安徽庐枞盆地罗河铁矿床中榍石LA-ICP-MS U-Pb定年及其意义

罗河铁矿床位于长江中下游铁铜金成矿带庐枞矿集区,已探明资源量约10亿吨,是成矿带内最大的铁矿床。矿床主成矿阶段广泛发育热液成因榍石,以榍石-硬石膏-磷灰石组合为特征,在矿床-800~-900m和-1500~-1600m两个不同深度稳定发育,为确定成矿时代和成矿流体演化提供了良好的研究对象。本次工作对罗河铁矿床深部和浅部两层矿体中热液榍石开展了年代学及地球化学研究,结果表明榍石中存在(Al,Fe)~(3+)+(F,OH)~-=Ti~(4+)+O~(2-)置换反应,并富含Zr、Nb和REE等元素。榍石中Zr含量估算矿床成矿温度约700℃,指示玢岩型矿床比矽卡岩型铁矿床具有更高的成矿温度,高温条件有利于Ti元素的迁移。榍石的稀土元素配分图均呈现出明显右倾,并具较高的稀土元素总量以及明显的负Eu异常特征,轻稀土富集表明其结晶早于磷灰石和绿帘石等矿物,形成于高温热液环境,不同深度榍石的Eu异常变化表明成矿流体的氧逸度从深部到浅部有所升高。热液榍石原位微区LA-ICPMS U-Pb定年结果表明,上、下两层榍石形成时代分别为130.0±0.9Ma和129.1±0.8Ma~129.7±0.8Ma,表明罗河铁矿床两层矿体是同一成矿系统的在不同深度的产物。矿床成矿时代与区内隐伏闪长岩体成岩时代一致,结合矿床地质特征研究,本文认为闪长玢岩是矿床的成矿母岩。罗河铁矿床属于燕山晚期岩浆热液活动的产物,形成于区域早白垩世岩石圈减薄的环境。     

锆石U-Pb定年对大兴安岭东北部“兴华渡口群”形成时代和组成的约束

兴华渡口群等大兴安岭北部前寒武纪变质岩系的组成和演化对于确定额尔古纳和兴安地块的构造属性具有重要意义,是近年大兴安岭北部基础地质研究的热点之一。本次工作通过对黑河北部石灰窑—明智山一带的兴华渡口群二云石英片岩和"混合岩"进行锆石LA-ICP-MS U-Pb定年发现该变质岩系并非前寒武纪变质岩,而是由早古生代碎屑沉积岩(或变质岩)和晚古生代岩浆岩经后期构造岩浆作用改造而形成的构造杂岩。其中二云石英片岩中具有岩浆成因特征的碎屑锆石核部年龄主要存在401~427 Ma、442~448 Ma、473~517 Ma、639~714 Ma、757~818Ma、896~933 Ma和1704~1751 Ma 7个年龄组,其中473~517 Ma段碎屑锆石的峰最明显,与早古生代多宝山组岛弧火山岩等早古生代岩浆作用形成时间相一致,其他年龄组亦在区域上其他地区有报道,这表明该变质岩的原岩物源来源较广泛,不仅有元古宙岩浆岩和变质岩系,还有大量的早古生代岩浆岩,因此其原岩形成时代不应是前寒武纪,而是早古生代。根据碎屑锆石最小峰值年龄,本次工作推断该二云石英片岩原岩的最大沉积年龄应不早于416Ma,另外大量的元古宙碎屑锆石表明区域上可能存在前寒武纪变质基底。对所谓混合岩的调查发现其应为发生动力变质的糜棱岩化二长花岗岩,其中岩浆锆石(304.5±3.1)Ma的206Pb/238U加权平均年龄反映花岗岩形成于晚石炭世晚期,该期花岗岩为晚古生代兴安地块东缘花岗岩带的一部分。     

