西藏恐弄拉地区中侏罗统桑卡拉佣组的厘定及其地质意义

贵州省地质调查院在开展西藏自治区1∶5万班戈县恐弄拉地区区域地质调查时,在马前乡恐弄拉西侧车尖西南一带前人划分的一套早白垩世桂牙岩组碳酸盐岩地层中采集了腕足类和腹足类化石,据采集的古生物化石时代确定此套碳酸盐岩地层为中侏罗世沉积(晚巴柔期—卡洛期),通过岩石组合特征、基本层序、沉积环境及生物化石时代对比,将该套地层重新厘定为桑卡拉佣组。这一地层的确定为冈底斯带地层区侏罗系地层划分对比、地层格架建立提供了重要的依据,并为中生代盆地的演化历史,古地理轮廓的确定提供了新的基础资料。     

变化环境下石羊河流域年径流频率计算

受气候变化与人类活动的影响,水文序列一致性遭到破坏,传统的频率计算方法受到挑战。针对石羊河流域8条河流年径流量序列,在基于水文变异诊断系统进行变异分析的基础上,采用条件概率分布法和混合分布法进行了变化环境下的年径流频率计算。结果表明,石羊河流域年径流量序列以向下跳跃变异为主,变异年份多集中在1960年附近;变异序列的两种分布均通过K-S检验,最优分布的拟合效率系数均大于0.97;对比由考虑变异的理论分布与不考虑变异的一致性P-III型分布确定的设计年径流量,当设计频率高于90%时,大靖河与西营河的设计年径流量值相差较大。因此,石羊河流域新建水利工程的规划设计,应适当考虑水文资料的变异特性,选择合理的频率分析方法确定设计年径流量。     

松辽盆地南缘基性岩脉中捕获锆石U-Pb年龄及其对基底岩浆事件的制约

团山子基性脉岩为松辽盆地南缘晚中生代最后一期岩浆活动,在其中获得了较多的捕获锆石。为了反映松辽盆地基底岩浆活动事件,对基性脉岩中捕获锆石进行了锆石LA-ICP-MS U-Pb定年。捕获锆石阴极发光(CL)图像和Th/U比值显示具有岩浆成因的特点。从锆石定年结果得到8组年龄,反映出早侏罗世晚期(176Ma)、海西期(291Ma)、加里东期(467Ma)、新元古代(942Ma)、中元古代(1368Ma)、古元古代(1886Ma和2165Ma)、新太古代(2458Ma)岩浆事件记录。松辽盆地南部基底组成以古生代和早中生代岩浆岩为主,并可能存在西保安群前寒武纪结晶基底(942Ma),并经历了复杂的岩浆演化。中元古代、古元古代、新太古代年龄的锆石具有磨圆和反应边,可能为与华北克拉通岩浆事件形成的锆石被搬运到松辽盆地南部,并被再次捕获的结果,反映松辽盆地南部与华北大陆具有一定的联系,但不确定存在该期的结晶基底。     

右江盆地晚侏罗世钾玄质高镁安山岩的厘定及其构造意义

右江盆地在大地构造上处于特提斯和滨太平洋构造域的结合部位。本文报道了该盆地东部杨屯安山岩的岩相学、年代学和地球化学特征。杨屯安山岩具斑状结构和气孔状构造,斑晶主要为辉石,基质以针状斜长石微晶为主,含少量辉石。LA-ICP-MS锆石U-Pb定年结果表明杨屯安山岩的喷发时代为159.3±2.8Ma,即晚侏罗世。样品的Si O2含量为53.13%~55.71%,具高MgO(6.74%~8.85%)、Mg#值(63~72)、Cr(416×10~(-6)~565×10~(-6))和Ni(207×10~(-6)~246×10~(-6)),低Fe OT/MgO(0.83~1.23)等特征,与典型高镁安山岩的特征相似。所有样品具高K2O(3.39%~4.77%)和K2O/Na2O(1.31~2.33),同时也具钾玄质岩石的地球化学特征。样品强烈富集大离子亲石元素和轻稀土元素,而亏损高场强元素,具较高的Rb/Sr(0.20~0.46)和较低的Ba/Rb(7.17~9.30),富集的Sr-Nd同位素组成((87Sr/86Sr)i=0.70738~0.70739,εNd(t)=-3.6~-3.4)。元素和同位素特征表明杨屯钾玄质高镁安山岩是含金云母的富集岩石圈地幔部分熔融的产物,形成于板内伸展环境而不是岛弧环境。晚侏罗世杨屯钾玄质高镁安山岩的厘定,反映了该时期右江地区处于岩石圈伸展-减薄阶段。     

