兰州—白银多目标地球化学调查野外工作方法浅析

多目标区域地球化学调查从调查区表层、深层采样土壤元素分布特征入手建立土壤元素地球化学分配机制,以景观、地貌及地质特征为基础,选择合理的采样位置,正确的采样方法、采样层位,应用掌上机（Pocket PC）及数字填图系统（Rgmap）采集野外样品,本文以兰州—白银黄土覆盖区景观区为例,对表层、深层采样方法和技术要求进行探讨,对全省开展多目标地球化学调查,特别是野外工作方法提供借鉴。     

天然气溶解过程中组分分馏模型及其应用

天然气不同组分在水中溶解度的差异,导致溶解相与残留游离相天然气组分组成不同,即发生组分的溶解分馏效应。溶解分馏效应在天然气水溶运移、溶解散失等过程中均有发生。揭示天然气组分的溶解分馏规律、建立定量分馏模型,有助于天然气气源对比和成藏过程示踪。以Henry定律为依据,对不同组分溶解特征分析,提出了溶解度分数的概念,并建立了溶解分馏模型。根据该模型和各组分的溶解度分数和天然气溶解量,可计算各组分的溶解分馏量,恢复天然气初始组成特征。计算表明,威远震旦系气藏初期的天然气组成为:CH4为72.70%,C2H6为0.09%,CO2为22.41%,N2为4.07%,干燥系数(C1/C1-5)为99.876%。溶解作用使天然气中CO2含量显著降低,烃类气体含量增加,而天然气干燥系数降低。结果有助于天然气成因判识和气源对比等。     

碳酸盐型磷矿的反浮选工艺研究

针对某碳酸盐型磷矿,采用反浮选工艺流程进行试验研究,获得了低镁优质磷精矿。反浮选工艺具有药剂种类少,分选效率高,选矿技术指标先进,操作控制容易等优点,是选别碳酸盐型磷矿的先进浮选工艺。     

俯冲带榴辉岩的变形作用及其对俯冲-折返过程的意义

榴辉岩是大洋和大陆俯冲带的重要岩石类型,在研究俯冲带的形成过程、热结构、壳幔相互作用等方面有重要意义。通过对天然和实验样品中石榴子石、绿辉石等矿物的变形特征、变形机制、变形的影响因素等的综合分析,系统总结了高压变质带中榴辉岩矿物显微和超微变形研究的进展,探讨了榴辉岩的变形特征在恢复俯冲与折返过程研究中的意义及一些尚待解决的一些问题。     

SOME NEW UNDERSTANDINGS OF LAND-SURFACE PROCESSES IN ARID AREA FROM THE HEIFE*

The survey for the HEIFE(Atmosphere-Land Surface Processes Experiment at Heihe River Basin,Western China) is given in the paper.The following basic subjects for land-surface processes in arid areas are studied:(1) the general characteristics of the energy budget on ground surface in arid areas;(2) the parameterization of the land surface processes;(3) the interaction between oasis and its desert circumstances,a special phenomenon in arid areas.The analysis shows that the sensible heat flux in the surface energy budget is in the majority,and the latent heat flux may be neglected.The influence of atmospheric stratification stability on the turbulent transfer of energy and substance must be considered in parameterization of land surface processes in arid areas.The "cold island effect" phenomenon in oasis and the "humidity inversion" phenomenon in desert near oasis are the result of the interaction between them.The results would improve the understanding of land surface processes in arid areas.     

Oil and gas resource assessment: The linkage between geological analysis and discovery process model results

Two widely-used techniques to estimate the volume of remaining oil and gas resources are discovery process modeling and geologic assessment. Both were used in a recent national assessment of oil and gas resources of the United States. Parallel estimates were obtained for 27 provinces. Geological-based estimates can typically see into areas not available to discovery process models (that is areas with little or no exploration history) and thus, on average, yield higher estimates. However, a linear relation does exist between the mean estimates obtained from these two methods. In addition, other variables were found in a multiple regression model that explained much of the difference. Thus, it is possible to perform discovery process modeling and adjust the estimates to yield results that might be expected from geological-based assessments.     

