北大巴山早古生代地幔交代作用与煌斑岩浆的起源和演化

产于陕西岚皋境内、赋存于碱质煌斑杂岩中的金云角 闪 辉石岩捕虏体是交 代地幔捕虏体。微量元素和SrNd同位素的对比研究表明,金云角闪辉石岩型交代地幔是寄 主煌斑岩的源区。金云角闪辉石岩捕虏体富含高Na、Ti的角闪石是本区寄主煌斑岩富Ti, 具 低K/Na值的根本原因。煌斑杂岩的同位素地球化学研究表明,早古生代地幔交代作用相对 于煌斑岩的侵位是一个相对近的时间间隔,大约发生于距今600～700 Ma。寄主煌斑岩 的 原生岩浆是金云角闪辉石岩型地幔经较大程度部分熔融而形成,原生岩浆为相似于橄榄金伯 利岩和橄辉玢岩的碱质超基性煌斑岩浆,其经初步分离结晶后形成两个不同的母岩浆,分别 相当于橄榄金伯利岩浆和橄辉玢岩岩浆,两个母岩浆各自具有不同的分离结晶系列,形成不 同的岩石类型。     

Deep xenoliths in alkalic porphyry, Liuhe, Yunnan, and implications to petrogenesis of alkalic porphyry and associated mineralizations

Na-rich microlite-glass is first discovered in deep-source xenoliths in alkali-rich porphyry, Liuhe village, Heqing County, Yunnan Province. It is shown that the ultramafic xenoliths originated from partial melting of primary mantle and the glass resulted from metasomatism between the xenoliths and mantle fluid derived from mantle degassing. Mantle metasomatism not only resulted in the enrichment of alkaline, large-ion elements, ore metals and volatiles but also created a favorable condition for the generation of alkaline magmas. The mantle xenoliths and their characteristics of mantle metasomatism provide important evidence for a better understanding of the petrogenesis and mineralization of the Cenozoic alkali-rich porphyry in western Yunnan.     

敞开酸溶和偏硼酸锂碱熔ICP-MS法测定多金属矿中的稀土元素及铌钽锆铪

用电感耦合等离子体质谱法(ICP-MS)测定地质样品中的稀土及难熔元素,混合酸敞开酸溶法和碱熔融法是两种主要的溶样方法。但地质样品组分复杂,元素之间存在相互共生的现象,对于特殊元素、特殊样品用传统酸溶法会造成部分元素消解不完全,使测定结果不准确;而碱熔法的操作过程繁琐,且溶液盐度高,易产生基体干扰和堵塞仪器进样系统。本文改进了传统四酸和五酸体系,采用氢氟酸-硝酸-硫酸敞开酸溶体系,用国家一级标准物质制作标准曲线测定15种稀土元素,方法准确度(ΔlgC)为0.001～0.027。同时改进了偏硼酸锂碱熔法,样品用偏硼酸锂碱熔提取,加入氢氧化钠调节溶液至碱性条件,所测元素与偏硼酸锂共沉淀后过滤分离熔剂,再用硝酸复溶测定15种稀土元素及铌钽锆铪。两种溶样方法的测定值与认定值的相对误差为1.09%～9.30%。将混合酸敞开酸溶法测定稀土元素、偏硼酸锂碱熔法测定铌钽锆铪的结果与其他实验室密闭酸溶法相比,两组数据的相对偏差为0.13%～15.32%。本实验表明,混合酸敞开酸溶法适用于测定地质样品中的稀土元素,偏硼酸锂碱熔法不仅适用于测定地质样品中的稀土元素及铌钽锆铪,也适用于测定如古老高压变质岩石及铝含量高的样品中的铌钽锆铪。     

Ancient deep roots for Mesozoic world-class gold deposits in the north China craton:An integrated genetic perspective

The North China Craton(NCC)hosts some of the world-class gold deposits that formed more than 2 billion years after the major orogenic cycles and cratonization.The diverse models for the genesis of these deposits remain equivocal,and mostly focused on the craton margin examples,although synchronous deposits formed in the interior domains.Here we adopt an integrated geological and geophysical perspective to evaluate the possible factors that contributed to the formation of the major gold deposits in the NCC.In the Archean tectonic framework of the NCC,the locations of the major gold deposits fall within or adjacent to greenstone belts or the margins of micro-continents.In the Paleoproterozoic framework,they are markedly aligned along two major collisional sutures-the Trans North China Orogen and the Jiao-Liao-Ji Belt.Since the Mesozoic intrusions hosting these deposits do not carry adequate signals for the source of gold,we explore the deep roots based on available geophysical data.We show that the gold deposits are preferentially distributed above zones of uplifted MOHO and shallow LAB corresponding to thinned crust and eroded sub-lithospheric mantle,and that the mineralization is located above regions of high heat flow representing mantle upwelling.The NCC was at the center of a multi-convergent regime during the Mesozoic which intensely churned the mantle and significantly en riched it.The geophysical data on Moho and LAB upwarp from the centre towards east of the craton is more consistent with paleo-Pacific slab subduction from the east exerting the dominant control on lithospheric thinning.Based on these results,and together with an evaluation of the geochemical and isotopic features of the Mesozoic magmatic intrusions hosting the gold mineralization,we propose a genetic model that invokes reworking of ancient Au archives preserved in the lower crust and metasomatised upper mantle and which were generated through multiple subduction,underplating and cumulation events associated with cratonization of the NCC as well as the subduction-collision of Yangtze Craton with the NCC.The heat and material input along zones of heterogeneously thinned lithosphere from a rising turbulent mantle triggered by Mesozoic convergent margins surrounding the craton aided in reworking the deep roots of the ancient Au reservoirs,leading to the major gold metallogeny along craton margins as well as in the interior of the NCC.     

