滇西丽江地区新生代富碱斑岩年代学、地球化学特征及其地质意义

滇西丽江地区新生代富碱斑岩位于滇西“三江”褶皱造山带与扬子板块西南缘结合部位,岩石类型多样,可分为碱性岩和碱性花岗岩,前者主要有正长斑岩、正长岩及粗面斑岩;后者主要包括花岗斑岩、二长花岗斑岩及石英二长斑岩。锆石LA ICP MS U Pb定年研究确定区内斑岩结晶年龄为346～371 Ma,侵位于始新世晚期。碱性岩石的SiO2含量为5454%～6770%,K2O＞Na2O,具有钾玄岩的特征;碱性花岗岩的SiO2含量为6716%～7066%,K2O＜Na2O,具有高钾钙碱性的特征。两类岩石都具有富碱(Na2O+K2O=703%～1170%)和准铝质—弱过铝质(A/CNK=064～115)的特征。富集轻稀土元素和大离子亲石元素(Sr、Ba、K、Pb等),相对亏损重稀土元素和高场强元素(Nb、Ta、Ti等),且具有高Sr、Sr/Y和La/Yb比值及低Y、Yb和镁值(Mg#＜05),表明区内斑岩兼具钾玄质岩石和埃达克质岩石的特征。综合研究认为,区内斑岩形成于印度－亚洲大陆碰撞造山的后碰撞阶段,其形成与减压熔融及幔源岩浆底侵促使增厚下地壳底部岩石发生部分熔融有关,是青藏高原东南缘构造转换带对主碰撞带造山作用过程的岩浆事件响应,进而分析确认本区具有斑岩-热液型金多金属矿床的找矿潜力,为深入认识丽江地区构造-岩浆-成矿作用提供了重要约束。     

Ancient deep roots for Mesozoic world-class gold deposits in the north China craton:An integrated genetic perspective

The North China Craton(NCC)hosts some of the world-class gold deposits that formed more than 2 billion years after the major orogenic cycles and cratonization.The diverse models for the genesis of these deposits remain equivocal,and mostly focused on the craton margin examples,although synchronous deposits formed in the interior domains.Here we adopt an integrated geological and geophysical perspective to evaluate the possible factors that contributed to the formation of the major gold deposits in the NCC.In the Archean tectonic framework of the NCC,the locations of the major gold deposits fall within or adjacent to greenstone belts or the margins of micro-continents.In the Paleoproterozoic framework,they are markedly aligned along two major collisional sutures-the Trans North China Orogen and the Jiao-Liao-Ji Belt.Since the Mesozoic intrusions hosting these deposits do not carry adequate signals for the source of gold,we explore the deep roots based on available geophysical data.We show that the gold deposits are preferentially distributed above zones of uplifted MOHO and shallow LAB corresponding to thinned crust and eroded sub-lithospheric mantle,and that the mineralization is located above regions of high heat flow representing mantle upwelling.The NCC was at the center of a multi-convergent regime during the Mesozoic which intensely churned the mantle and significantly en riched it.The geophysical data on Moho and LAB upwarp from the centre towards east of the craton is more consistent with paleo-Pacific slab subduction from the east exerting the dominant control on lithospheric thinning.Based on these results,and together with an evaluation of the geochemical and isotopic features of the Mesozoic magmatic intrusions hosting the gold mineralization,we propose a genetic model that invokes reworking of ancient Au archives preserved in the lower crust and metasomatised upper mantle and which were generated through multiple subduction,underplating and cumulation events associated with cratonization of the NCC as well as the subduction-collision of Yangtze Craton with the NCC.The heat and material input along zones of heterogeneously thinned lithosphere from a rising turbulent mantle triggered by Mesozoic convergent margins surrounding the craton aided in reworking the deep roots of the ancient Au reservoirs,leading to the major gold metallogeny along craton margins as well as in the interior of the NCC.     

白云鄂博赋矿白云岩与微晶丘和碳酸岩墙的碳氧同位素对比研究

本文通过方解石和白云石的碳和氧同位素分析,对比研究了白云鄂博赋矿白云岩、黑脑包微晶丘、北京西山微晶丘、宽沟北正常沉积灰岩和白云鄂博碳酸岩墙,从而探讨了赋矿白云岩的成因及其与超大型Fe-Nb-REE矿床的成因关系。结果为:①黑脑包腮林忽洞群顶部微晶丘和北京西山寒武系顶部微晶丘碳酸盐的δ~(13)C值都在0±2‰左右,δ~(18)O值为18.3‰～25.1‰,均具有典型海相沉积碳酸盐岩的特点;②白云鄂博东矿采场δ~(13)C值为-7.9‰～-1.1‰,δ~(18)O值为9.1‰～20.9‰;矿区东西两端δ~(13)C值-7.9‰～-0.6‰,δ~(18)O值8.6‰～25.7‰;均介于地幔流体与典型沉积碳酸盐岩之间。部分赋矿白云岩样品中白云石与方解石之间的碳氧同位素分馏△~(13)C和△~(18)O值均小于0‰,表明其受到过次生蚀变作用,低δ~(18)O值白云石样品所对应的负△~(18)O值反映了地幔镁质流体对沉积碳酸盐岩的强烈交代作用;③矿区—富稀土碳酸岩墙的δ~(13)C值为-7.2‰～-4.7‰,δ~(18)O价值为11.9‰～16.4‰,表明其碳酸岩岩浆并非原始地幔来源,而可能与俯冲板块携带的沉积碳酸盐岩与地幔流体在深部的高温混合熔融有关。碳酸岩墙中白云石与方解石之间的碳和氧同位素分馏均小于0‰,说明该碳酸岩墙中的白云石与方解石并非同成因矿物,至少其中之一为     