Rupture process of large earthquakes in the northern Mexico subduction zone

The Cocos plate subducts beneath North America at the Mexico trench. The northernmost segment of this trench, between the Orozco and Rivera fracture zones, has ruptured in a sequence of five large earthquakes from 1973 to 1985; the Jan. 30, 1973 Colima event (M _s 7.5) at the northern end of the segment near Rivera fracture zone; the Mar. 14, 1979 Petatlan event (M _s 7.6) at the southern end of the segment on the Orozco fracture zone; the Oct. 25, 1981 Playa Azul event (M _s 7.3) in the middle of the Michoacan gap; the Sept. 19, 1985 Michoacan mainshock (M _s 8.1); and the Sept. 21, 1985 Michoacan aftershock (M _s 7.6) that reruptured part of the Petatlan zone. Body wave inversion for the rupture process of these earthquakes finds the best: earthquake depth; focal mechanism; overall source time function; and seismic moment, for each earthquake. In addition, we have determined spatial concentrations of seismic moment release for the Colima earthquake, and the Michoacan mainshock and aftershock. These spatial concentrations of slip are interpreted as asperities; and the resultant asperity distribution for Mexico is compared to other subduction zones. The body wave inversion technique also determines theMoment Tensor Rate Functions; but there is no evidence for statistically significant changes in the moment tensor during rupture for any of the five earthquakes. An appendix describes theMoment Tensor Rate Functions methodology in detail.The systematic bias between global and regional determinations of epicentral locations in Mexico must be resolved to enable plotting of asperities with aftershocks and geographic features. We have spatially shifted all of our results to regional determinations of epicenters. The best point source depths for the five earthquakes are all above 30 km, consistent with the idea that the down-dip edge of the seismogenic plate interface in Mexico is shallow compared to other subduction zones. Consideration of uncertainties in the focal mechanisms allows us to state that all five earthquakes occurred on fault planes with the same strike (N65°W to N70°W) and dip (15±3°), except for the smaller Playa Azul event at the down-dip edge which has a steeper dip angle of 20 to 25°. However, the Petatlan earthquake does prefer a fault plane that is rotated to a more east-west orientation—one explanation may be that this earthquake is located near the crest of the subducting Orozco fracture zone. The slip vectors of all five earthquakes are similar and generally consistent with the NUVEL-predicted Cocos-North America convergence direction of N33°E for this segment. The most important deviation is the more northerly slip direction for the Petatlan earthquake. Also, the slip vectors from the Harvard CMT solutions for large and small events in this segment prefer an overall convergence direction of about N20°E to N25°E.All five earthquakes share a common feature in the rupture process: each earthquake has a small initial precursory arrival followed by a large pulse of moment release with a distinct onset. The delay time varies from 4 s for the Playa Azul event to 8 s for the Colima event. While there is some evidence of spatial concentration of moment release for each event, our overall asperity distribution for the northern Mexico segment consists of one clear asperity, in the epicentral region of the 1973 Colima earthquake, and then a scattering of diffuse and overlapping regions of high moment release for the remainder of the segment. This character is directly displayed in the overlapping of rupture zones between the 1979 Petatlan event and the 1985 Michoacan aftershock. This character of the asperity distribution is in contrast to the widely spaced distinct asperities in the northern Japan-Kuriles Islands subduction zone, but is somewhat similar to the asperity distributions found in the central Peru and Santa Cruz Islands subduction zones. Subduction of the Orozco fracture zone may strongly affect the seismogenic character as the overlapping rupture zones are located on the crest of the subducted fracture zone. There is also a distinct change in the physiography of the upper plate that coincides with the subducting fracture zone, and the Guerrero seismic gap to the south of the Petatlan earthquake is in the wake of the Orozco fracture zone. At the northern end, the Rivera fracture zone in the subducting plate and the Colima graben in the upper plate coincide with the northernmost extent of the Colima rupture zone.     

Kinetics of redox cycling of iron coupled with fulvic acid

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.     

Brønsted reactions on oxide mineral surfaces and the temperature-dependence of their dissolution rates

The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO ^–), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge.