Organic geochemical studies have been carried out to assess the qualities of source rocks penetrated by four wells (Kemar-1, Murshe-1, Tuma-1 and Ziye-1) in the Nigerian sector of the Chad basin. The Chad basin is a large intracratonic basin in Central West Africa. Commercial hydrocarbon accumulations have been discovered in some sectors of the basin outside the Nigerian border in a structurally related contiguous basin. Fair to poor quality source rocks are inherent in the sequences penetrated by the studied wells. About 80% of all samples have their total organic carbon (TOC) contents more than 0.5 wt.%, the minimum limit for hydrocarbon generation. Juxtaposition of the hydrogen indices against the TOC and Tmax indicates that the source rocks are entirely gas-prone. However, biomarker chromatograms and extract vs. TOC plots indicate the presence of oil shows in Ziye-1 well at a depth of 1210 m. Although generated hydrocarbons (wherever they have accumulated) would be overwhelmingly gaseous, gas is the energy of the future. The gas resources of this part of Nigeria's inland basins can be economically exploited through policies that will increase the tempo of gas-utilization projects and the construction of a national grid of gas pipelines with nodal points of input and output. 相似文献
Experimental petrologists have successfully located basalticliquid compositions parental to mid-ocean ridge basalt thatare, within experimental resolution, multiply saturated withthree-phase harzburgite or four-phase lherzolite assemblageson their liquidus at some elevated pressure. Such an experimentalresult is a necessary consequence of any paradigm in which eruptedbasalts derive from single-batch primary liquids that equilibratewith a mantle residue and undergo no subsequent magma mixingbefore differentiation and eruption. Here we investigate whether,conversely, such evidence of multiple saturation is sufficientto exclude dynamic melting models wherein increments of meltare mixed after segregation from residues, during melt transportor in magma chambers. Using two independent models of crystalliquidequilibria to simulate polybaric near-fractional peridotitemelting, we find that aggregate liquids from such melting processescan display near-intersections of liquidus surfaces too closeto distinguish experimentally from exact multiple saturationpoints. Given uncertainties in glass compositions, fractionationcorrections, experimental temperature and pressure conditions,and achievement of equilibrium, these results suggest that polybaricmixtures can in fact masquerade as mantle-equilibrated single-batchprimary liquids. Multiple saturation points on the liquidussurfaces of primitive basalts do, however, preserve informationabout the average pressure of extraction of their constituentincrements of liquid. KEY WORDS: mantle melting; basaltic volcanism; experimental igneous petrology; thermodynamic modelling; inverse method相似文献
Experimental simulation of incremental crystal fractionationof a hy-normative hawaiite indicates that the spectrum of compositionsfrom mildly alkalic hawaiite to sodic rhyolite found in silica-saturatedalkalic suites of the ocean islands and continental hotspotsand rifts can be produced by fractionation at 9·3 kbarwith bulk water contents > 相似文献
Direct measurements of the Earth's magnetic field in Italy since 1640 a.d. have been used to check the remanence directions derived from historically dated volcanic rocks of Etna and Vesuvius. Direct measurements consist of the records of L’Aquila and Pola geomagnetic observatories, the repeat stations of the Italian Magnetic Network and the data base of the Historical Italian Geomagnetic Data Catalogue. All have been relocated to the same reference site (Viterbo — lat. 42.45°N, long. 12.03°E) in order to draw a reference secular variation (SV) curve. The direction of the Earth's field at Viterbo has also been calculated from the historical records (2000-1600) of ref. [Jackson, A., Jonkers, A.R.T., Walker, M.R., 2000. Four centuries of geomagnetic secular variation from historical records. Phil. Trans. R. Soc. London, Ser. A 358, 957-990] database. The remanence directions from Etna show a general agreement with the trend of the SV curve, although their inclination is usually lower than that from the direct measurement. The directions from Vesuvius are more scattered. Large discrepancies occur at both volcanoes and in some cases have been ascribed in the literature to poor geographic information, making it difficult to identify the flows actually emplaced during the eruptions reported in the chronicles. Closer examination shows that the great majority of the best-defined remanence directions (semi-angle of confidence α95 < 2.5°) deviate significantly from the geomagnetic direction measured at the time of the emplacement, the angle between the two directions being larger than the α95 value. The value of 2.5-3.0° can thus be regarded as a conservative evaluation of the error when dealing with dating Etna and Vesuvius lava flows older than 17th century, even when the accuracy attained in remanence measurements is higher. In default of a SV curve for Italy derived from archaeological artefacts, a further error in dating is introduced when reference is made to SV curves of other countries, even if well-established, as these are from regions too far from Italy (>600 km) to confidently relocate magnetic directions. 相似文献
Our two newly obtained high-quality 40Ar/39Ar ages suggest that the high-K volcanic rocks of the Lawuxiang Formation in the Mangkang basin, Tibet were formed at 33.5±0.2 Ma. The tracing of elemental and Pb-Sr-Nd isotopic geochemistry indicates that they were derived from an EM2 enriched mantle in continental subduction caused by transpression. Their evidently negative anomalies in HFSEs such as Nb and Ta make clear that there is an input of continental material into the mantle source. The high-K rocks at 33.5±0.2 Ma in the Mangkang basin may temporally, spatially and compositionally compare with the early one of two-pulse high-K rocks in eastern Tibet distinguished by Wang J. H. et al., implying that they were formed in the same tectonic setting. 相似文献
The internal architecture of the immense volumes of eruptive products in Continental Flood Basalt Provinces (CFBPs) provides vital clues, through the constraint of a chrono-stratigraphic framework, to the origins of major intraplate melting events. This work presents close examination of the internal facies architecture and structure, duration of volcanism, epeirogenetic uplift associated with CFBPs, and the potential environmental impacts of three intensely studied CFBPs (the Parana-Etendeka, Deccan Traps and North Atlantic Igneous Province). Such a combination of key volcanological, stratigraphic and chronologic observations can reveal how a CFBP is constructed spatially and temporally to provide crucial geological constraints regarding their development.
Using this approach, a typical model can be generated, on the basis of the three selected CFBPs, that describes three main phases of flood basalt volcanism. These phases are recognized in Phanerozoic CFBPs globally. At the inception of CFBP volcanism, relatively low-volume transitional-alkaline eruptions are forcibly erupted into exposed cratonic basement lithologies, sediments, and in some cases, water. Distribution of initial volcanism is strongly controlled by the arrangement of pre-existing topography, the presence of water bodies and local sedimentary systems, but is primarily controlled by existing lithospheric and crustal weaknesses and concurrent regional stress patterns. The main phase of volcanism is typically characterised by a culmination of repeated episodes of large volume tholeiitic flows that predominantly generate large tabular flows and flow fields from a number of spatially restricted eruption sites and fissures. These tabular flows build a thick lava flow stratigraphy in a relatively short period of time (c. 1–5 Ma). With the overall duration of flood volcanism lasting 5–10 Ma (the main phase accounting for less than half the overall eruptive time in each specific case). This main phase or ‘acme’ of volcanism accounts for much of the CFBP eruptive volume, indicating that eruption rates are extremely variable over the whole duration of the CFBP. During the waning phase of flood volcanism, the volume of eruptions rapidly decrease and more widely distributed localised centres of eruption begin to develop. These late-stage eruptions are commonly associated with increasing silica content and highly explosive eruptive products. Posteruptive modification is characterised by continued episodes of regional uplift, associated erosion, and often the persistence of a lower-volume mantle melting anomaly in the offshore parts of those CFBPs at volcanic rifted margins. 相似文献