溶剂萃取原子吸收光谱法测定高纯石英砂中痕量铁

高纯石英砂用HF等溶剂溶解并蒸干后,在微酸性介质中用抗坏血酸还原Fe^3＋为Fe^2＋,与1,10-二氮杂菲形成Fe2＋3络合物,加入适量ClO4^-阴离子与之形成离子缔合物,用硝基苯萃取,原子吸收测定有机相,本法检出限1.1μg/g,样品分析结果的RSD%为：4.52～10.3.     

强震作用下铁路隧道横通道交叉结构抗震措施研究

依托四川茂县跃龙门铁路隧道工程,以主线单线隧道与横通道正交结构为研究对象,通过ABAQUS建立有限元分析模型。选取El-Centro地震波数据,通过应用扩展有限元理论,对横通道与主隧道交叉结构在最不利地震条件下的裂损进行研究,并提出减震层结合柔性接头的抗震措施。研究分析得到:减震层结合柔性接头的设置减小并抑制了交叉结构隧道在强震作用下的开裂范围。柔性接头的设置阻止了纵向裂缝的扩展,在交叉口处中部设置环向柔性接头能完全阻止交叉部位拱顶的裂缝生成;在初期支护和二次衬砌之间设置减震层,给予衬砌更大变形空间,使二次衬砌不易受初期支护变形受力影响而开裂。     

建筑抗震实时混合试验时滞补偿方法研究综述

时滞补偿是建筑抗震实时混合试验的重要问题。文章对时滞补偿方法的研究进行总结,将时滞补偿方法分为基于时间的位移预测时滞补偿方法、基于反馈力的位移预测时滞补偿方法、基于加载系统模型求逆的时滞补偿方法、基于控制理论的时滞补偿方法和基于集成理念的综合补偿方法。     

海洋沉积物中铜含量测量不确定度评定 ——电热板加热消解法与微波消解法的比对

电热板加热消解法和微波消解法是目前海洋沉积物样品消解的常用方法。为了比较这两种处理方法对检测结果准确性的影响程度,文章依据《测量不确定度的评定与表示》技术规定中的相关要求对海洋沉积物中铜含量测定过程中采取的两种消解方法进行了不确定度评定与对比,建立了模型,并对各不确定度分量进行分析和量化,计算出两种消解方法测量沉积物中铜含量的相对合成不确定度分别为0.06721和0.04033,扩展不确定度分别为4.0mg/kg和2.4mg/kg。通过比较两种消解方法对测定结果不确定度的贡献,发现微波消解法明显优于电热板加热法。     

蓖齿眼子菜的光合速率及影响因素

本文研究了蓖齿眼子菜(Potamogeon pectinatus L)在滇池的光合速率、体内叶绿素季节变化及光和水温对其光合速率影响,并根据实验,计算出了蓖齿眼子菜生长的光补偿点,研究结果表明,蓖齿眼子菜1～3月份的净光合产氧量最大,为1.82～1.83mg/(g·h),6月份最低,为0.63 mg/(g·h);植物体内Chl.a和Chl.b平均含量分别为0.25～1.15mg/(g·h)和0.28～0.85mg/(g·h),蓖齿眼子菜可以通过调节体内Chl.a/Chl.b值来适应不同季节生长;蓖齿眼子菜有较宽的水温适应范围,10℃时的净光合产氧量可达0.88mg/(g·h),最高值出现在水温25℃,为1.16mg/(g·h),而30℃以上的水温已表现出对其生长的不利影响;蓖齿跟子菜生长的光补偿点为358～1256Lx,并随温度上升而逐渐增加.     

夏季新安江水库(千岛湖)颗粒物吸收光谱特征分析

通过对2013年夏季新安江水库(千岛湖)53个站点悬浮颗粒物的吸收光谱进行研究,系统分析了总颗粒物吸收系数ap(λ)、非藻类颗粒物吸收系数ad(λ)和浮游藻类光谱吸收系数aph(λ)的变化规律以及影响因素.结果表明:总颗粒物吸收除西北河流区上游段外,其他各站点均呈现出明显的浮游藻类吸收特性,反映新安江水库总颗粒物中浮游藻类贡献较高.全库ap(440)在0.068 ～0.629 m-1之间变化,西北河流区总颗粒物吸收系数显著大于其他水域,而湖泊区与西南河流区则显著小于其他水域.非藻类颗粒物吸收光谱随着波长增加大致呈现出指数函数衰减的规律,其光谱斜率Sd均值为8.52±1.62μm-1,存在显著的空间差异,但整体偏低,与新安江水库无机颗粒物含量低有关.ad (440)与浮游藻类色素浓度存在显著的线性相关,表明夏季新安江水库非藻类颗粒物可能主要来源于浮游藻类降解.浮游藻类的光谱吸收在440和675 nm附近有明显的吸收峰.aph(440)和aph(675)存在显著的空间差异,其与浮游藻类色素浓度存在极显著的正线性关系,而与总悬浮颗粒物浓度相关性较弱.     

