Chemical Profiles across a Jurassic Stratiform Manganese Deposit at Katsuyama in the Mino Terrane of Central Japan: Implications for Depositional Environment, Diagenetic Metal Redistribution and Paleoceanography

Abstract. Inorganic chemical compositions are determined for a series of rocks crossing an Early Jurassic stratiform manganese ore deposit in a chert‐dominant sequence at Katsuyama, in the Mino Terrane of central Japan. The lithology in the vicinity of the manganese ore bed is classified into lower bedded chert, black shale, massive chert, manganese ore and upper bedded chert, in ascending order. The rocks surrounding the manganese deposit are anomalously high in certain elements: Pb (max. 29 ppm), Ni (1140) and Co (336) in the lower bedded chert, Mo (438), As (149), Tl (29) and U (12) in the black shales, V (210) and Cr (87) in the massive chert, and MnO and W (24) in the manganese ore. The aluminum‐normalized profiles reveal a distinct zonation of redox‐sensitive elements: Pb‐Zn, Ni‐Co‐Cu(‐Zn) and U‐Cr in the lower bedded chert, Mo‐As‐Tl in the black shale, V(‐Cr) in the massive chert, and Mn‐Fe‐Ba‐W in the manganese ore, in ascending order. The lower and upper bedded cherts and manganese ore generally exhibit flat rare earth element patterns with positive Ce anomalies, whereas the uppermost part of the lower bedded chert, the black shale and massive chert have flat patterns with weak or nonexistent negative Ce anomalies and weak positive Eu anomalies. The strong enrichment in Ni, Co, W, Tl and As detected in the Katsuyama section is not recognized in other sediments, including those of anoxic deposition origin, but is identified in modern ferromanganese nodules, suggesting that metal enrichment in the Katsuyama section is essentially due to the formation of ferromanganese nodules rather than to deposition in an anoxic environment. The observed elemental zonation is well explained by equilibrium calculations, reflecting early diagenetic formation and associated gradual reduction with depth. The concentration profiles in combination with litho‐ and biostratigraphical features suggest that formation of these bedded manganese deposits was triggered by an influx of warm, saline and oxic water into a stagnant deep ocean floor basin in Panthalassa at the end of the middle Early Jurassic. Paleoceanographic environmental controls thus appear to be important factors in the formation and preservation of this type of stratiform manganese deposit.     

Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.     

全球早古生代造山带(Ⅱ):俯冲-增生型造山

全球早古生代增生造山带极其发育,主要分布在古亚洲洋南北两侧、Iaeptus洋南侧、Rheic洋北侧和环冈瓦纳大陆地带,其中原特提斯洋封闭的产物主要发育在中国境内,大量微陆块在早古生代可能都是冈瓦纳北缘的俯冲-增生带中的重要组成。增生造山带中组成复杂,具有沟-弧-盆体系、海山、洋壳等残存记录,尤以榴辉岩发育为特征,增生造山成为早古生代古亚洲洋和特提斯洋构造体系的显著独特特征。早古生代末中亚早古生代造山带多为微陆块增生造山阶段,沟-弧-盆体系发育,具有增生-软碰撞造山的特点,发生时限较晚,为早古生代末;原特提斯洋中的西昆仑、东昆仑、柴达木北缘、南阿尔金、北阿尔金与北祁连、北秦岭等围限或夹杂的微陆块在早古生代具有相同的增生造山过程,整体是向南俯冲线性增生到冈瓦纳大陆北缘,现今多次重复是早古生代弯山构造所致。400 Ma左右,南部古特提斯洋和北部勉略带的打开,导致其北漂,经复杂变形改造,它们现今为一巨型弯山构造横亘在中国中部,对中国构造格局影响最为重要。     

