内蒙古苏尼特左旗地区阿木乌岩体LA-ICP-MS锆石U-Pb年龄及其地球化学特征

对苏尼特左旗地区阿木乌岩体进行LA-ICP-MS锆石U-Pb测年、主量元素、稀土元素和微量元素测试分析。结果表明,岩体成岩年龄为235.1±3.2 Ma,属中三叠世。岩体具有高SiO2、富K2O、低CaO、低TiO2的特征。强烈亏损Sr、Ba、Ti、P等元素,富集K、Rb、Th等亲石元素,具有右倾"海鸥型"球粒陨石标准化稀土配分型式及强烈的负铕异常等特点。A/CNK=0.77～1.19,A/NK=1.26～1.64,表明阿木乌岩体具有偏铝质A型花岗岩的特征。具有较高的Y/Nb值(2.31～3.001.2),显示出A2型花岗岩的特征,说明岩体形成于造山后的伸展环境。     

湖北省罗田凤凰关混合岩浅色体的类型及其锆石U-Pb年龄

根据混合岩浅色体的重褶、横切和叠加关系并剔除因粘性褶皱效应引起的重褶皱假象，在湖北罗田凤凰关识别出８个世代的浅色体。它们的主量、微量和稀土元素地球化学研究表明，用于锆石Ｕ－Ｐｂ定年的浅色体是深熔成因的。锆石Ｕ－Ｐｂ定年结果表明，在大别杂岩内存在燕山期的混合岩化作用，其时代为（１２９．３．８）Ｍａ。     

祁漫塔格苏鲁格萨依花岗岩LA-ICP-MS锆石U-Pb定年及其地质意义

祁漫塔格是青海省内一个重要的多金属成矿区。近年来,新发现了多处与花岗岩有关的钨、锡、铜、多金属矿床。本文报道了祁漫塔格西段苏鲁格萨依花岗岩LA-ICP-MS锆石U-Pb定年数据,15颗岩浆锆石给出的206Pb/238U年龄加权平均值为(450±5.5)Ma,代表了花岗岩的结晶年龄。结合区域地质背景,认为该岩体形成于祁漫塔格洋由俯冲向碰撞转换的构造背景下。     

黑龙江龙江盆地中侏罗统万宝组时代确定新证据及其地质意义

黑龙江西部大兴安岭地区侏罗纪地层研究程度不高,以往中侏罗世含煤地层的确定主要借助于与吉林西部万宝组的对比。近年来随着新一轮大兴安岭地区含煤及油气地层的区域地质调查工作的开展,笔者在大兴安岭地区中段的龙江盆地（黑龙江省龙江县以西）发现一套新的中侏罗世含煤地层,该地层由砂砾岩和火山碎屑岩夹煤层组成。文中对龙江盆地万宝组火山岩夹层内2件凝灰岩进行了LA-ICP-MS锆石U-Pb定年分析,获得凝灰岩形成时代,其年龄分别为(165.2±1.7) Ma和(162.1±1.6) Ma;笔者采得的植物大化石为Neocalamites Coniopteris Raphaelia组合,时代显示为早-中侏罗世;孢粉化石经初步鉴定,时代倾向于早-中侏罗世;综合同位素年龄及地层古生物研究,笔者认为龙江盆地万宝组的形成时代为中侏罗世晚期。地球化学分析显示：万宝组凝灰岩具有高Si、Al,低Ca、P过铝质钙碱性火山岩特点,富集轻稀土元素,配分曲线呈平缓右倾型,并具有明显负Eu异常;富集大离子亲石元素Cs、Th、U,亏损高场强元素Nb、Ti、Zr,反映火山岩为壳源成因类型。万宝期火山活动可能与古太平洋板块俯冲作用和蒙古-鄂霍茨克缝合带演化双重作用有关,而与蒙古-鄂霍茨克缝合带演化联系更密切。目前中侏罗统万宝组是油气勘探的重要新层系,本研究不仅为大兴安岭东坡地区中侏罗世含煤地层的划分、对比提供同位素年代学和生物地层学依据,而且为龙江盆地形成演化历史及油气资源勘查提供了基础地质新资料。     

Isothermal annealing of partially metamict zircon: evidence for a three-stage recovery process