珠江流域降水集中度时空变化特征及成因分析

基于珠江流域内43个常规气象站点1960~2012年的逐日降水资料,计算了流域内各站点长期降水集中度(LCI)和逐年降水集中度(ACI);采用Mann-Kendall趋势检验法和Sen’s坡度检验法检测ACI时间上的变化趋势;同时采用反距离权重插值法(IDW)对LCI的区域特征和ACI的变化趋势进行空间插值以分析降水集中度的时空分布规律;采用随机森林(RF)算法对降水集中度的影响因子进行重要度分析。结果表明:(1)珠江流域逐年降水集中度ACI的年际变化不明显,东南部呈上升趋势,西北部呈下降趋势;(2)珠江流域西北部长期降水集中度LCI值偏小,即降水分布较平均;东南部长期降水集中度LCI值偏大,即降水较集中,表明该地区降水极值情况发生的几率相对较高,该空间分布趋势可能是受距离海洋的远近及海拔的影响;(3)众多气候影响因子中,东亚夏季季风(EASMI)对珠江流域的降水集中度影响最明显。     

浙江南部丽水盆地地层时代及构造演化

位于浙江南部的丽水盆地是华南东部典型的白垩纪火山岩盆地。对盆地中5个凝灰岩夹层样品进行了锆石LA-MC-ICPMS U-Pb同位素年代学分析,结果给出了(114±1)Ma,(114±2)Ma,(118±1)Ma,(122±1)Ma和(112±1)Ma的主体谐和年龄。结合区域沉积-构造接触关系,本文将盆地内火山-沉积序列分为上、下2个组合:下火山-沉积组合包括馆头组和朝川组,其形成时代在124~112 Ma;上火山-沉积组合以方岩组为代表,其时代在104~91 Ma。这两套岩石组合的形成记录了盆地两期伸展断陷事件。结合区域构造变形和古构造应力场反演结果,本文认为丽水盆地早白垩世经历了两个伸展-挤压旋回的构造演化过程,每一旋回的古构造应力场均以NW-SE伸展和NWSE挤压应力场的交替演化为特征。NW-SE伸展事件控制了盆地的初始张开、断陷和沉积物充填作用,其产生的动力背景与古太平洋板块俯冲过程中因俯冲板片后撤(roll-back)诱发的弧后扩张作用有关。NW-SE挤压事件导致盆地的构造反转,下白垩统普遍褶皱,并形成区域角度不整合面,其形成与俯冲板片的深部几何学变化或大陆碰撞的远程效应有关。丽水盆地伸展-挤压事件的幕式交替反映了弧后扩张过程中复杂的深部动力学背景。     

青海德令哈盆地石炭纪古环境研究

采自德令哈地区石炭系的12个碳酸盐岩样品测试、分析结果表明,德令哈地区石炭纪整体为分层中等的弱还原海相环境,水体受陆源碎屑注入影响明显。这种湿热、还原的高盐度水体利于生物的繁盛及有机质的保存,使德令哈地区石炭系发育极为优越的烃源岩条件。垂向上,克鲁克组偏高的咸化程度及分层程度,表明克鲁克组沉积水体相对闭塞、咸化程度较高,而怀头他拉组、扎布萨尕秀组灰岩形成于水体交换相对通畅的海域。从岩性组合、陆源碎屑注入变化及盐度、还原性的差异来看,克鲁克组主体为局限台地环境,而怀头他拉组、扎布萨尕秀组为开阔台地。作为对克鲁克组高盐度、还原性水介质环境的响应,克鲁克组烃源岩TOC条件要比怀头他拉组及扎布萨尕秀组优越。     

琼东南盆地深水区新近系海底扇沉积特征与资源潜力

综合利用钻井、岩心、薄片及分析化验资料研究了琼东南盆地深水区新近系海底扇沉积特征,并利用最新的三维地震资料,通过井震精细标定、多属性融合技术、方差体切片、三维地貌砂体镂空等综合技术手段,精细刻画了海底扇砂体的空间分布特征。研究结果表明,深水区新近系海底扇是由陆架区的砂体滑塌并二次搬运形成,形成过程具有多期次性。受不同物源的影响,海底扇岩性和物性存在较大的差异。海底扇岩性及沉积构造具有砂质滑塌、碎屑流、浊流和深水底流改造的特征。海底扇的沉积微相、厚度、砂泥比和砂泥岩空间配置关系直接控制了地震振幅反射强度和频率的变化。砂体纵向叠置,横向连片,并被后期泥质水道切割分块形成多个岩性圈闭。综合分析认为,深水区海底扇砂体发育区烃源条件优越,储盖配置关系和圈闭条件良好,具备形成大中型岩性油气藏的有利条件,具有较大的油气勘探潜力。     

