不仅时代宽度大,并且具有连续发育的特点。对正确认识地幔柱活动在显生宙中亚造山带地壳增生过程中的贡献提供新的资料和证据。     

华北克拉通西部临县紫金山碱性岩体地球化学特征及地质意义

山西吕梁地区出露的紫金山岩体为我国著名的碱性岩体之一.为了探讨紫金山碱性岩体的物质来源及地质意义,对该岩体主要岩石进行了岩相学及岩石地球化学研究.结果表明:紫金山岩体各期次岩石具有低硅、富碱、高钾的特点,属钾质碱性岩石;岩石轻重稀土元素分馏较强烈,具有轻稀土相对富集、重稀土相对亏损、无明显Eu异常的特征;微量元素总体表现为大离子亲石元素(Rb、Ba、K、Sr等)明显富集、高场强元素(Th、Nb、Ta、La、Ce、Nd、P、Ti等)亏损的特征.紫金山岩体岩浆来源较深,与富集地幔关系密切,岩浆演化机制以部分熔融作用为主且存在陆壳物质混染.结合山西境内多处同时期的碱性、偏碱性岩体特征,推断华北中部早白垩世碱性岩浆活动与古太平洋板块俯冲背景下华北克拉通破坏作用关系密切.     

Interpretation of aeromagnetic anomalies over part of Southeastern Nigeria using three-dimensional Hilbert transformation

We present the results of the application of three-dimensional Hilbert transformation to the analysis of airborne total field magnetic anomalies over part of Southeastern Nigeria. This study not only substantiates the usefulness of 3-D Hilbert transforms in the interpretation of magnetic anomaly maps but also more clearly delineates the structural pattern of the area, of study. Results from the previous study are discussed in relation to the results of previous geological and geophysical studies of the area.     

论地质作用中元素间的相关性及制约因素

本文把地质作用中元素间的相关性划分为曲线相关、准线性相关和线性相关三种类型;并在建立反映岩浆、沉积作用过程中元素间相关关系的数学模型及其它工作的基础上,详细讨论分配系数、源区成分和作用过程等方面对地质作用中元素间相关关系的制约作用。进而获得批式熔融、结晶分异、岩浆混合、化学沉积、碎屑沉积等过程中元素间呈线性和(?)线性关系的一般特征和应用前景。最后还给出La/Ce相关性的应用实例。     

Post-collisional volcanism in a sinking slab setting—crustal anatectic origin of pyroxene-andesite magma, Caldear Volcanic Group, Neogene Alborán volcanic province, southeastern Spain

Caldear Volcanic Group (CVG), a stratigraphically well defined, calc-alkaline rock complex within S^a de Gata in the eastern part of the Alpine Betic mountain chain, S Spain, consists of three distinct formations: Hernández pyroxene andesites, Bujo hornblende-bearing pyroxene andesites and Viuda hornblende-bearing pyroxene dacites–rhyolites. The letter rock formation may have developed through crystal fractionation of mainly plagioclase and pyroxenes, however there is no direct relation between two formations. CVG has a domainal structure with a northeastern domain where Hernández formation is overlain by Bujo formation while Viuda formation is absent, and a southwestern domain where Viuda formation forms the only fractionate after Hernández formation. Hernández parent magma is thought generated through crustal anatexis by dehydration melting of a predominantly amphibolitic source rock complex which was formed by metamorphism from c. 500 Ma volcano-sedimentary parent material. The domainal structure of CVG is explained by compositional variation within this protogenetic complex. Single crystal U–Pb ages of c. 500 Ma to 1800 Ma for inherited zircon support the presence of clastic material of Proterozoic derivation within the original volcano-sedimentary complex. Regional study of syn-collisional rock formations (Alpine nappe complexes) indicate that the collisional tectonic stage in the Betic-Rif orogenic belt took place rather early (25–30 Ma?) and was followed by a stage of rapid regional rock uplift, fast cooling (c. 500°C/my) and extensional tectonics in the period 22–17 Ma. This later tectonic stage was set into motion by slab break-off which set the stage for a high temperature regime in the overlying lithosphere, providing the framework for the crustal melting and magma production responsible for the calc-alkaline rocks of Alborán volcanic province. Miocene zircon with ages ranging from c. 17 to 11 Ma indicate a rather protracted magmatic development prior to eruption at c. 11 Ma. Post-collisional character of Caldear Volcanic Group thus seems well established.     