 Raman spectroscopy and the powder diffraction technique have been used to monitor the recovery process of two partially metamict zircons (2.6 and 4.8 × 10¹⁸ α-decays g⁻¹) from Sri Lanka during a series of isothermal annealing experiments in the temperature range from 870 to 1622 K. These experiments show for the first time that structural recovery in partially metamict zircon proceeds via three distinct recovery stages, each of which occurs within a distinct time-temperature regime. Whereas the first two stages have previously been recognized (recovery of damaged crystalline remnants and epitaxial recrystallization), the third stage has not yet been identified as a single activated process. It is suggested that anisotropic defect annealing during the first stage at low temperatures, where the structure recovers preferentially along the a(b) plane, produces a geometrical situation where large structural rearrangements are necessary to remove the remaining defects inside the crystalline material. This situation is approximately reached when the amorphous domains start to recrystallize. The reason for anisotropic annealing can be found in a different connectivity between polyhedral linkages in both directions of the zircon lattice. High apparent activation energies, in the range of 6.4 to 7.9 eV, were determined for the third recovery stage from the Raman data, which are interpreted to reflect large structural rearrangements (i.e. polyhedral tilting) associated with the final recovery of the c axis. This explains the occurrence of a distinct recrystallization stage without defect annealing. Finally, it should be mentioned that the first recovery stage is not necessarily expected to occur in less damaged zircon crystals (<∼2 × 10¹⁸ α-decays g⁻¹), since less stable defects along the basal plane might have already been self-annealed during radiation damage accumulation under ambient temperatures. Received: 6 September 2001 / Accepted: 25 February 2002     

滇西南团梁子岩组绿片岩、基性脉岩及构造分异石英脉岩锆石U-Pb年龄及其地质意义

滇西南团梁子岩组是南澜沧江构造带内重要的构造岩石单元之一,与兰坪-思茅盆地演化有密切联系。由于层序恢复困难和缺乏标志生物化石,该套岩石地层的时代归属缺乏有效约束。江桥团梁子岩组中基性脉岩和构造分异石英脉岩较为发育,在岩石学观察基础上,以绿片岩、辉长(绿)岩及与区域面理(S2)同期的构造分异石英脉岩为研究对象,借助激光剥蚀等离子体质谱(LA-ICP-MS)技术,对其中分选出的锆石开展了精确的U-Pb年龄测定。2件绿片岩样品31个锆石测点中存在4组206Pb/238U年龄,分别为1816~1542 Ma(加权平均为1630±210 Ma,N=6)、850~832 Ma(加权平均为844±95 Ma,N=2)、517~422 Ma(加权平均为438±26 Ma,N=4)和292~188Ma(加权平均为219.7±8.5 Ma,N=19)。2件辉长(绿)岩样品31个锆石测点中也存在4组206Pb/238U年龄,分别为2256~1357 Ma(加权平均为1646±160 Ma,N=16)、861~750 Ma(加权平均为773±92 Ma,N=2)、484~388 Ma(加权平均为433±38 Ma,N=6)和320~233 Ma(加权平均为253±16 Ma,N=7)。1件构造分异石英脉岩样品20个锆石测点中有3组206Pb/238U年龄,分别为1244±19 Ma(N=1)、430±5 Ma(N=1)和312~212 Ma(加权平均为229.6±6.7 Ma,N=18)。不同类型岩石中的各组锆石206Pb/238U加权平均年龄极为接近,代表了不同的地质意义,其中1646~1630 Ma可能代表了团梁子岩组原岩的形成年龄,而253~219 Ma可能代表了团梁子岩组在此时期受到构造热事件影响,该事件可能与古特提斯洋盆由西向东的俯冲消减作用有关。本次获得的绿片岩、基性脉岩及构造分异石英脉岩锆石U-Pb年龄将团梁子岩组时代约束为老于1630 Ma,即中元古代,可能属澜沧岩群的一部分。     

西藏曲水县达布斑岩铜(钼)矿床成岩成矿年代学研究

本文采用锆石LA-ICP-MS微区U-Pb测年技术,对冈底斯成矿带东段曲水县达布斑岩Cu(Mo)矿床北部达布矿区含矿斑岩体、南部显角囊含矿花岗闪长斑岩岩体进行了年代学研究,通过对3件岩体样品中单颗粒锆石的分析,达布主矿体花岗闪长斑岩样品206Pb/238U年龄加权平均值为16.5±0.05Ma(n=15,MSWD=3),达布主含矿体二长花岗斑岩样品年龄为16.1±0.13Ma(n=15,MSWD=1.03),南部显角囊矿体花岗闪长斑岩年龄为16.2±0.04Ma(n=13,MSWD=0.0064)。对达布矿床斑岩Cu(Mo)矿床主矿体中4件辉钼矿样品,显角囊矿体中6件辉钼矿样品,分别进行了Re-Os同位素测试,等时线年龄分别为14.6±0.50Ma(MSWD=0.35,主矿体)、14.8±0.23Ma(MSWD=1.3,显角囊)。结合前人研究以及本次测年结果认为:1)达布斑岩铜(钼)矿床岩体侵位的年龄应限定在16Ma左右,成矿时代为14Ma左右,成矿时间差小于0.86Ma,与区域上"成矿瞬时发生"的成矿规律是一致的;2)矿床产出于印度-亚洲大陆板块后碰撞伸展环境。     