会理县小青山铜金矿区硅质钠长石岩研究

岩石空间产出特征、岩相学、岩石化学、稀土元素地球化学特征及成岩成矿作用特征等分析研究表明,硅质钠长石岩是经沉积变质、硅质钠质交代作用形成的,原岩组成多样,主要为碳质板岩,其次为条带状泥砂质白云岩,局部也可以是辉绿辉长岩。     

The Texture,Mineral Assemblages and Origin of Metamorphic Peridotite from Kuda Ophiolite,Xinjiang

There are two grades of network-type texture in metamorphic peridotite from the Kuda ophiolite,Xinjiang,China,The first graduation consists of coarse-grained olivine with plastic deformation fabrics,orthopyroxene and minor clinopyroxene and Cr-spinel.The second graduation consists of small minerals filling among the mineral grains of the first graduation.Four kinds of assemblages containing tremolite have been discovered in the second graduation,which were formed during mantle partial melting and mantle metasomatism of a highly depleted peridotite.     

利用水合硅酸钠钙渣回收碱并用于制备硅灰石纳米粉体的实验研究

从高硅含铝原料霓辉正长岩中提取氧化铝时,硅以水合硅酸钠钙的形式排出。实验研究了水合硅酸钠钙渣的高效利用技术。利用水合硅酸钠钙自身的水解作用和在NaOH溶液中使之分解两种方法来回收其中的Na2O,所得NaOH溶液经蒸发浓缩后可循环利用。回收碱后剩余的固体渣用来制备硅灰石粉体。实验得出回收碱的优化条件为温度180 ℃,起始溶液的Na2O浓度为20 g/L,液固比为4∶1,洗涤6~7次。在此条件下,碱回收率可达90%以上。对回收碱后所得固体渣进行差热-热重分析,确定制备硅灰石粉体的煅烧温度。在820 ℃下煅烧2 h,制得颗粒尺寸为50~100 nm的α-CaSiO3纳米粉体,对其反应机理进行了初步的探讨。     

Geochemical studies on Dachang antimony ore deposit in Qinglong, Guizhou Province

The Dachang antimony deposit in Qinglong,Guizhou Province,is strictly controlled by the “Dachang Layer” which is a complex altered rock occurring at unconformity between the Permian Emeishan basalt and the Maokou limestone.Based on the studies of the hanging-and foot-wall rocks,the trace elements and REE contents of the rocks and ores and heavy placer minerals in the basalt,this paper is focused on the relations between these data and the “Dachang Layer”and its hanging- and oot-wall rocks.The author pointed out that the “Dachang Layer” and basalt are the source-beds of antimony;ilmenite and magnetite are the major mineral carriers of antimony.In the processes of halmyrosis and burial metamorphism of the “Dachang Layer” an basalt,antimony was mobilized along with the mobilization of iron and was preliminarily concentrated in the“ Dachang Layer”.     

中国东部新生代碱性玄武岩及幔源捕虏体中的流体组成

中国东部新生代碱性玄武岩及其幔源二辉橄榄岩捕虏体中的流体组分存在差异,幔源二辉橄榄岩形成于以Ｈ２,ＣＯ等还原性气体为主的流体环境中,其流体组分以含Ｈ２高,挥发性气体总量低为特征;碱性玄武岩中流体组分以ＣＯ２,ＳＯ２和挥发性气体总量高为特征,在其形成演化过程中有ＳＯ２等氧化性气体的流体加入。     

从碱湖沉积和孢粉组合看内蒙古伊盟地区近5ka以来的古植被古气候变迁

内蒙古伊盟地区哈马尔太碱湖沉积特征和孢粉组合特征反映了该区近５ｋａ以来的古植被古气候变迁。研究表明，此期间该区植被由阔叶、灌木草原变为疏树灌木草原，最后变为荒漠草原。在这５ｋａ中存在两次暖期两次冷期，近１．６ｋａ以来以冷干为主。湿润气候只存在于４．５～５．５ｋａＢ．Ｐ．，气候总的趋势是由较湿润变干旱直至干燥。     

Regional Variations in the Mineralogy of Metasomatic Assemblages in Mantle Xenoliths from the West Eifel Volcanic Field, Germany

Xenoliths record two distinct events in the mantle below theQuarternary West Eifel Volcanic Field, Germany. The first, duringthe Hercynian Orogeny, led to widespread formation of secondary,Ti-poor amphibole, clinopyroxene and phlogopite. The signatureof the second event, related to Quaternary volcanism, variesacross the field. At Dreiser Weiher and Meerfelder Maar, thisevent is characterized by amphibole–phlogopite–clinopyroxeneveins, hosted in lherzolite and harzburgite xenoliths broughtto the surface by sodic olivine nephelinite–basanite suitelavas. These veins formed from crystallization of sodic magmathat flowed along fractures in the mantle. At Rockeskyller Kopf,Gees and Baarley, the Quaternary event is characterized by wehrlitexenoliths, many of which have phlogopite–clinopyroxeneveins, that were transported by potassic foid suite lavas. Wehrliteformed by reaction of lherzolite–harzburgite, with a largevolume of potassic magma that flowed along grain boundariesrather than in fractures. During reaction, orthopyroxene wasconsumed and secondary clinopyroxene, olivine and phlogopiteprecipitated. Veins formed in wehrlites only during periodicover-pressure events. The composition of the magmas parentalto the veins is similar to the lavas that carried the xenolithsto surface, indicating that the source of foid and olivine nephelinite–basanitesuite magma is domainal, as was the flow regime and magma flux. KEY WORDS: Eifel; mantle xenoliths; metasomatism; trace elements