Heat flow in the Basin and Range province and thermal effects of tectonic extension

In regions of tectonic extension, vertical convective transport of heat in the lithosphere is inevitable. The resulting departure of lithosphere temperature and thickness from conduction-model estimates depends upon the mechanical mode of extension and upon how rapidly extension is (and has been) taking place. Present knowledge of these processes is insufficient to provide adequate constraints on thermal models. The high and variable regional heat flow and the intense local heat discharge at volcanic centers in the Basin and Range province of the United States could be accounted for by regional and local variations in extensional strain rate without invoking anomalous conductive heat flow from the asthenosphere. Anomalous surface heat flow typical of the province could be generated by distributed extension at average rates of about 1/2 to 1%/m.y., similar to rates estimated from structural evidence. To account for higher heat flow in subregions like the Battle mountain High, these rates would be increased by a factor of about 3, and locally at active bimodal volcanic centers, by an order of magnitude more.     

滇池福保湾间隙水氮磷分布及其与底泥微生物和磷酸酶相互关系

在滇池福保湾不同区域应用Peeper(渗析膜式)技术,分析了底泥间隙水NH4 -N、Po43--p的垂向分布特征和近表层10cm内底泥的微生物活性(FDA)、碱性磷酸酶活性(APA),并对它们之间的相互关系进行了统计分析.结果表明,NH4 -N和Po43--p浓度自上覆水向下层间隙水呈先升后降趋势,反映它们有自间隙水向上覆水扩散的潜在危害;底泥有机质(Loss-on-Ignion,LOI)、APA和FDA活性也有从表层底泥向下层逐步降低的趋势.在空问分布上,Po43--p浓度变化为河口区>湾心区>西部沿岸区>东部沿岸区,与沉积物中LOI、APA和FDA活性的大小顺序基本相同.间隙水NH4 6-N浓度与表层10cm内底泥的APA和FDA活性具有显著正相关性(α＝0.01).Po43--p浓度与底泥APA和FDA活性具有负相关性.但相关系数很低.     

新疆东准噶尔老鸦泉富碱花岗岩型锡矿床地质及成矿流体

老鸦泉碱性花岗岩位于新疆北部东准噶尔地区。老鸦泉碱性花岗岩体及其内卡姆斯特、干梁子锡矿床的矿石和岩石的岩矿鉴定、稀土元素以及流体包裹体的系统研究表明,老鸦泉碱性花岗岩及其内的花岗斑岩及含矿石英岩、云英岩化锡矿体、石英脉锡矿体,实际上是富碱花岗质岩浆逐渐分异演化的同源和最终产物,锡成矿流体为中-高温、低盐度。碱性岩浆晚期分异的大量气水热液富锡、富硅、富碱、富含F、Cl、SO²₄离子及离子团,其氧逸度高、酸度高、温度高,这种热液引起花岗岩体的硅化、云英岩化等自变质作用,在该作用中随温度、压力的降低及CH₄等还原性气体及CO₂气体的逃逸,改变了成矿流体的氧化-还原环境,流体向相对还原及碱性条件转化,在新的氧化还原、酸碱度界面条件下,其携带的锡的络合物不稳定而分解,锡沉淀成矿。     

雅鲁藏布江蛇绿岩中地幔柱型岩浆作用——来自氦、氩同位素的证据

雅鲁藏布江蛇绿岩的氦、氩同位素组成分别是：蛇绿岩中变质橄榄岩的^3He/^4He比值为1．104-3．384Ra,平均为2．383Ra;玄武岩的He同位素组成比较均一,^3He/^4He平均值为5．359 Ra;辉绿岩的^3He／^4He比值变化较大,为1—5Ra。由于各岩石样品有不同程度的蚀变,造成放射性成因He的加入,因此大多数样品He同位素组成比低于亏损地幔大洋中脊玄武岩的值(MORB≈8Ra),不能真实反映源区特征。而采自吉定的辉绿岩样品^3He/^4He比值平均高达31．57Ra,与夏威夷发现的热点地幔源区的样品比值接近;分步加热法进一步测试,其高比值的He是在低温区段释放的。这种高^3He/^4He比值He的捕获,表明雅鲁藏布江蛇绿岩形成时存在地幔柱型富集地幔岩浆作用。