Impact of Montmorillonite and Calcite on Release and Adsorption of Cyanobacterial Fatty Acids at Ambient Temperature

Minerals might act as important sorbents of sedimentary organic matter and reduce biodegradation, which favors the formation of hydrocarbon source rocks in the earth's history. Since most organic matter is degraded during the sinking process, at ambient temperature, it is important to investigate the adsorption capacity of different minerals during this process, to assess the organic loss from primary productivity to sedimentary organic matter. In this study, montmorillonite and calcite have been selected to study the impact of different minerals on the release, adsorption, and deposition of cyanobacterial (Synechococcus elonpata) fatty acids (FAs) at ambient temperature. Gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) have been utilized to detect the variation in fatty acids. Primary results suggest that minerals have a different impact on dissolved organic matter. Montmorillonite can specifically enhance the release of fatty acids from cyanobacterial cells by lowering the pH values of the solution. The adsorption of the dissolved organic matter by montmorillonite will also be enhanced under a lower pH value. Conjunction of fatty acids with montmorillonite to form a complex will favor the sinking and preservation of these organics. Selective adsorption is observed among fatty acids with different carbon numbers. In contrast, calcite does not show any impact on the release and adsorption of organic matter even though it is reportedly capable of acting as a catalyst during the transformation of organic matter at high temperature. The primary data bridge a link between primary productivity and sedimentary organic matter, suggesting the relative importance of claystones in the formation of hydrocarbon source rocks in the earth's history.     

酸溶——催化极谱法测定地质样品中的钨、钼

本文采用混合酸溶解样品,对影响催化体系稳定的酸度、温度和不同反应时间的因素分别进行了对比试验,确定催化体系相对稳定的最佳条件,经过大量样品的分析验证,分析方法可靠。     

模拟酸雨及施磷对水稻土中铅的淋溶特性影响

采用pH=3.0、pH=4.5与对照pH=5.6的3种模拟酸雨淋溶土柱的方法,研究酸雨及含磷酸雨淋溶下合肥市郊水稻土中铅的释放特征与规律。结果表明:经过相当于1 980 mm降水量的淋溶后,铅释放量总体上表现为随着酸雨强度增加累积淋溶量也增加的现象。酸雨作用下,施磷量越多土壤中铅的淋失总量越大。在酸雨及施磷条件下,大兴地区黄褐土中Pb较义城地区水稻土中易于淋失。     

火山沉积岩及其矿床研究中伽马测井曲线解释的误区

根据酸性凝灰岩和酸性火山事件粘土岩的自然伽马测井曲线,对当前流传的"沉积岩层的放射性强度(或放射性核素的含量)随泥质含量的增加而增高"的概念和用自然伽马值及经验公式求泥质含量提出质凝。酸性凝灰岩的自然伽马曲线有高异常响应,若解释为泥岩显然是误解,故将沉积岩伽马曲线高异常一律解释为泥岩是片面的。各类火山事件粘土岩的伽马值相差悬殊,但其泥质含量几乎相等,用它们的伽马值计算泥质含量误差甚大。最后对铝土矿层的伽马曲线稍加解释,指出核测井应用的远景。     

Interaction of copper with fatty acids in Soxhlet extraction and its influence

Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry （ICP-OES）, thermal analysis （TG-DSC） and Fourier Transform Infrared spectroscopy （FFIR）. Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one.     

大冶铁矿国家矿山公园规划实践

大冶铁矿的开发利用在为我国的钢铁事业作出巨大贡献的同时,也给矿区的地表环境、森林资源带来了很大的破坏。矿山公园的规划实施可极大地改善矿山环境,为矿山的可持续发展提供较好的途径。     

江苏新沂市露采矿山地质环境现状及恢复治理措施

新沂市的矿产资源开发利用程度低,潜力大,矿山开采规模小、资源浪费严重,采矿毁坏土地和植被,破坏生态环境,对自然地貌景观破坏严重;采矿掘进面高差大,边坡陡立,埋下诱发山体崩塌、滑坡等地质灾害隐患,易造成人员伤亡事故;露采矿山地质环境整治滞后,绝大多数露采矿山地质环境没有得到有效整治。根据露采矿山开采中存在的问题,提出了包括管理措施、工程技术措施和经济政策措施等地质环境恢复治理措施。     

江苏镇江韦岗铁矿区深部找矿前景分析

镇江韦岗铁矿是一个已经勘查开发数十年的老矿山,目前保有资源储量保证程度已达严重危机。分析矿区成矿地质条件和矿床特征,铁矿体主要分布在碳酸盐岩层与中酸性侵入岩的接触带上,铁矿体普遍磁性强,且在地表形成一定规模的磁异常,梯度北陡南缓,向南有规则地递减呈梯形散开,说明矿体有一定的延伸。深部已施工的见矿钻孔和井中磁测异常对应,反映矿区深部-200m～-800m找矿前景良好。     

黑龙江省矿山主要环境地质问题及防治对策

黑龙江省在矿产资源开采过程中产生了诸多的矿山环境地质问题。这些矿山环境地质问题可分为资源毁损、地质灾害、环境污染3大类。又可细分为土地资源压占、植被资源破坏、地下水位下降、风景景观和地质遗迹破坏、地面塌陷、地裂缝、崩塌、滑坡、泥石流、煤层自燃、煤矸石自燃、水土侵蚀、土地沙化、盐碱化、草原退化、水污染、土壤污染、大气污染等种类。这些矿山环境问题给黑龙江省的经济发展和生态环境造成了巨大的损失和危害。论文阐述了主要矿山环境问题及其危害,并提出了有关防治对策建议,以促进黑龙江省矿山环境保护与治理工作的进步。     

广西佛子冲铅锌矿田成岩成矿时代研究

广西佛子冲铅锌矿田位于桂东南博白-岑溪多金属成矿带的NE端,区内发育燕山期花岗岩、花岗闪长岩、二长花岗斑岩和英安质凝灰熔岩等;其中花岗闪长岩和二长花岗斑岩与铅锌成矿关系密切,成矿岩体形成时代分别为156Ma和127Ma。