氟碳铈矿U-Pb定年技术研究

本文以稀土矿床中的常见副矿物氟碳铈矿为研究对象,通过优化实验条件和仪器参数,分别采用激光剥蚀多接收电感耦合等离子体质谱法(LA-MC-ICP-MS)和同位素稀释热电离质谱法(ID-TIMS)对氟碳铈矿样品SAM进行U-Pb定年技术研究,并将此两种方法得到的结果进行对比。LA-MC-ICP-MS得到的U-Pb年龄为(409±18)Ma(N=27,MSWD=4.5),ID-TIMS得到的206Pb/238U U-Pb年龄为(407.8±3.3)Ma(N=3,MSWD=0.029),两种方法得到的U-Pb年龄结果在误差范围内一致。通过比较两种方法的实验流程和结果,总结了各自的优缺点,为氟碳铈矿U-Pb定年方法选择提供了参考依据。     

Zircon U-Pb ages and Hf isotopic characteristics of the Dehe biotite monzonitic gneiss pluton in the North Qinling orogen and their geological significance

The Dehe granitic pluton intruded the Xiahe Group which is in the core complex of the North Qinling Orogenic Belt(NQOB).It shows gneissic bedding and possesses typical S-type granite minerals such as muscovite and garnet.LA-ICP-MS U-Pb isotopic dating of the Dehe granite yielded a weighted average age of 925±23 Ma which represents the emplacement age of the pluton.Most of the εHf(t) values are negative,and the two-stage model ages are consistent with the age of the Qinling Group.The isotope data show that the Dehe granite was formed in the following geological setting:in the syn-collision setting of the NQOB in the Neoproterozoic,crustal thickening induced partial melting of materials derived from the Qinling complex,and then the maga upwelled and intruded into the Xiahe Group.The formation of the Dehe S-type granite implied the occurrence of a convergent event in the QOB during the Neoproterozoic.     

西藏多龙矿集区地堡铜(金)矿床年代学、流体包裹体、地球化学特征及其成因类型研究

多龙矿集区位于班公湖-怒江成矿带西段北侧、羌塘地块南缘,是我国近年来发现的最大斑岩-浅成低温热液型Cu(Au)矿集区。地堡是多龙矿集区最西南边缘的矿床,资源潜力巨大,有望达到超大型规模,但研究程度薄弱。本次工作对地堡Cu(Au)矿开展了锆石U-Pb测年、流体包裹体、地球化学等方面的研究,为推动资源勘查和矿集区成矿规律的总结提供理论依据。含矿斑岩锆石206 Pb/238 U平均加权年龄为111.2±0.4Ma(MSWD=0.67),与矿集区成矿岩浆活动时限一致,是矿集区重要组成部分。石英脉流体包裹体显示矿床主成矿期成矿流体温度集中于140~382℃,主要集中在240~280℃。成岩阶段石英斑晶中Ⅰ型包裹体盐度范围为0.2%~20.7%NaCleqv.,含盐子晶包裹体盐度为33.6%NaCleqv.和43.9%NaCleqv.;成矿阶段不含石膏石英脉Ⅰ型包裹体盐度范围为0.2%~20.8%NaCleqv.,黄铁矿石英脉Ⅰ型包裹体盐度范围为1.1%~11.1%NaCleqv.,石膏中Ⅰ型包裹体盐度范围为0.5%~9.3%NaCleqv.。对钻孔DNZK6428样品进行主微量元素测试并进行因子分析计算,结果表明F1、F2、F3代表成岩阶段,因子主成分为Y-Ho-Er-Tm-Yb-Dy-Lu-Tb-Eu-Gd-Sm-La-Ce-Pr-Nd-SiO_2-Al_2O_3-CaO等,F4和F5代表铜金矿化阶段,因子主成分为Sn-Sb-Ba-Fe_2O_3-Sr-|SiO_2|-Ni-Cu-U-In-Cd-Au-Zn。黄铁矿δ34SV-CDT值总体较为集中,呈"双峰塔式"分布,变化范围为-7.8‰~4.1‰,均值为-4.23‰,为深源岩浆硫,硫的来源接近地幔硫。矿床粒状黄铁矿Co/Ni比值为0.207~10.775,平均值4.39,脉状黄铁矿Co/Ni比值为0.353~23.155,平均值3.802,均为热液成因。矿相学与岩相学研究结果显示矿床具明矾石和硫砷铜矿典型高硫化浅成低温热液矿床的矿物组合,地堡Cu(Au)矿为高硫型浅成低温热液矿床。