Sorption of carbon dioxide–methane mixtures

The paper reports the results of experiments concerning the sorption/desorption processes, observed under laboratory conditions, in two types of coal extracted from operational coal-mines in Poland, using CH₄ and CO₂ to observe their relative inter-reaction with the coal samples when introduced in varying proportions and conditions. Numerous studies concerning the sorption/desorption phenomena have described the operational mechanisms and the relationship of mine gases to the organically-created coal-body in mines. The differences in the behaviour of certain gases is twofold: firstly the essentially different characteristics of CO₂ and CH₄, and secondly the structure of the coal-bed itself: its degree of metamorphism and content of macerals. From the results yielded, it was observed that the divergence of the isotherms of sorption of CH₄ and other gases in comparison with the isotherms of sorption of CO₂ and a CO₂/CH₄ mixture differed and that the curve on the sorption isotherm was more clearly distinct after the introduction of CO₂ molecules to the system: coal with a higher degree of metamorphism—CH₄, which is closely related to the rigidity of the structure according to the level of metamorphism. Since coals with higher carbon content exhibit lower molecular bonding than low-carbonised coals, the characteristic feature of the bonds in the first case is their mobility. Knowledge of the physical and chemical properties of hard coals, as well as their interaction with mining gases, is of great use in solving problems concerned with the extraction of methane from mines or its storage in goafs.     

Numerical modeling of toxic nonaqueous phase liquid removal from contaminated groundwater systems: mesh effect and discretization error estimation

Numerical modeling has now become an indispensable tool for investigating the fundamental mechanisms of toxic nonaqueous phase liquid (NAPL) removal from contaminated groundwater systems. Because the domain of a contaminated groundwater system may involve irregular shapes in geometry, it is necessary to use general quadrilateral elements, in which two neighbor sides are no longer perpendicular to each other. This can cause numerical errors on the computational simulation results due to mesh discretization effect. After the dimensionless governing equations of NAPL dissolution problems are briefly described, the propagation theory of the mesh discretization error associated with a NAPL dissolution system is first presented for a rectangular domain and then extended to a trapezoidal domain. This leads to the establishment of the finger‐amplitude growing theory that is associated with both the corner effect that takes place just at the entrance of the flow in a trapezoidal domain and the mesh discretization effect that occurs in the whole NAPL dissolution system of the trapezoidal domain. This theory can be used to make the approximate error estimation of the corresponding computational simulation results. The related theoretical analysis and numerical results have demonstrated the following: (1) both the corner effect and the mesh discretization effect can be quantitatively viewed as a kind of small perturbation, which can grow in unstable NAPL dissolution systems, so that they can have some considerable effects on the computational results of such systems; (2) the proposed finger‐amplitude growing theory associated with the corner effect at the entrance of a trapezoidal domain is useful for correctly explaining why the finger at either the top or bottom boundary grows much faster than that within the interior of the trapezoidal domain; (3) the proposed finger‐amplitude growing theory associated with the mesh discretization error in the NAPL dissolution system of a trapezoidal domain can be used for quantitatively assessing the correctness of computational simulations of NAPL dissolution front instability problems in trapezoidal domains, so that we can ensure that the computational simulation results are controlled by the physics of the NAPL dissolution system, rather than by the numerical artifacts. Copyright © 2014 John Wiley & Sons, Ltd.     

Diagnosing snow accumulation errors in a rain‐snow transitional environment with snow board observations

Diagnosing the source of errors in snow models requires intensive observations, a flexible model framework to test competing hypotheses, and a methodology to systematically test the dominant snow processes. We present a novel process‐based approach to diagnose model errors through an example that focuses on snow accumulation processes (precipitation partitioning, new snow density, and snow compaction). Twelve years of meteorological and snow board measurements were used to identify the main source of model error on each snow accumulation day. Results show that modeled values of new snow density were outside observational uncertainties in 52% of days available for evaluation, while precipitation partitioning and compaction were in error 45% and 16% of the time, respectively. Precipitation partitioning errors mattered more for total winter accumulation during the anomalously warm winter of 2014–2015, when a higher fraction of precipitation fell within the temperature range where partition methods had the largest error. These results demonstrate how isolating individual model processes can identify the primary source(s) of model error, which helps prioritize future research.     

