太白维山中生代火山岩特征及其与成矿的关系

晋北太白维山火山岩属钾质碱性玄武岩系列,产于板块内部活化带,来源于上地幔或下部地壳,被上部地壳物质混染,为壳幔源型或同熔型火山岩.火山岩与Ag(Pb、Zn)矿化关系密切,是成矿热液和矿质的主要来源之一.     

Lower palaeozoic and precambrian petroleum source rocks and the coalification path of alginite

Organic-rich samples derived from a Middle Cambrian Formation in the Georgina Basin, and from the Middle Proterozoic of the McArthur Basin in northern and central Australia, yielded alginite ranging from immature oil shale material to overmature residue. A maturation scale has been developed based on the thermal evolution of alginite as determined from reflectance and fluorescence. The coalification path of alginite is marked by jumps in contrast to the linear path of wood-derived vitrinite. Six zones have been recognised, ranging from undermature (zone I), through the mature (zones II/III), followed by a stable stage of no change (zone IV) to the overmature (zones V and VI). The onset of oil generation in alginite as evident from the present study is at 0.3% R_{o Alg.} and is expressed in a change of fluorescence from yellow to brown, and a coalification jump from 0.3 to 0.6% R_o of Alg. In many boreholes zone III can be distinguished between 0.6 and 0.8% R_o of Alg. where subsequent oil generation occurs. Zones II and III represent the oil window.A zone of little or no change designated zone IV, at of alginite follows zones II/III. A marked coalification jump characterises zone V, where a pronounced change in reflectance occurs to >1.0% R_{o Alg.}, signifying peak gas generation. The border of oil preservation lies at the transition of zone V and VI, at 1.6% R_{o Alg.} In zone VI gas generation only occurs.Comparison of reflectance results with experimental and geochemical pyrolysis data supports high activation energies for hydrocarbon generation from alginite, and therefore a later onset of oil generation than other liptinite macerals (i.e. cutinite, exinite, resinite) as well as a narrow oil window.Transmission electron microscopy (TEM) confirms that alginite does not go through a distinct intermediate stage but that the percentage of unreacted organic matter decreases as maturation proceeds. A clear distinction can be made in TEM between immature alginite, alginite after oil generation, and alginite residue following gas generation. Alginite beyond 1.6% R_o acquires very high densities and the appearance of inertinite in TEM.Bitumens/pyrobitumens make a pronounced contribution to the organic matter throughout the basins and have been shown to effect pyrolysis results by suppressing T_max. The bitumens/pyrobitumens have been divided into four groups, based on their reflectance and morphology, which in turn appears to be an expression of their genetic history. Their significance is in aiding the understanding of the basins' thermal history, and the timing of oil and gas generation.     

滇西墨江西部石炭、二叠纪火山岩

墨江西部出露有石炭纪和晚二叠世两套火山岩,它们呈平行的两条带分布。石炭纪火山岩以拉斑玄武岩为主,少量流纹岩,它们是由上地幔源区10%部分熔融形成的原始岩浆,经橄榄石、辉石和斜长石不同程度结晶分异作用形成。其喷发环境可能是一个发育在大陆边缘的张性海盆地。晚二叠世火山岩较为复杂,熔岩与火山碎屑岩交互发育,熔岩主要属于拉斑系列,还含有少量钙碱性系列岩石;形成于陆缘火山弧环境。     

大别超高压岩石中石英的组构和变形

通过对大别地区不同超高压岩石和同一超高压岩石中不同变形期次石英的变形特征的研究 ,探讨超高压岩石折返时的流变学特征和状态。运用野外构造解析、组构分析、透射电镜和应变分析发现 ,除榴辉岩中静态重结晶石英外 ,其它超高压岩石中石英均发生了强烈的塑性变形 ,波状消光、变形纹、变形条带等极为常见。石英石榴岩中石英交叉滑移位错的发育 ,说明经历了高温位错蠕变 ,其代表的差异应力为Δσ =78.92MPa。石英脉的变形是超高压岩石折返到中地壳以后的角闪岩相退变峰期产物 ,其差异应力为Δσ =2 5 .2MPa。超高压二云母片岩中石英典型的糜棱结构代表的差异应力为 :Δσ =5 9.6 1MPa。大别超高压岩石可能是在构造应力比较低的情况下区域隆升的结果     

新疆坡十铜镍硫化物含矿岩体岩浆源区特征及构造背景探讨

新疆坡北辉长岩体位于塔里木古陆东北缘的北山裂谷带中,坡一和坡十铜镍硫化物含矿超镁铁岩体位于坡北岩体内.尽管坡十超镁铁岩体与坡北辉长岩呈侵入接触,但两者的微量元素和同位素组成显示良好 的一致性,表明两岩相虽然分不同阶段侵入就位,但仍为同源岩浆的产物.MnO-TiO2-R2O5及Th-Hf-Ta判别图解显示坡北及坡十岩体的...     

