全文获取类型
收费全文 | 3641篇 |
免费 | 720篇 |
国内免费 | 1085篇 |
专业分类
测绘学 | 194篇 |
大气科学 | 210篇 |
地球物理 | 492篇 |
地质学 | 3401篇 |
海洋学 | 507篇 |
天文学 | 6篇 |
综合类 | 342篇 |
自然地理 | 294篇 |
出版年
2024年 | 12篇 |
2023年 | 36篇 |
2022年 | 93篇 |
2021年 | 134篇 |
2020年 | 138篇 |
2019年 | 167篇 |
2018年 | 140篇 |
2017年 | 116篇 |
2016年 | 174篇 |
2015年 | 201篇 |
2014年 | 302篇 |
2013年 | 248篇 |
2012年 | 247篇 |
2011年 | 292篇 |
2010年 | 245篇 |
2009年 | 284篇 |
2008年 | 252篇 |
2007年 | 280篇 |
2006年 | 314篇 |
2005年 | 210篇 |
2004年 | 171篇 |
2003年 | 183篇 |
2002年 | 162篇 |
2001年 | 154篇 |
2000年 | 143篇 |
1999年 | 124篇 |
1998年 | 113篇 |
1997年 | 90篇 |
1996年 | 81篇 |
1995年 | 53篇 |
1994年 | 56篇 |
1993年 | 52篇 |
1992年 | 37篇 |
1991年 | 26篇 |
1990年 | 19篇 |
1989年 | 21篇 |
1988年 | 10篇 |
1987年 | 17篇 |
1986年 | 14篇 |
1985年 | 12篇 |
1984年 | 13篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1976年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有5446条查询结果,搜索用时 15 毫秒
111.
The effect of elevated nitric acid concentrations on cloud particle number concentrations and sizes of mixed phase cirrus cloud (containing both supercooled liquid and frozen ice particles) is studied using a detailed multicomponent condensation model. Our model calculations suggest that high nitric acid volume mixing ratios (VMRs), corresponding to upper tropospheric measurements, can increase the ice crystal number concentrations substantially especially in the case of freezing of non-activated solution droplets (as opposed to freezing of supercooled cloud droplets). This is due to increased droplet sizes caused by nitric acid absorption and the resulting uptake of water. 相似文献
112.
Javier Castro-Larragoitia Utz Kramar Harald Puchelt 《Journal of Geochemical Exploration》1997,58(1):81-91
The Ag---Pb---Zn---Cu---Au mining district of Santa María de La Paz has been extensively exploited for approximately 200 years. Consequences of these activities are several deposits of tailings with high As and heavy metal concentrations, which are completely unstable. The climate is semiarid and as the dumps have no protective cover, material from the dumps is dispersed by strong winds. It is also washed out during seasonally heavy rainfalls. By these processes approximately 100 km2 of surrounding have been contaminated by dump material. The As and heavy metal content of the soils was determined as well as their level in crops (Zea Maize) from agricultural lands in the vicinity of the dumps. In the direction of prevailing winds concentrations up to 1000 ppm Zn, 400 ppm Pb, 16 ppm Cd, 550 ppm Cu and 300 As have been detected in top soils. Using fuzzy cluster analysis the different contamination sources could be identified. Grains of corn from contaminated sites showed no critical concentrations, but leaves which are also used tor fodder, have As-concentrations up to 20 ppm. 相似文献
113.
铅—试铁灵络合物吸附波及溴化十六烷基三甲基铵增敏效应的研究 总被引:1,自引:0,他引:1
在030mol/LHAc介质中,Pb(Ⅱ)与7_碘_8_羟基喹啉_5_磺酸(试铁灵,Feron)的络合物于-054V(vs.SCE)产生一尖锐的极谱波,加入溴化十六烷基三甲基铵(CTMAB)显著增敏,可使极谱波增高约4倍。峰电流与Pb(Ⅱ)浓度在96×10-9~48×10-6mol/L呈良好的线性关系,检出限为48×10-9mol/L。用多种电化学方法研究了该极谱波的性质及电极反应机理表明,络合物组成比为nPb(Ⅱ)∶nFeron=1∶1,极谱波为吸附波,峰电流由中心离子Pb(Ⅱ)还原产生,电子转移数为2。试验了多种离子对峰电流的影响,拟定的方法用于矿样分析,结果与原结果相符。 相似文献
114.
