Thermodynamic modeling of binary CH4–CO2 fluid inclusions

An equation of state (EOS) explicit in Helmholtz free energy has been improved to calculate the PVTx and vapor–liquid phase equilibrium properties of CH₄–CO₂ fluid mixture. This EOS, where four mixing parameters are used, is based on highly accurate EOSs recommended by NIST for pure components (CH₄ and CO₂) and contains a simple generalized departure function presented by Lemmon and Jacobsen (1999). Comparison with experimental data available indicates that the EOS can calculate both vapor–liquid phase equilibrium and volumetric properties of this binary fluid system with accuracy close to that of experimental data up to high temperature and pressure within full range of composition. The EOS of CH₄–CO₂ fluid, together with the updated Gibbs free energy model of solid CO₂ (dry ice), is applied to calculate the CH₄ content (x_CH4) and molar volume (V_m) of the CH₄–CO₂ fluid inclusion based on the assumption that the volume of an inclusion keeps constant during heating and cooling. $V_{\text{m}}-x_{{\text{CH}}_4}$ diagrams are presented, which describe phase transitions involving vapor, liquid and CO₂ solid phases of CH₄–CO₂ fluid inclusions. Isochores of CH₄–CO₂ inclusions at given $x_{{\text{CH}}_4}$ and V_m can be easily calculated from the improved EOS.     

Thermal equation of state of majorite with MORB composition

In situ synchrotron X-ray diffraction experiments were conducted using the SPEED-1500 multi-anvil press at SPring-8 on majoritic garnet synthesized from natural mid-ocean ridge basalt (MORB), whose chemical composition is close to the average of oceanic crust, at 19 GPa and 2200 K. Pressure-volume-temperature data were collected using a newly developed high-pressure cell assembly to 21 GPa and 1273 K. Data were fit to the high-temperature Birch-Murnaghan equation of state, with fixed values for the ambient cell volume (V₀ = 1574.14(4) Å³) and the pressure derivative of the isothermal bulk modulus (K^′T = 4). This yielded an isothermal bulk modulus of K_T0 = 173(1) GPa, a temperature derivative of the bulk modulus (∂K_T/∂T)_P = −0.022(5) GPa K⁻¹, and a volumetric coefficient of thermal expansivity α = a + bT with values of a = 2.0(3) × 10⁻⁵ K⁻¹ and b = 1.0(5) × 10⁻⁸ K⁻². The derived thermoelastic parameters are very similar to those of pyrope. The density of subducted oceanic crust compared to pyrolitic mantle at the conditions in Earth's transition zone (410-660 km depth) was calculated using these results and previously reported thermoelastic parameters for MORB and pyrolite mineral assembledges. These calculations show that oceanic crust is denser than pyrolitic mantle throughout the mantle transition zone along a normal geotherm, and the density difference is insensitive to temperature at the pressures in lower part of the transition zone.     

基于Zoeppritz方程的纵横波模量反演

叠前地震反演的主要目的是根据地震数据精确地求取地下介质的弹性参数,进而进行流体识别和油藏描述.常规叠前反演方法使用Zoeppritz方程近似式计算反射系数,但是含有丰富信息的大偏移距地震数据无法被有效利用,针对这个问题,将纵横波模量引入Zoeppritz方程,建立了基于Zoeppritz方程的纵横波模量广义线性反演方法,适用于大角度地震数据.模型测试和实际地震资料应用表明,此方法能够可靠的得到地下介质的纵横波模量,相对于间接反演减小了间接反演带来的累积误差,为后续流体识别和含油气检测提供了很好的数据基础.     

Effect of pressure on the thermal expansion of MgO up to 8.2 GPa

Isobaric volume measurements for MgO were carried out at 2.6, 5.4, and 8.2 GPa in the temperature range 300–1073 K using a DIA-type, large-volume apparatus in conjunction with synchrotron X-ray powder diffraction. Linear fit of the thermal expansion data over the experimental pressure range yields the pressure derivative, (∂α/∂P) _T , of −1.04(8) × 10⁻⁶ GPa⁻¹ K⁻¹ and the mean zero-pressure thermal expansion α_{0, T}  = 4.09(6) × 10⁻⁵ K⁻¹. The α_{0, T} value is in good agreement with results of Suzuki (1975) and Utsumi et al. (1998) over the same temperature range, whereas (∂α/∂P) _T is determined for the first time on MgO by direct measurements. The cross-derivative (∂α²/∂P∂T) cannot be resolved because of large uncertainties associated with the temperature derivative of α at all pressures. The temperature derivative of the bulk modulus, (∂K _T/∂T) _P , of −0.025(3) GPa K⁻¹, obtained from the measured (∂α/∂P) _T value, is in accord with previous findings. Received: 2 April 1999 / Revised, accepted: 22 June 1999     

The Environmental benefits and costs of conservation tillage

 Every production practice, including conservation tillage, has positive or negative environmental consequences that may involve air, land, water, and/or the health and ecological status of wildlife. The negative impacts associated with agricultural production, and the use of conventional tillage systems in particular, include soil erosion, energy use, leaching and runoff of agricultural chemicals, and carbon emissions. Several of these impacts are quantified. The conclusions suggest that the use of conservation tillage does result in less of an adverse impact on the environment from agricultural production than does conventional tillage by reducing surface water runoff and wind erosion. Additionally, wildlife habitat will be enhanced to some extent with the adoption of conservation tillage and the benefits to be gained from carbon sequestration will depend on the soil remaining undisturbed. Finally, further expansion of conservation tillage on highly erodible land will unquestionably result in an increase in social benefits, but the expected gains will be modest.     

