On the scavenging of gaseous nitrogen compounds by large and small rain drops I. A wind tunnel and theoretical study of the uptake and desorption of NH3 in the presence of CO2

An experimental study has been carried out in the Mainz vertical wind tunnel to determine the rate at which NH₃ in the presence of CO₂ is absorbed by freely suspended water drops. The experimental uptake rates were found to be in good agreement with the rates predicted by the Kronig-Brink convective diffusion model and, for gas concentrations in the ppbv range also by the model in which it is assumed that the absorbed gas is well mixed inside the drop (henceforth called well mixed model). The same conclusion was shown to apply also to the desorption of NH₃ from a drop previously exposed to NH₃. The latter result is in contrast to the desorption of SO₂ which must be described by a model which accounts for the diffusion of the species inside the drop. Comparison of our experimental results with theory show further that the uptake of NH₃ in presence of CO₂ is significantly overestimated if the slow reaction CO_2(aq)+H₂OHCO ₃ ^– +H⁺ is neglected in the theoretical computation.     

应用断层气氡进行地震监测预报

概述了断层气氡观测点的地理位置,地质环境和观测条件,用最优周期谱持和多元逐步回归分析方法对观测资料进行了详细分析,分析结果表明观测曲线具有“冬高夏低”的年动态变化和固体潮变化特征。其中固体潮变化是断层气氡进行地震监测预报的力不基础。     

Immobilization of Cu and As in two contaminated soils with zero-valent iron – Long-term performance and mechanisms

Immobilization of trace elements in contaminated soils by zero-valent iron (ZVI) is a promising remediation method, but questions about its long-term performance remain unanswered. To quantify immobilization and predict possible contaminant remobilization on long timescales detailed knowledge about immobilization mechanisms is needed. This study aimed at assessing the long-term effect of ZVI amendments on dissolved copper and arsenic in contaminated soils, at exploring the immobilization mechanism(s), and at setting up a geochemical model able to estimate dissolved copper and arsenic under different scenarios. Samples from untreated and ZVI-treated plots in two field experiments where ZVI had been added 6 and 15 years ago were investigated by a combination of batch experiments, geochemical modeling and extended X-ray absorption fine structure (EXAFS) spectroscopy. Dissolved copper and arsenic concentrations were described by a multisurface geochemical model with surface complexation reactions, verified by EXAFS. The ZVI remained “reactive” after 6–15 years, i.e. the dissolved concentrations of copper and arsenic were lower in the ZVI-treated than in the untreated soils. There was a shift in copper speciation from organic matter complexes in the untreated soil to surface complexes with iron (hydr)oxides in the ZVI-treated soil. The pH value was important for copper immobilization and ZVI did not have a stabilizing effect if pH was lower than about 6. Immobilization of arsenic was slightly pH-dependent and sensitive to the competition with phosphate. If phosphate was ignored in the modeling, the dissolution of arsenate was greatly underestimated.     

The Cyclic Spectrum Analysis of IMFs of EMD and Its Application to Gravity Tide

IMFs sifted out by EMD are the FM-AM components. In the paper, by the cyclic spectrum analysis, IMFs are demodulated as the two periodic components which are identical to the intrinsic physical concepts. Using the method, the half-day-tide M₂, the day-tide O₁, and the half-month-tide M_f are extracted from the gravity tide signal, and a conclusion is drawn that the half-day-tide M₂ and the day-tide O₁ are primary components of gravity tide signal, and the half-month-tide M_f is modulated in the half-day-tide M₂ and the day-tide O₁.     

水合铁离子及铁络合物吸收系数光谱(400-900 nm)测量

测量铁化合物溶解物的吸收光谱曲线是水中铁离子含量遥感反演的关键。采用自主设计的水体透射光测量装置,利用ASD光谱仪测量相同厚度不同浓度铁离子溶液的透射光辐亮度,然后运用比值法计算出水中3种铁化合物(硫酸铁、氯化铁和铁氰化钾)的消光系数和吸收系数,最终得到400—900 nm波长范围内3种铁离子吸收系数光谱。该方法可以较好地消除实验装置和水中悬浮物的影响。结果表明,水中3种铁离子均在紫蓝光波段吸收作用较大,绿光次之,逐渐减少至红光波段后,吸收系数变化很小呈平缓直线。测量结果可作为水体铁离子浓度遥感反演模型所需的基础参数。     

Effect of Band Width on Fatigue Life under Random Stress Response

A fatigue life estimation method for offshore structures under random stress response is studied in this paper. The method of broad band cumulative frequency number is used to determine the effect of band width of stress frequency spectra on fatigue. A formula of correction factor for fatigue under broad band stress spectra is suggested and compared with that given by P. H. Wirsching.     

海参中微量元素的分析

本文用原子吸收分光光度法研究黑乳参(Holothuria nobilis Seleka)和刺参(StiChops japonicus Selenka)样品的消化方法,并测定样品中11种微量元素(K,Ca,Mg,Fc,Co,Ni,Mn,Cu,Cd,Pb,Zn)的含量。结果表明,这些海参样品,用干法或湿法消化均可得到满意结果。作者还将部分元素的分析结果与阳极溶出伏安法和交流示波极谱滴定法相对照,其结果一致。     

Numerical Simulated Study on the Separation of Oblique Incident and Reflected Waves

The Goda's method of separating the frequency spectrum of the unidirectional incident and reflected waves is improved. The proposed method can be applied to the separation of oblique incident and reflected waves and the two wave gauges can be arranged in an arbitrary angle in front of a structure. When the projected distance of the two probes on the incident wave direction is the multiple ofthe half length of the incident waves, the singular problem will emerge by using the method. It is advised that when the projected distance of the two measured points on the incident wave direction is 0.05～0.45 times the wave length of peak frequency wave, good results can be obtained. The simulated resultant waves are separated by the method of numerical simulation and the separated wave spectra are basically corresponding to the target spectra input. The wave trains calculated by the separated incident and reflected wave frequency spectrum are approximated to the input wave trains and the reflected coefficient can be derived correctly. Therefore, the method proposed in this paper is reliable.     

Automated trinocular stereo imaging system for three-dimensional surface wave measurements

A novel automated trinocular stereo imaging system (ATSIS) is developed for non-intrusively measuring the temporal evolution of three-dimensional wave characteristics. The system consists of three progressive digital cameras to provide three independent stereo-pairs, i.e. left–right, left–center, and center–right, for accurately estimating depth of a scene. A third camera assists to resolve correspondence problems due to specular reflection on the water surface and provides additional constraints on image matching, dramatically reducing the chance of a mismatch. An oblique configuration for the trinocular system effectively increases spatial coverage, allowing observations of wave phenomena over a broad range of spatial scales. The height resolution is increased with the optical axes of the cameras pointed at an oblique angle with respect to vertical surface wave displacements. A new exterior calibration procedure is developed in this paper to determine the orientation of cameras in the field. Field experiments demonstrate that ATSIS can robustly measure hundreds of matched image points in seconds, allowing fast extraction of the temporal evolution of a three-dimensional surface wave field.     

Transformation of Wave Energy Spectrum in Shallow Water

- Combined with irregular wave-maker, the growing process of Wave Energy Spectrum in shallow water can be studied in wind wave channel on different water depth conditions, and its transformation characteristics and rules can be obtained.