西藏南羌塘增生杂岩中俯冲反向驱动高压变质岩折返:来自猫耳山大型拆离断层的启示

大洋岩石圈俯冲增生过程中可能伴随着复杂的深部板片运动过程。高压变质岩无疑是记录这些深部过程的良好载体。最近的研究提出,在特定情况下,双向俯冲中占主导的俯冲板块拖曳另一侧板块发生反向运动,从而短板片可能被另一侧长板片拖出。该研究提示我们关注俯冲增生过程中这种可能的“不正常”的板片运动方式,从而客观而全面地剖析碰撞造山带。现有高压变质岩折返模式中,除了俯冲隧道流模式,其余模式均强调单次快速折返。然而,俯冲反向运动导致的折返过程有所不同:对单个高压变质岩来说仍是快速折返,但是对整体高压变质岩带来说,整个俯冲反向期间必然都存在高压变质岩折返,从而形成较长的折返过程持续时间。对上地壳层次的折返相关构造变形的研究有助于揭示上述过程。     

Pore-water geochemistry in methane-seep sediments of the Makran accretionary wedge off Pakistan: Possible link to subsurface methane hydrate

Cold seeps are pervasive along the continental margin worldwide,and are recognized as hotspots for elemental cycling pathway on Earth.In this study,analyses of pore water geochemical compositions of one-400 cm piston core(S3) and the application of a mass balance model are conducted to assess methane-associated biogeochemical reactions and uncover the relationship of methane in shallow sediment with gas hydrate reservoir at the Makran accretionary wedge off Pakistan.The results revealed that approximately 77% of sulfate is consumed by the predominant biogeochemical process of anaerobic oxidation of methane.However,the estimated sulfate-methane interface depth is-400 cm below sea floor with the methane diffusive flux of 0.039 mol/(m~2·a),suggesting the activity of methane seepage.Based on the δ~(13)C_(DIC) mass balance model combined with the contribution proportion of different dissolved inorganic carbon sources,this study calculated the δ~(13)C of the exogenous methane to be-57.9‰,indicating that the exogenous methane may be a mixture source,including thermogenic and biogenic methane.The study of pore water geochemistry at Makran accretionary wedge off Pakistan may have considerable implications for understanding the specific details on the dynamics of methane in cold seeps and provide important evidence for the potential occurrence of subsurface gas hydrate in this area.     

东特提斯地质调查研究进展综述

以青藏高原为主体的东特提斯构造演化一直是国内外地学研究中关注的重大科学问题.为了更全面、更深入地认识青藏高原及东特提斯构造域的形成演化历史,本文在综述前人有关特提斯构造域时空演变和演化阶段研究的基础上,重点总结了近年来1∶5万区域地质调查中取得的最新研究进展,提出昌宁-澜沧构造带原-古特提斯连续演化、南冈底斯构造带古-...     

Refining accretionary orogen models for the Tasmanides of eastern Australia

The well-known southwest-to-northeast younging of stratigraphy over a present-day cross strike distance of >1500 km in the southern Tasmanides of eastern Australia has been used to argue for models of accretionary orogenesis behind a continually eastwards-rolling paleo-Pacific plate. However, these accretionary models need modification, since the oldest (ca 530 Ma) outcrops of Cambrian supra-subduction zone rocks occur in the outboard New England Orogen, now ～900 km east of the next oldest (520–510 Ma) supra-subduction zone rocks. This is not consistent with simple, continuous easterly rollback. Instead, the southern Tasmanides contain an early history characterised by a westwards-migrating margin between ca 530 and ca 520 Ma, followed by rapid eastwards rollback of the paleo-Pacific plate from 520 to 502 Ma that opened a vast backarc basin ～2000 km across that has never been closed. From the Ordovician through to the end of the Carboniferous, the almost vertical stacking of continental margin arcs (within a hundred kilometres of each other) in the New England Orogen indicates a constant west-dipping plate boundary in a Gondwana reference frame. Although the actual position of the boundary is inferred to have undergone contraction-related advances and extension-related retreats, these movements are estimated to be ～250 km or less. Rollback in the early Permian was never completely reversed, so that late Permian–Triassic to Cretaceous arcs lie farther east, in the very eastern part of eastern Australia, with rifted fragments occurring in the Lord Howe Rise and in New Zealand. The northern Tasmanides are even more anomalous, since they missed out on the middle Cambrian plate boundary retreat seen in the south. As a result, their Cambrian-to-Devonian history is concentrated in a ～300 km wide strip immediately west of Precambrian cratonic Australia and above Precambrian basement. The presence in this narrow region of Ordovician to Carboniferous continental margin arcs and backarc basins also implies a virtually stationary plate boundary in a Gondwana frame of reference. This bipolar character of the Tasmanides suggests the presence of a segmented paleo-Pacific Plate, with major transform faults propagating into the Tasmanides as tear faults that were favourably oriented for the formation of local supra-subduction zone systems and for subsequent intraplate north–south shortening. In this interpretation of the Tasmanides, Lower–Middle Ordovician quartz-rich turbidites accumulated as submarine fan sequences, and do not represent multiple subduction complexes developed above subduction zones lying behind the plate boundary. Indeed, the Tasmanides are characterised by the general absence of material accreted from the paleo-Pacific plate and by the dominance of craton-derived, recycled sedimentary rocks.     