粉煤灰增强回填碱渣工程特性的试验研究

碱渣与饱和卤水混合制成浆体回填到盐矿废弃盐腔可同时解决碱渣处理问题和地下废弃盐腔存在的地质隐患。回填碱渣强度是影响充填效果的重要因素。因此,为了提高回填碱渣强度,采用掺入粉煤灰制成复合碱渣对其强度特性进行改良。针对不同粉煤灰掺合比的碱渣开展了组成、力学和细观试验。研究结果表明：（1）掺入粉煤灰能明显改善碱渣的强度,使其黏聚力、内摩擦角都大幅提高,抗剪强度大幅增加;（2）粉煤灰掺合比越大,增强效果越明显,但强度并非随掺合比呈线性变化,对黏聚力而言,在0～20%内的掺合比下增加速度最快,而对内摩擦角则在20%～30%的掺合比区间增加最快,对抗剪强度而言,0～20%的掺合比内增加最明显;（3）粉煤灰掺入还可显著改善碱渣的压缩固结特性,使其固结系数大幅提高,从而提高碱渣固结速度,缩短充填工期,其中在0～10%的掺合比内对压缩固结特性改善最显著;（4）矿物组成分析表明,粉煤灰掺入改变了矿物组成,使得亲水性矿物含量急剧锐减,进而改变了其沉积特性。而细观分析则表明,粉煤灰掺入使碱渣从絮凝团细观结构变成了粉煤灰充当骨架的充填结构,且粒间支撑和拉联效应明显。从增强效果提高、压缩固结特性增强、控制成本和工期综合分析表明,最优掺合比为20%左右,建议工程中以不高于20%的掺合比作为实用掺合比即可取得较为理想的充填增强效果。该研究为揭示碱渣增强机制及废弃盐腔碱渣充填工艺优化提供了有益参考。     

居隆庵地段铀成矿的地质条件

从区域环境到矿化阶段的系统论述,其用意是强调区域环境的深部构造热作用是成矿的热动力基础,多种地球物理-地球化学场（晕）叠置区是成矿区的标志。火山-岩浆演化是热源的积累．先钼后铀的矿化作用基础,碱性流体交代蚀变和氢交代铀富集成矿等综合因素决定了居隆庵是一个具有较大潜力的铀资源地段。     

吉林白山地区玄武岩中宝石矿床成矿特征

白山市矿产资源丰富,宝石矿床种类繁多,具有十分重要的研究价值及经济意义.本文仅对碱性玄武岩中宝石矿床产出的构造背景及相关联的蓝宝石、橄榄石矿床的形成条件、特征及成矿规律进行探讨.     

冀东下营坊地区晚古生代富碱侵入岩锆石U-Pb年代学、岩石地球化学及其地质意义

富碱侵入岩具有重要的地质和矿产意义,倍受学者关注。冀东地区晚古生代钙碱性岩浆岩十分发育,而碱性岩少见,笔者首次在冀东下营坊地区识别出一批与金(铜铅锌银)多金属矿化有关的晚古生代中晚期的富碱侵入岩体。通过锆石LA-ICP-MS U-Pb测年,获得下营坊地区三处富碱侵入岩的侵位年龄分别为300.0±1.5Ma、299.3±2.1Ma、300.0±2.0Ma,侵位时间显示这些岩浆岩均为晚石炭世末—早二叠世的产物。岩石地球化学特征显示富碱(K2O+Na2O8%),稀土元素含量较高,并强烈富集轻稀土,指示其具有富碱侵入岩的基本特征。下营坊富碱侵入岩富集大离子亲石元素,高La/Yb比,较高的La/Sm比值且变化范围大(5),低Y,Eu异常不明显等特点,表明其源区可能与富集地幔有关,并可能受到俯冲板片脱水所释放流(熔)体的影响,在岩浆的侵位过程中可能受到地壳物质的混染。由成岩时代结合区域构造演化历史推断,该地区富碱侵入岩很可能与古生代期间古亚洲洋板块向华北板块俯冲有关,并形成于由俯冲板块后撤的伸展环境。     