本文剖析了柿竹园钨锡钼铋矿床地勘阶段地质观察粗浅,勘探投入超前,探明储量积压、B+C级储量比例偏大等不合理的勘查工作及其原因。在此基础上,探讨矿区合理的勘探程度,储量比例及由此带来的经济效益。 相似文献
115.
Summary This paper explores an approach to estimation of the viscoelastic parameters of weak floor strata using plate-loading tests. Mathematical equations are derived to describe deformation-time history for the standard Burgers model under three-dimensional stress-strain conditions, which are verified with a finite element model. A number of time-dependent in-mine plate-loading tests were conducted and the values of the viscoelastic parameters were estimated based on the derived equation. It is shown that large discrepancies between the parameter values estimated from the plate-loading tests and those acquired from the in-mine convergence data are the results of neglecting adjacent pillar interaction. Finite element modelling was conducted to investigate the effects of adjacent pillar interactions upon the pillar settlement. Based on the finite element analyses, a correction curve was developed to adjust the viscoelastic parameter values to take into account the interaction between adjacent pillars. With the correction, the parameter values estimated from the plate-loading tests compared favourably with those acquired from the in-mine convergence results. 相似文献
116.
Acid mine drainage (AMD) occurs when sulfide minerals are exposed to an oxidizing environment. Most of the methods for preventing
AMD are either short-term or high cost solutions. Coating with iron phosphate is a new technology for the abatement of AMD.
It involves treating the sulfide with a coating solution composed of H2O2, KH2PO4, and sodium acetate as a buffer agent. The H2O2 oxidizes the sulfide surface and produces Fe3+ so that iron phosphate precipitates as a coating on the sulfide surface. Experiments performed under laboratory conditions
prove that an iron phosphate coating can be established on pyrrhotite surfaces with optimal concentrations of the coating
solution in the range of: 0.2M/0.01M H2O2, 0.2M KH2PO4, and 0.2M sodium acetate NaAc, depending on the experimental scale. Iron phosphate coating may be a long-term solution to
the problem of AMD. The method would be easy to implement; the reagent cost, however, is not low enough, although it is lower
than the conventional treatment with lime.
Received: 30 March 1995 · Accepted: 6 September 1995 相似文献
117.
118.
The focus of this research was to determine if abandoned mines constitute a major environmental hazard in the Black Hills. Many abandoned gold mines in the Black Hills contribute acid and heavy metals to streams. In some areas of sulfide mineralization local impacts are severe, but in most areas the impacts are small because most ore deposits consist of small quartz veins with few sulfides. Pegmatite mines appear to have negligible effects on water due to the insoluble nature of pegmatite minerals. Uranium mines in the southern Black Hills contribute some radioactivity to surface water, but the impact is limited because of the dry climate and lack of runoff in that area. 相似文献
119.
N. F. Gray 《Environmental Geology》1996,27(4):358-361
Both sulfate and conductivity are useful indicators of acid mine drainage (AMD) contamination. Unlike pH, they are both extremely sensitive to AMD even where large dilutions have occurred. The advantage of using sulfate to trace AMD is that unlike other ions it is not removed to any great extent by sorption or precipitation processes, being unaffected by fluctuations in pH. These two parameters are also closely associated as would be expected, as conductivity is especially sensitive to sulfate ions. Therefore, as sulfate analysis is difficult in the field, conductivity can be used to predict sulfate concentration in both AMD and contaminated surface waters using regression analysis. Most accurate predictions are achieved by using equations given for specific conductivity ranges or AMD sources. There is also potential to use conductivity to predict approximate concentrations of key metals when the pH of the water is within their respective solubility ranges. 相似文献
120.
催化分光光度法测定痕量钛 总被引:2,自引:0,他引:2
催化分光光度法测定痕量钛周之荣1吴伟华东地质学院应化系江西临川344000催化褪色光度法测定钛的报道较少[1],本文研究了痕量Ti(Ⅳ)催化过氧化氢氧化酸性铬蓝K褪色反应的影响因素,建立了测定痕量Ti(Ⅳ)的催化光度法,并用于测定植物及人发中钛。方法... 相似文献