Predictive optimal control for seismic analysis of non-linear and hysteretic structures

In this paper, an effective active predictive control algorithm is developed for the vibration control of non-linear hysteretic structural systems subjected to earthquake excitation. The non-linear characteristics of the structural behaviour and the effects of time delay in both the measurements and control action are included throughout the entire analysis (design and validation). This is very important since, in current design practice, structures are assumed to behave non-linearly, and time delays induced by sensors and actuator devices are not avoidable. The proposed algorithm focuses on the instantaneous optimal control approach for the development of a control methodology where the non-linearities are brought into the analysis through a non-linear state vector and a non-linear open-loop term. An autoregressive (AR) model is used to predict the earthquake excitation to be considered in the prediction of the structural response. A performance index that is quadratic in the control force and in the predicted non-linear states, with two additional energy related terms, and that is subjected to a non-linear constraint equation, is minimized at every time step. The effectiveness of the proposed closed-open loop non-linear instantaneous optimal prediction control (CONIOPC) strategy is presented by the results of numerical simulations. Since non-linearity and time-delay effects are incorporated in the mathematical model throughout the derivation of the control methodology, good performance and stability of the controlled structural system are guaranteed. Copyright © 1999 John Wiley & Sons, Ltd.     

冲击荷载下玄武岩纤维水泥土吸能及分形特征

为研究玄武岩纤维对水泥土冲击破坏过程中能量吸收及碎块块度分布特征的影响,采用Φ50 mm变截面霍普金森压杆（split Hopkinson pressure bar,简称SHPB）试验装置对不同玄武岩纤维掺量的水泥土进行了冲击压缩和动态劈裂试验,分析了冲击荷载作用下玄武岩纤维掺量与水泥土吸收能、破坏形态和分形维数 的关系,试验结果表明：随着玄武岩纤维掺量的增加,水泥土吸收能呈先增大后减小的趋势,超过最佳掺量后,由于纤维-纤维薄弱面的存在,水泥土吸收能减少;冲击破坏后水泥土破碎块度分布是具有统计意义上的分形,冲击压缩试验中水泥土破碎块度平均粒径随玄武岩纤维掺量的增加而不断增大,对应的 值总体上呈现不断减小的趋势;在动态劈裂试验中,玄武岩纤维掺量在0～2.0%范围内,水泥土破碎块度平均粒径呈现上升趋势, 值不断减小,玄武岩纤维掺量超过2.0%后,平均粒径有所降低,对应 值增大。玄武岩纤维水泥土吸收能和 值之间有着密切的联系,冲击压缩试验中,吸收能在分形维数为2.20～2.26范围内呈先增大后减小的趋势,而在动态劈裂试验中,吸收能在分形维数为1.85～2.20范围内总体呈现下降趋势,两者具有一定的负相关性;合适掺量的玄武岩纤维对水泥土动态特性起着积极作用,通过试验得出玄武岩纤维的合适掺量为1.5%～2.0%。     

大连市滨海湿地现状及加强管护工作对策研究

文章利用遥感技术获取了大连市2016年滨海湿地基本状况信息,通过实地调查和查阅资料基本摸清了研究区水鸟及栖息地概况,收集整理了研究区开展滨海湿地管理与保护工作情况,简要阐释了当前滨海湿地管护工作中存在的功能退化等问题,辨识性分析了引发问题的填海造地、建设力度与保护经费不足等驱动力因素,提出了应从健全滨海湿地管理与保护制度机制、加大新建保护区与已建保护区管护工作力度、开展生态修复工作、开展滨海湿地生态补偿工作、严格自然滨海湿地开发利用管理和加强滨海湿地调查监测6个方面加强滨海湿地管护工作的对策及建设性意见。     

Progress in the Research on Benefit-sharing and Ecological Compensation Mechanisms for Transboundary Rivers

Transboundary rivers have important geopolitical and geo-economic connotations, but riparian states of transboundary rivers are often driven by their own rapid population growth and economic development to be-come involved in regional conflicts about the development and use of water resources. Therefore, finding a balance between the need for fair and reasonable development of water resources and the effective protection of environment from an ecological perspective has become a major problem faced by the international community. This paper begins with consideration of international water laws related to transboundary rivers and then reviews advances in the research on benefit-sharing, ecological compensation mechanisms, and adaptive management systems. We believe that existing international water laws form a complete legal system and that more attention needs to be paid to transboundary cooperation and sustainable water resource use. With respect to how transboundary water conflicts are resolved, there is a trend to move away from single water resource allocation (a zero-sum game) to benefit-sharing in order to achieve a win-win situation for riparian states, but there are still some difficulties in transboundary ecological compensation. In China, the central government has paid attention to horizontal ecological compensation between upstream and downstream, offering guidance to promote establishment of inter-province ecological compensation. Based on existing practice, horizontal ecological compensations are still in their infancy, small in scale, supported by a weak legal system, lacking market mechanisms to encourage their use and relying on fiscal transfers as the method of payment. In the future, China will need to intensify its research on legal system development, international cooperation, and benefit-sharing as these impact transboundary water resources. Because government can be seen as a management department with multiple identities (enabler, regulator and buyer), to improve adaptive transboundary ecological compensation mechanisms, government must develop as soon as possible data sharing platforms, standards of water consumption behaviors and intergovernmental policies (or ordinances).