内蒙古东乌旗泥盆纪塔尔巴格特组凝灰岩锆石U-Pb年龄及其地质意义

内蒙古东乌珠穆沁旗地区是中国北方造山带内泥盆系最为发育地区之一。前人运用古生物化石确定了该区泥盆纪地层的相对年代,但缺少精确的同位素年龄。本文采用LA-ICP-MS测年技术,对发育在泥盆纪塔尔巴格特组上部的凝灰岩夹层进行了锆石U-Pb同位素测年,获得~(206)Pb/~(238)U加权平均年龄为380.8±1.6 Ma(MSWD=2.7),确定其时代为晚泥盆世早期,为本区泥盆系提供了精确的年代学数据。结合古生物化石组合资料,将塔尔巴格特组时代确定为中泥盆世吉维特期—晚泥盆世弗拉期。     

新疆东天山哈尔里克奥陶纪的构造属性:来自火山岩LA ICP MS锆石U Pb年代学与地球化学的制约

新疆东天山哈尔里克造山带火山岩为一套酸性—基性岩(流纹岩、英安岩、安山岩、玄武岩)夹火山碎屑岩(凝灰岩)的岩石组合。流纹岩样品的LA ICP MS锆石U Pb定年结果显示,时代为中奥陶世大坪期((4688±91) Ma),代表了该套火山岩的形成年龄。岩石地球化学分析结果显示,该套火山岩SiO2含量介于4912%～7824%,TiO2介于012%～100%,Al2O3介于1131%～2086%;铝饱和指数A/CNK值为080～131(均值为099),里特曼指数σ值为019～386(均值为129),Mg#值为887～4929(均值为3120);富集大离子亲石元素(LILE)Ba、Rb以及轻稀土元素(∑LREE)La、Ce,亏损高场强元素(HFSE)Nb、Ta、Ti等。微量元素和稀土元素的相关图解与比值以及发育的捕获锆石反映了俯冲带岛弧钙碱性火山岩特征,且存在大陆地壳混染作用。综合区域地质资料分析,在早古生代期间(中奥陶世—早志留世),哈尔里克造山带存在大面积的与岛弧演化有关的加里东期岩浆活动,此期间哈尔里克造山带的构造背景为洋壳俯冲有关的岛弧环境,其形成可能与东准噶尔南部克拉麦里洋向南俯冲作用有关。     

北秦岭西段黄牛铺岩体锆石U Pb年代学、岩石地球化学特征及其地质意义

对北秦岭西段黄牛铺岩体进行了LA ICP MS锆石U Pb年代学与岩石地球化学分析。结果显示,黄牛铺岩体的锆石U Pb年龄为(4493±49) Ma,表明其形成时代为晚奥陶世。黄牛铺岩体属于准铝质高钾钙碱性系列,在成因类型上具有I型花岗岩的岩石矿物学与地球化学特征,其稀土元素配分曲线呈轻稀土元素富集、重稀土元素亏损(LREE/HREE=983~1155)、铕弱负异常(δEu=082~095)的右倾型,微量元素Rb、Th、U、Sm等富集,Ta、Nb、Ti、Hf等明显亏损,表现为岛弧岩浆岩的地球化学特征。结合区域地质资料,认为黄牛铺岩体形成于晚奥陶世商丹洋俯冲过程中的岛弧环境,是壳幔岩浆混合作用的产物,这为进一步研究北秦岭的构造演化过程提供了更加充分准确的岩浆活动证据。     

Jurassic Hornblende Gabbros in Dongga, Eastern Gangdese, Tibet: Partial Melting of Mantle Wedge and Implications for Crustal Growth