Temperature and Water Vapor Weighting Functions from Radiative Transfer Equation with Surface Emissivity and Solar Reflectivity

Linearization of Radiative Transfer Equation (RTE) is the key step in physical retrieval of atmospheric temperature and moisture profiles from InfRared (IR) sounder observations. In this paper, the successive forms of temperature and water vapor mixing ratio component weighting functions are derived by applying one term variation method to RTE with surface emissivity and solar reflectivity contained. Retrivals of temperature and water vapor mixing ratio profiles from simulated Atmospheric Infrared Sounder (AIRS) observations with surface emissivity and solar reflectivity are presented.     

An evaluation of the universal soil loss equation and field techniques for assessing soil erosion on a tropical alfisol in western Nigeria

Four techniques for soil erosion assessment were compared over two consecutive seasons for bare-fallow plots and a maize-cowpea sequence in 1985 at IITA, Ibadan, Nigeria. The techniques used were: tracer (aluminium paint), nails (16 and 25), the rill method, and the Universal Soil Loss Equation (USLE). Soil loss estimated by these techniques was compared with that determined using the runoff plot technique. There was significantly more soil loss (P < 0·01) in bare-fallow than in plots under maize (Zea mays) or cowpea (Vigna unguiculata). In the first season, soil loss from plots sown to maize was 40·2 Mg ha^?1 compared with 153·3 Mg ha^?1 from bare-fallow plots. In the second season, bare-fallow plots lost 87·5 Mg ha^?1 against 39·4 Mg ha^?1 lost from plots growing cowpea. The techniques used for assessing erosion had no influence on the magnitude of soil erosion and did not interfere with the processes of erosion. There was no significant difference (P < 0·05) between soil erosion determined by the nails and the runoff plot technique. Soil loss determined on six plots (three under maize, three bare-fallow) by the rill technique, at the end of the season, was significantly lower (P < 0·05) than that determined by the runoff plot technique. The soil loss estimated by the rill method was 143·2, 108·8 and 121·9 Mg ha^?1 for 11, 11, and 8 per cent slopes respectively, in comparison with 201·5, 162·0, and 166·4 Mg ha^?1 measured by the runoff plot method. Soil loss measured on three bare-fallow plots on 10 different dates by the rill technique was also significantly lower (P < 0·01) than that measured by the runoff plot. In the first season the USLE significantly underestimated soil loss. On 11, 11, and 8 per cent slopes, respectively, soil loss determined by the USLE was 77, 92, and 63 per cent of that measured by the runoff plot. However, in the second season there was no significant difference between soil loss determined by the USLE and that determined by the conventional runoff plot technique.     

Using GIS-based distributed soil loss modeling and morphometric analysis to prioritize watershed for soil conservation in Bago river basin of Lower Myanmar

Bago River is an important river in Myanmar. Although shorter than other rivers, it has its own river system, and people along the river rely heavily on it for their daily lives. The upper part of the watershed has changed rapidly from closed forest to open forest land in the 1990s. Since the recent degradation of the forest environment, annual flooding has become worse during the rainy season in Bago City. This paper aims at determining soil conservation prioritization of watershed based on soil loss due to erosion and morphometric analysis in the Bago Watershed by integrating remote sensing and geographic information system (GIS) techniques. In this study, soil erosion of the Bago watershed was determined using the Universal Soil Loss Equation. Such factormaps as rainfall, soil erodibility, slope length gradient, and crop management were compiled as input parameters for the modeling; and the soil loss from 26 sub-watersheds were estimated. Then, the soil erosion maps of the Bago watershed for 2005 were developed. The resulting Soil Loss Tolerance Map could be utilized in developing watershed management planning, forestry management planning, etc.     

用HJ-1B IRS数据反演海表温度的2种辐射传输方程改进算法

针对使用NCEP再分析数据和辐射传输方程法反演SST出现偏差较大的问题,以HJ-1B SST反演为例,从修正大气透过率入手,提出中心点算法和均值点算法2种辐射传输方程改进算法。2种改进算法对大气透过率偏差和HJ SST反演偏差均有明显改善,反演的HJ SST与MODIS SST均呈现显著的一致性。MODIS SST验证表明2种改进算法的平均偏差和均方差在0.5 ℃左右;浮标SST验证表明均值点算法的反演精度较高,其平均偏差为0.55 ℃,而中心点算法的为0.81 ℃。