华南沉积岩系Hg、Sb丰度

从区域构造地球化学演化的角度来看,华南Hg、Sb矿床的形成主要可划分为三个阶段:(1)沉积层(主要是元古宙基底沉积层)堆积过程中Hg、Sb的储集;(2)元古宙基底(沉积层)的下沉-熔融-花岗岩形成与Hg、Sb释放;(3)在有利构造的引控下,含Hg、Sb流体形成、演化与成矿,简称为储存-释放-富集宏观三阶段。本文重点阐述的是第一阶段,华南沉积层特别是元古宙基底沉积层的Hg、Sb丰度。文中将华南沉积层Hg、Sb丰度分为四种类型:Ⅰ原生本底丰度;Ⅱ同生异常丰度;Ⅲ后生丰度;Ⅳ混合丰度。本文计算、统计出华南沉积岩系本底丰度Hg为0.368μg/g,Sb为1.28μg/g。华南元古宙基底沉积岩系本底丰度Hg为0.363μg/g,Sb为1.45μg/g都明显高于地壳及花岗岩Hg、Sb丰度值。     

辽西建昌碱性粗面岩的年代学及岩石成因研究

义县组火山岩在辽话分布广泛,研究区碱性粗面岩位于建昌地区义县组火山岩的顶部,详细的年代学及地球化学研究表明,锆石u—Pb年龄为（120．3±1．5）Ma,具有较高的SiO2：和碱含量,ω（SiO2）=63．52％～65．94％,ω（Na20＋K2O）=9．63％一10．15％,ω（Na20）／ω（K20）为0．96～1．08,属于高钾碱性岩系列,同时具有较低的ω（MgO）（0．75％～1．05％）,稀土配分模式为轻稀土富集,重稀土亏损的右倾型模式（La／Yb）n=8．96～12．02）,较弱的正Eu异常（δEu=1．07—1．16）,相容元素Cr（1．46×10^6～4．15X10^6）、c0（19．8X10^6。～45．9X10^6）和Ni（0．100x10^6～1．55×10^6）含量低。微量元素蛛网图显示明显的Ba和Pb正异常,以及Sr、Ti和Y负异常,此外,zr和Hf显示一定的正异常。认为碱性岩形成于拉张的构造环境,且来源深度较大,是壳幔相互作用的结果,研究区火山岩是经过强烈橄榄石、斜方辉石和单斜辉石结晶分异的富集地幔岩浆上升底侵至下地壳,并经历同化混染和部分熔融,然后沿着深大断裂喷发至地表。     

鲁南苏北榴辉岩的特征及其成因

鲁南苏北榴辉岩按产状分为两类:一类是呈条带状、透镜状或肠状鳌合赋存于胶南混杂岩系中,另一类是呈透镜状赋存于石榴石橄榄岩中,以前者分布最为广泛,后者仅见于日照及东海地区。胶南混杂岩系中的榴辉岩由橄榄拉斑玄武岩深成变质作用形成,石榴石橄榄岩中的榴辉岩为地幔来源,它们共同经历了早期2.8 GPa,800℃的高温高压平衡结晶及后期600—700℃,1.1—1.3 GPa的退变质作用改造。Sm-Nd等时年龄为222±6Ma,~(143)Nd/~(144)Nd初始比值为0.511 36±3,推测本区榴辉岩形成于早三叠世华南陆块与华北陆块的碰撞事件。     

中亚造山带南缘中—新元古代地壳的揭示——来自北山—阿拉善北部钻遇碱性花岗岩的年代学和Hf同位素示踪研究

前寒武纪微陆块是北山—阿拉善北部增生造山带的重要组分,旱山、雅干和珠斯楞—杭乌拉地区的前寒武纪基底是否存在学界尚存争议.居延海介于北山造山带北部和阿拉善地块北缘的构造衔接部位,受限于巴丹吉林沙漠覆盖,岩石露头极少,我们通过钻井工程,钻遇一套晚石炭世碱性花岗岩,锆石U-Pb年龄和Hf同位素特征揭示,该花岗质岩浆锆石结晶年龄为(312±1)Ma(MSDW=0.46,n=18)和(315±2)Ma(MSWD=0.93,n=15),具有正的εHf(t)值,介于+0.8~+4.4之间,平均值为+2.2,对应二阶段模式年龄TDM2为1048~1267 Ma,平均值为1183 Ma,具有古老地壳的源区属性.通过与旱山构造带、雀儿山构造带、雅干构造带和珠斯楞—杭乌拉构造带的晚石炭世花岗质岩浆对比分析,结合旱山构造带、雅干构造带和珠斯楞—杭乌拉构造带0.9 Ga花岗质岩石的出露以及区域上的重磁资料解译,我们认为旱山、雅干和珠斯楞—杭乌拉构造带存在中—新元古代地壳,且可开展进一步的衔接关系研究.     

张家口水泉沟碱性杂岩体单颗粒锆石^207Pb／^206Pb年龄分析

用单颗粒锆石铅蒸发－沉积法分析张家口地区赋金水泉沟碱性杂岩体形成时代,保持封闭体系３颗锆石的＾２０７Ｐｂ／＾２０６Ｐｂ值表面年龄在１６０７－１６６７Ｍａ之间,与锆石Ｕ－Ｐｂ法上交点年龄（１７１８±６５）Ｍａ基本一致,水泉沟碱性杂岩体是１６－１７亿前形成的。