The Gangdese batholith, more than 2500 km in length, is composed mainly of JurassicMiocene igneous rocks. This batholith is one of the most important constituents of the Tibetan orogenesis and provides an ideal place for study of Neo-Tethyan ocean geodynamic evolution and plateau uplift. Recent studies on the Gangdese Jurassic felsic magmatism highlight its juvenile source. However, important aspects concerning the genesis of the juvenile magmatism and related deep geodynamic evolution are still unclear. Here, we report detailed petrological, geochronological, geochemical, whole-rock Sr-Nd isotopic, and in situ Sr-Hf isotopic data for a recently identified hornblende gabbro in the Dongga area, southern Lhasa sub-block. This hornblende gabbro is dominated by hornblende and plagioclase, dated at Early Jurassic(ca. 180–190 Ma), and characterized by a narrow compositional range in SiO_2(49.38wt%–52.27wt%), MgO(4.08wt%–7.00wt%), FeO(10.43wt%–11.77wt%), Na_2O(2.58wt%–3.51wt%), and K_2O(0.48wt%–1.53wt%). It has depleted isotopic signatures, with whole-rock(~(87)Sr/~(86)Sr)i ratios of 0.7033–0.7043, ε_(Nd)(t) values of +4.90 to +6.99, in situ plagioclase(~(87)Sr/~(86)Sr)i ratios of 0.7034–0.7042, and zircon ε_(Hf)(t) of +12.2 to +16.8. Our results integrated with published data suggest a model of Gangdese juvenile crustal growth by a subduction-related water-enriched mantle wedge. The hydrous partial melting of the lithosphere mantle was triggered by the dehydration of a Neo-Tethyan oceanic slab. This mafic magmatism emplaced in the middle-lower crust of intraoceanic arcs or active continental margins, leading to Jurassic juvenile crustal growth in southern Tibet.     

Chronology and Geochemistry of the Berezitovoe Polymetallic Gold Deposit in Eastern Siberia, Russia and its Geological Significance

The Berezitovoe deposit is a large-sized Au-Ag-Zn-Pb deposit in the east of the SelengaStanovoi superterrane, Russia. Au-Ag orebodies are hosted by tourmaline-garnet-quartz-muscovite metasomatic rocks; Zn-Pb orebodies are hosted by granodiorites, porphyritic granites and tourmalinegarnet-quartz-muscovite metasomatic rocks. These orebodies are surrounded by wall rocks dominated by the Tukuringra Complex granodiorites, porphyritic granites, and gneissic granodiorites. The alteration includes silicification and garnet, sericitization chloritization, carbonatization and kaollinization. LA-ICP-MS U-Pb zircon dating indicates that the gold mineralization can be divided into two stages in the Berezitovoe polymetallic gold deposit(at 363.5 ± 1.5 Ma, and133.4± 0.5).Hornblende-plagioclase gneisses of the Mogocha Group in the study area underwent Paleoproterozoic metamorphism(at 1870 ± 7.8 and 2400 ± 13 Ma), gneissic granodiorite of the Tukuringra Complex yields a late Paleozoic magmatic age(at 379.2 ± 1.1 Ma),and subalkaline porphyritic granitoid of the Amudzhikan Complex yield late Mesozoic magmatic ages(133-139 and 150-163 Ma). Granodiorites of the Tukuringra Complex in the study area have high concentrations of SiO_2(average of 60.9 wt%), are aluminum-oversaturated(average A/CNK of 1.49), are enriched in the large ion lithophile elements(e.g.,K, Rb, and Ba), U, Th, and Pb, are depleted in high field strength elements(e.g., Ta, Nb, and Ti), and have slightly negative Eu and no Ce anomalies in chondrite-normalized rare earth element diagrams.Fluid inclusions from quartz veins include three types: aqueous two-phase, CO_2-bearing three-phase,and pure CO_2. Aqueous two-phase inclusions homogenize at 167℃-249℃ and have salinities of 4.32%-9.47% NaCl equivalent, densities of 0.86-0.95 g/cm~3, and formed at depths of 0.52-0.94 km. In comparison, the C0_2-bearing three-phase inclusions have homogenization temperatures of 265℃-346℃,salinities of 7.14%-11.57% NaCl equivalent, and total densities of 0.62-0.67 g/cm~3. The geochemical and zircon U-Pb data and the regional tectonic evolution of the study area, show that the Berezitovoe polymetallic gold deposit formed in an island arc or active continental margin setting, most probably related to late Paleozoic subduction of Okhotsk Ocean crust beneath the Siberian Plate.     