Zircon recycling and crystallization during formation of chromite- and Ni-arsenide ores in the subcontinental lithospheric mantle (Serranía de Ronda,Spain)

The ultramafic massifs of the Serranía de Ronda (namely Ronda, Ojén and Carratraca) are portions of Proterozoic (∼1.2–1.8 Ga) subcontinental lithospheric mantle (SCLM) affected by partial melting and infiltration of melts. The latter of these events was broadly coeval with the tectonic emplacement of the peridotites into the continental crust in the Early Miocene. This resulted in the formation of chromite and Ni-arsenide ores (Cr-Ni) associated with orthopyroxenites and cordieritites. Six zircons recovered from a massive chromitite sample from the Ronda massif yield both concordant and discordant ages between 2309 ± 37 Ma and 109 ± 15 Ma, and δ¹⁸O between 8.3‰ and 9.4‰. Two Proterozoic ages obtained for zircons of this population (1815 ± 9 Ma and 1794 ± 17 Ma) are identical, within error, to those of zircons reported previously in the garnet pyroxenites of Ronda (1783 ± 37 Ma). Similarly, concordant Early Jurassic (192 ± 13 Ma) and Cretaceous ages (109 ± 15 Ma) obtained from the core and rim, respectively, of a single zircon from the chromitite are also consistent with the ages (180 ± 5 Ma, 178 ± 6 Ma, and 131 ± 3 Ma) already reported for magmatic zircons from corunudum-bearing garnet pyroxenites in the Ronda massif. The observation that chromitites and garnet-pyroxenites contain similar populations of zircons suggests that the parental melts of chromitites inherited zircons from their protolithic garnet pyroxenites, representing relics of oceanic/arc crust recycled in the mantle. Eleven zircons recovered from a massive cordieritite associated with chromitite in the Ronda massif yield scattered concordant and discordant ages between 568 Ma and 21 Ma, with correspondingly variable δ¹⁸O (4.8–13.5‰) and unradiogenic Hf-isotope ratios (ε_Hf(t) from −12.36 to −4.43). The youngest age is concordant at 21.18 ± 0.4 Ma and matches the ages of zircons from the chromitite (weighted average age of 20.4 ± 0.87 Ma, n = 4) and a plagioclasite dyke (scattering between 20.1 ± 0.2 Ma and 17.9 ± 0.1 Ma; n = 11) associated with the Cr-Ni mineralization in the Ojén massif. These zircons show similar unradiogenic Hf-(ε_Hf(t) between −14.5 and −7.6) and heavy O-isotope compositions (δ¹⁸O = 11.3–12.4‰). A sample of the massive cordieritite hosting the chromitites contains abundant zircons that yield scattered concordant, sub-concordant and discordant U-Pb ages varying from 33.8 ± 1 Ma to 781 ± 10 Ma; these zircons (n = 21) have variable U-contents (105–13900 ppm) and Th/U ratios (0.003–0.8). On the basis of O- and Hf-isotope compositions, these zircons define three populations independently of their ages: (1) grains with consistent high δ¹⁸O (6.1–12.7‰) and negative ε_Hf(t) (from −14.42 to −6.88); (2) grains with high δ¹⁸O (7.6–11.1‰) and positive ε_Hf(t) (3.10–4.84); and (3) grains with δ¹⁸O < 5.5‰ typical of mantle values. We suggest that zircons from this cordieritite with U-Pb ages older than Miocene are inherited, and were incorporated physically into the SCLM by fluids or melts produced during dehydration-melting of the crustal rocks wrapping the peridotite massifs. The population of Early Miocene zircons found in the chromitites and associated cordieritites and the plagioclasite dyke in the mineralization of the Ojén massif date the crustal emplacement of the peridotites and, therefore, the formation of the Cr-Ni ores. We propose a model in which the unique Cr-Ni mineralizations found in the ultramafic rocks of the Serranía de Ronda were formed as a result of contamination of the SCLM with crustal components.     

利用水合硅酸钠钙渣回收碱并用于制备硅灰石纳米粉体的实验研究

从高硅含铝原料霓辉正长岩中提取氧化铝时,硅以水合硅酸钠钙的形式排出。实验研究了水合硅酸钠钙渣的高效利用技术。利用水合硅酸钠钙自身的水解作用和在NaOH溶液中使之分解两种方法来回收其中的Na2O,所得NaOH溶液经蒸发浓缩后可循环利用。回收碱后剩余的固体渣用来制备硅灰石粉体。实验得出回收碱的优化条件为温度180 ℃,起始溶液的Na2O浓度为20 g/L,液固比为4∶1,洗涤6~7次。在此条件下,碱回收率可达90%以上。对回收碱后所得固体渣进行差热-热重分析,确定制备硅灰石粉体的煅烧温度。在820 ℃下煅烧2 h,制得颗粒尺寸为50~100 nm的α-CaSiO3纳米粉体,对其反应机理进行了初步的探讨。