经验加速度补偿对HY-2A卫星精密定轨的影响

针对HY-2A卫星定轨中存在系统误差的问题,该文提出了加入经验加速度补偿系统误差。为了获得HY-2A卫星的高精度轨道,采用星载DORIS距离变率数据探索了经验加速度对定轨精度的影响。探讨了1d、3d和7d作为经验加速度周期的定轨精度差异,分析了3d作为经验加速度周期时在径向、法向和切向3个方向设置经验加速度对定轨精度的不同影响。研究结果表明:HY-2A卫星在径向和切向不存在系统误差,而在法向存在系统误差,因而在法向设置经验加速度进行力学模型补偿能够取得较好的定轨结果;3d作为经验加速度的补偿周期较为合适,不仅能够减少解算参数个数,缩短计算时间,而且径向定轨精度可达到1.00cm,满足HY-2A卫星精密定轨需求。     

Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy

Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample).     

Identification of Uranyl Minerals Using Oxygen K‐Edge X‐Ray Absorption Spectroscopy

Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant.     

ASTER mapping of gypsum deposits of Thumrait region of southern Oman

This study demonstrates the use of ASTER data for the mapping of gypsum deposits and associated geological formations that occurred in the Thumrait region of southern Oman. The measurement of spectra over samples of gypsum in the 1,300–2,500 nm wavelength using a PIMA spectrometer showed the presence of distinct absorptions at 1400–1600, 1750, 1940, 2,100, and 2,400 nm characteristics to O? H stretching, H₂O combinations, and S? O bending overtones and stretching, respectively. Studying the unique spectral absorption characters of gypsum samples, we developed a false color composite (FCC) and an image by decorrelation stretch using the spectral bands 7, 3, and 2 of ASTER. The results FCC showed the regions of gypsum occurrences, and the decorrelated image discriminated the gypsum occurrences from other geological formations of the area. The study of surface mineralogy of the region using the VNIR‐SWIR bands by the spectral angle mapper method showed the presence of sulfate, carbonate, and clay minerals of the geological formations in the study area. We compared the results of ASTER with the results obtained using spectral bands 12, 8, and 4 of Sentinel‐2A processed by the same methods. The study showed that the spectral bands of ASTER can be used for mapping the gypsum and associated geological formations.     

Absorption of Arsenite on Several Iron （Hydro-）Oxides and Impact from Pre-processing Methods

The absorption reactions of arsenite on Fe （hydro-）oxides are studied. The three absorbent types are Fe（OH）3 gel and two Fe （hydro-）oxides, in which the Fe（OH）3 gel was dried in a microwave oven under vacuum at 80℃. It is found that pH changes from 9.71 to 10.36 in 6 minutes after the Fe （OH）3 gel was mixed with NaAsO2 solution, as the arsenite replaces the OH- in goethite and Fe（OH）3. At the 40th minute after the start of the reaction, pH decreases, which is most probably because that the monodentate surface complex of absorbed arsenite has changed into mononuclear-bidentate complex and released proton. The decline in pH values indicates not the end of the absorption but a change in the reaction type. Temperature and dissolved gas has little effect on these two types of reactions. The total absorption of arsenite increases after the absorbent is irradiated with ultrasound, which also lead to difficulty in separating the solids from solution. The absorption capacity for arsenite of Fe（OH）3 gel dried in a microwave oven under vacuum is 53.18% and 17.22% respectively better than that of Fe （OH）3 gel and gel dried at 80℃. The possible reasons are that the water molecules in the gel vibrates with high frequency under the effect of microwave irradiation, thereby producing higher porosity and improved surface activity.     

电镀金刚石钻头镀前超声清洗机理及工艺研究

电镀金刚石钻头镀前清洗是钻头生产的关键制造工艺.超声清洗作为一种精清洗技术,在不少领域获得了成功.本文阐述了超声波对金刚石钻头镀前清洗工艺的适应性,分析了电镀金刚石钻头中的主要清洗对象及超声清洗机理,对超声清洗中的各项工艺参数及工艺流程进行了研究,说明了超声清洗的经济适用性及可操作性.     

浏阳河流域生态补偿标准额度动态估算

生态补偿标准是生态补偿研究发展的关键问题,特别是以定量的方式量化补偿金额.以浏阳河流域为研究区,提出了基于单位面积价值当量因子的生态服务功能价值评估法.该方法利用GIS技术对研究区生态服务功能价值进行动态评估,并将皮尔生长曲线模型和表征社会经济发展水平的恩格尔系数相结合计算生态补偿系数,最终构建得到单位面积生态补偿标准...     

由粒子吸收光谱提取浮游植物吸收光谱的人工神经网络方法

基于现场实验数据集及人工神经网络技术,论文提出了一种从海中粒子吸收光谱提取浮游植物吸收光谱的方法。这个数据集包含了海中粒子吸收光谱和对应的浮游植物吸收光谱,并被分为三个子集:训练集、印证集和试验集。本研究所利用的人工神经网络系统为多层感知器,训练后的人工神经网络的性能由印证集和试验集来评价。实验结果表明,文中所提出的方法可成功地提取浮游植物的吸收光谱,其提取精度与传统的实验方法相当。     

Analysis on the effect of salinity in underwater wireless optical communication

Abstract

This article deals with the effect of salinity variation on underwater wireless optical communication (UWOC). Effect of different concentration of salt on underwater optical communication has been carried out experimentally in terms of received power at different link lengths. Based on the analysis of experimental data, a mathematical model has been proposed to describe the saline water channel. A simulation study is performed for different data rates and link lengths. It is seen that with increased salinity the attenuation is higher and the UWOC system performance degrades with higher data rate and increased link length.     

点吸收式波浪能俘获装置结构优化方法研究

根据布设海域波浪能资源特征,对点吸收式波浪能装置结构进行优化,可有效提高装置的能量俘获效率。本文以威海褚岛北部海域为装置布设目标海域,在对该海域波浪资源特征进行统计分析的基础上,计算得到装置的直径,同时利用数值软件计算出多组工况下点吸收装置吃水深度和装置固有周期的对应关系,并利用统计学方法得出装置固有周期随吃水深度的变化规律,进而分析得出装置在该海域的最佳设计吃水深度,为点吸收波浪能装置结构优化设计提供了新的思路。该方法对于其他技术类型波浪能装置的结构优化设计同样具有借鉴意义。