Geological and Geochemical Constraints on the Newly Discovered Yangchongli Gold Deposit in Tongling Region, Lower Yangtze Metallogenic Belt

The newly discovered Yangchongli gold deposit is a unique independent gold deposit in the Tongling ore-cluster region controlled by the tectonic alteration firstly discovered in the Lower Yangtze Metallogenic Belt(LYMB). The host magmatic rocks mainly consist of monzodiorite and K-feldspar granite. The LA-ICP-MS U-Pb zircons dating yielded weighted mean ~(206)Pb/~(238)U ages of 140.7 ± 1.8 Ma and 126.4 ± 1.2 Ma for the monzodiorite and K-feldspar granite, respectively. Monzodiorites are enriched in Sr, Ba, Rb, and depleted in Y, Yb with high Sr/Y and La/Yb ratios, similar to the geochemical features of adakite, considered as products of differentiation of mafic magmas originating from lithospheric mantle melt/fluids caused by metasomatism during paleo-Pacific Plate subduction in the Mesozic. In contrast, the compositions of K-feldspar granites are A-type granites, indicating an extensional tectonic background. Gold ores hosted in the fracture zone occurred as quartz vein within cataclastic rock. Sulfur and lead isotopes from pyrites show crust-mantle mixing characteristics. Metal components from strata also took part in the gold mineralization, and resulted from two episodes of magmatism that were probably related to tectonic transition from a compressive to an extensional setting between 140–126 Ma, which led to the Mesozoic large-scale polymetallic mineralization events in eastern China.     

铼-锇同位素体系定年研究综述

铼-锇(Re-Os)同位素体系以其特殊的地球化学性质为确定岩石的形成时间、演化过程及其地球动力学背景提供了重要参数。随着测试技术和超净化实验室的发展,Re-Os同位素的应用领域不断扩大,测试对象种类也随之扩展。然而,不同测试对象的Re-Os同位素赋存形式、活动特征及其体系封闭性有所差异。文章总结了以辉钼矿、普通硫化物、地幔橄榄岩包体、富有机质沉积岩以及灰岩作为Re-Os同位素体系定年对象的基本原理和研究进展,并对存在问题进行简要地评述,最后对其未来的发展方向作了展望,以期推动Re-Os同位素体系在地质科学中的研究和应用。     

内蒙古东乌旗巴彦都兰铜矿床地质和地球化学特征及其意义

内蒙古巴彦都兰铜矿床位于二连—东乌旗成矿带,该矿区出露下泥盆统泥鳅河组粉砂岩和海西中期黑云母花岗岩体,铜矿体呈脉状产出于泥鳅河组粉砂岩中,严格受断裂控制。主要金属矿物为黄铁矿、磁黄铁矿、黄铜矿等,脉石矿物主要为石英和碳酸盐岩等。矿区黑云母花岗岩La-ICP-MS锆石~(206)Pb/~(238) U加权平均年龄为303.5 Ma±1.1 Ma,铜矿床属于晚古生代构造-岩浆作用的产物。岩石地球化学特征反映黑云母花岗岩属准铝质-弱过铝质高钾钙碱性系列,A/CNK值介于0.99~1.04之间,高碱(w(K_2O+Na_2O)=7.36%~8.73%),富钾(w(K_2O)/w(Na_2O)=1.08~1.66),其形成具有岛弧或后碰撞环境I型花岗岩特征;微量元素特征显示岩体可能形成于后碰撞伸展阶段早期的构造环境中。黄铜矿硫同位素组成介于0.1×10~(-3)~2.1×10~(-3)之间,反映成矿所需的硫可能来自于岩浆,巴彦都兰铜矿区花岗岩很可能是成矿硫的提供者。