Improved spatial delineation of streambed properties and water fluxes using distributed temperature sensing

A new method was developed for analysing and delineating streambed water fluxes, flow conditions and hydraulic properties using coiled fibre‐optic distributed temperature sensing or closely spaced discrete temperature sensors. This method allows for a thorough treatment of the spatial information embedded in temperature data by creating a matrix visualization of all possible sensor pairs. Application of the method to a 5‐day field dataset reveals the complexity of shallow streambed thermal regimes. To understand how velocity estimates are affected by violations of assumptions of one‐dimensional, saturated, homogeneous flow and to aid in the interpretation of field observations, the method was also applied to temperature data generated by numerical models of common field conditions: horizontal layering, presence of lateral flow and variable streambed saturation. The results show that each condition creates a distinct signature visible in the triangular matrices. The matrices are used to perform a comparison of the behaviour of one‐dimensional analytical heat‐tracing models. The results show that the amplitude ratio‐based method of velocity calculation leads to the most reliable estimates. The minimum sensor spacing required to obtain reliable velocity estimates with discrete sensors is also investigated using field data. The developed method will aid future heat‐tracing studies by providing a technique for visualizing and comparing results from fibre‐optic distributed temperature sensing installations and testing the robustness of analytical heat‐tracing models. Copyright © 2016 John Wiley & Sons, Ltd.     

基于“一张图”平台的国土资源执法监察系统设计与研究

从土地执法监察管理的实际需求出发,探讨了基于"一张图"平台的国土资源执法监察系统建设方案,设计了土地执法监察系统结构和功能模块,并进一步给出了土地执法监察数据库建设和数据交换的技术方法。该系统方案的应用将有利于快速、准确地监控国土资源违法行为,强化对国土资源违法行为的监控能力,有效地提高了国土部门执法监察工作效率和执法水平。     

地面三维激光扫描仪测量误差检定

在利用三维激光扫描仪进行测量工作前,我们首先应了解其实际测量精度是否符合标称精度,而可靠的评价方式对得到精确的数据结果至关重要。本文利用北京卓立汉光TSA50-C型电动位移台作为评价标准,通过其精确的位移功能,准确地评价了RIGEL VZ-400三维激光扫描仪在测量单点位移时的误差,从而得到了其最佳工作距离。     

GPS精密卫星钟差估计研究

随着精密单点定位技术的发展,对于精确的卫星坐标以及卫星钟差改正精度的要求越来越高,精密卫星星历以及精密卫星钟差的求解成为制约精密单点定位技术发展的瓶颈。本文基于修复周跳的载波相位观测值与相位平滑伪距观测值,采用无电离层延迟星间单差精密卫星钟差估计模型,在先估计出整周模糊度后,进行了精密卫星钟差的估计,并采用与IGS事后精密钟差作二次差的方法进行精度分析,这对于提高精密单点定位精度具有一定的意义。     

AEKF在星敏感器低频误差补偿中的应用

高分辨率对地观测卫星需要精确的姿态信息来满足后续对地定位等工作,因此姿态确定精度十分重要。星敏感器的低频误差是影响卫星姿态确定精度的重要因素之一,主要是由空间周期性的热环境变化引起的。为进一步提高卫星姿态确定精度,对星敏感器的低频误差产生机理即星敏感器主光轴做周期性扰动进行了分析,设计了星敏感器低频误差补偿方案,建立了考虑星敏感器低频误差在内的组合定姿模型,利用拓维卡尔曼滤波(AEKF)对低频误差进行补偿,并引入RTS平滑滤波进一步提高姿态确定精度。仿真实验表明,设计的星敏感器低频误差补偿方案能有效对其进行补偿,提高卫星姿态确定精度。     

Possible sources of forecast errors generated by the global/regional assimilation and prediction system for landfalling tropical cyclones. Part I: Initial uncertainties

This paper investigates the possible sources of errors associated with tropical cyclone (TC) tracks forecasted using the Global/Regional Assimilation and Prediction System (GRAPES). The GRAPES forecasts were made for 16 landfalling TCs in the western North Pacific basin during the 2008 and 2009 seasons, with a forecast length of 72 hours, and using the default initial conditions (“initials”, hereafter), which are from the NCEP-FNL dataset, as well as ECMWF initials. The forecasts are compared with ECMWF forecasts. The results show that in most TCs, the GRAPES forecasts are improved when using the ECMWF initials compared with the default initials. Compared with the ECMWF initials, the default initials produce lower intensity TCs and a lower intensity subtropical high, but a higher intensity South Asia high and monsoon trough, as well as a higher temperature but lower specific humidity at the TC center. Replacement of the geopotential height and wind fields with the ECMWF initials in and around the TC center at the initial time was found to be the most efficient way to improve the forecasts. In addition, TCs that showed the greatest improvement in forecast accuracy usually had the largest initial uncertainties in TC intensity and were usually in the intensifying phase. The results demonstrate the importance of the initial intensity for TC track forecasts made using GRAPES, and indicate the model is better in describing the intensifying phase than the decaying phase of TCs. Finally, the limit of the improvement indicates that the model error associated with GRAPES forecasts may be the main cause of poor forecasts of landfalling TCs. Thus, further examinations of the model errors are required.