The Zoulang Nanshan Caledonian Subduct ion Complex in the Northern Qilian Mountains and Its Dynamics

The front of the Zoulang Nanshan Caledonian volcanic island arc zone in the northern Qilian Mountains is a forearc accretionary terrane, composed of multiple accretionary volcanic island arcs, flysch accretionary wedges,high-pressure metamorphosed detachment zones and remnants of ophiolites. It resulted from the northeastward subduction of the Early Palaeozoic Qilan oceanic crust beneath the Alxa block. High-pressure metamorphism, which occurred during the subduction, progressed through three stages: the initial stage of medium T-high P,the main stage of temperature decrease and pressure increase, and the lag stage of pressure decrease and temperature increase. Finally the paper presents a retrotrench subduction dynamic model indicative of northward subduction of the central Qilian block and southward accretion of the Alxa block during the period of 450-500 Ma.     

Early deformation fabrics of melange in the Mesozoic Waipapa Terrane, North Island, New Zealand

Abstract The Waipapa Terrane in northern North Island, New Zealand, is a Mesozoic accretion-ary complex formed along the Gondwana margin. It contains abundant melange rocks with distinctive characteristics. Precise analyses of their mesoscopic fabrics in Waiheke Island near Auckland have revealed the following sequence of deformation. The earliest phase of deformation of the sandstone/mudstone association, which is the main constituent of this terrane, originated by chaotic mixing of sand and mud due to liquidization of water-saturated, poorly consolidated sediments. The second phase was characterized by hydrofracturing and subsequent forceful injection of ductile mud into rather brittle sand. Local intrusions of sand forming dykes and sills followed these events, as well as intrusions of pelagic/hemipelagic green argillite originally underlying the sandstone/mudstone association. An abundant occurrence of these mixing and multi-stage injection/intrusion fabrics strongly suggest that the Waipapa Terrane around the study area was a site of high pore-fluid pressure. Scaly-foliated melange fabrics with monoclinic symmetry, originating from layer-parallel shearing, were then locally superimposed on the pre-existing melange fabrics. Similar scaly-foliated fabrics also developed in the chert beds originally intercalated between the green argillite and the uppermost part of the oceanic crust. These scaly fabrics might have been related to the regional stacking and juxtaposition of the accreted sediments. The sequence and variation in style of deformation forming the melange fabrics presumably reflected changes in porosity and state of compaction of accreted sediments in a shallow tectonic level.     

Geomorphological study on a clastic accretionary prism: The Nankai Trough

Abstract The Nankai Trough, off southwest Japan, is one of the best sites for the study of geomorphic characteristics of a clastic accretionary prism. A recent multibeam survey over the central and eastern parts of the Nankai accretionary prism has revealed a large variation of the topography along the trough axis. Analysis of the bathymetric data suggests the existence of prism deformational features of different scales, such as depressions, embayment structures and cusps. These structures are the results of slope instability caused by basement relief of subducted oceanic plate. Unstable slopes recover by new accretion and development of a low angle thrust. Small-scale deformation due to the subduction of a small isolated seamount is then adjusted to the regional trend. By contrast, a 30 km indentation of the wedge observed in the eastern part of the Nankai Trough, the Tenryu Cusp, has seemed to retain its geometry. The subducted Philippine Sea plate has deformed greatly near the eastern end of the Nankai Trough, because of the collision between the Izu-Ogasawara (Bonin) arc and central Japan. Therefore, the indentation may be the result of the continuous subduction of a basement high, such as the Zenisu Ridge, which has been formed under north-south compression due to the arc-arc collision.