Diagenesis and origin of calcite cement in the Flemish Pass Basin sandstone reservoir (Upper Jurassic): Implications for porosity development

The Flemish Pass Basin is a deep-water basin located offshore on the continental passive margin of the Grand Banks, eastern Newfoundland, which is currently a hydrocarbon exploration target. The current study investigates the petrographic characteristics and origin of carbonate cements in the Ti-3 Member, a primary clastic reservoir interval of the Bodhrán Formation (Upper Jurassic) in the Flemish Pass Basin.The Ti-3 sandstones with average Q_86.0F_3.1R_10.9 contain various diagenetic minerals, including calcite, pyrite, quartz overgrowth, dolomite and siderite. Based on the volume of calcite cement, the investigated sandstones can be classified into (1) calcite-cemented intervals (>20% calcite), and (2) poorly calcite-cemented intervals (porous). Petrographic analysis shows that the dominant cement is intergranular poikilotopic (300–500 μm) calcite, which stared to form extensively at early diagenesis. The precipitation of calcite occured after feldspar leaching and was followed by corrosion of quartz grains. Intergranular calcite cement hosts all-liquid inclusions mainly in the crystal core, but rare primary two-phase (liquid and vapor) fluid inclusions in the rims ((with mean homogenization temperature (T_h) of 70.2 ± 4.9 °C and salinity estimates of 8.8 ± 1.2 eq. wt.% NaCl). The mean δ¹⁸O and δ¹³C isotopic compositions of the intergranular calcite are −8.3 ± 1.2‰, VPDB and −3.0 ± 1.3‰, VPDB, respectively; whereas, fracture-filling calcite has more depleted δ¹⁸O but similar δ¹³C values. The shale normalized rare earth element (REE_SN) patterns of calcite are generally parallel and exhibit slightly negative Ce anomalies and positive Eu anomalies. Fluid-inclusion gas ratios (CO₂/CH₄ and N₂/Ar) of calcite cement further confirms that diagenetic fluids originated from modified seawater. Combined evidence from petrographic, microthermometric and geochemical analyses suggest that (1) the intergranular calcite cement precipitated from diagenetic fluids of mixed marine and meteoric (riverine) waters in suboxic conditions; (2)the cement was sourced from the oxidation of organic matters and the dissolution of biogenic marine carbonates within sandstone beds or adjacent silty mudstones; and (3) the late phases of the intergranular and fracture-filling calcite cements were deposited from hot circulated basinal fluids.Calcite cementation acts as a main controlling factor on the reservoir quality in the Flemish Pass reservoir sandstones. Over 75% of initial porosity was lost due to the early calcite cementation. The development of secondary porosity (mostly enlarged, moldic pores) and throats by later calcite dissolution due to maturation of organic matters (e.g., hydrocarbon and coals), was the key process in improving the reservoir quality.     

Nano-scale pore structure and fractal dimension of organic-rich Wufeng-Longmaxi shale from Jiaoshiba area,Sichuan Basin: Investigations using FE-SEM,gas adsorption and helium pycnometry

Much attention have been recently paid to the upper Ordovician Wufeng shale (O₃w) and lower Silurian Longmaxi shale (S₁l) in the Jiaoshiba area of Sichuan Basin, which is now the largest producing shale gas field in China. Field emission scanning electron microscopy (FE-SEM), low pressure gas (N₂ and CO₂) adsorption, helium pycnometry, X-ray diffraction and geochemical analyses were performed to investigate the pore structure and fractal dimension of the pores in O₃w-S₁l shale formation in the Jiaoshiba area. FE-SEM images show that organic matter (OM) pores are dominant in the organic-rich samples and these pores are often irregular, bubble-like, elliptical and faveolate in shape, while in organic-poor samples, limited and isolated interparticle (interP), intraparticle (intraP) and OM pores are observed. Reversed S-shaped isotherms obtained from nitrogen adsorption are type Ⅱ, and hysteresis loops indicate that the shape of micropore in the samples is slit-or plate-like. BET surface areas and total pore volume vary from 12.2 to 27.1 m²/g and from 1.8 × 10⁻² to 2.9 × 10⁻² cm³/g, with an average of 19.5 m²/g and 2.3 × 10⁻² cm³/g, respectively. Adsorption volume from both N₂ and CO₂ adsorption increases with respect to TOC contents. Porosities obtained from helium porosimetry are comparable with these from gas (CO₂ and N₂) adsorption in O₃w-S₁l shale. However, porosity determined by quantitative FE-SEM analysis is much smaller, which is mainly related to limited resolution and the small areas of investigation.Based on the Frenkel-Halsey-Hill (FHH) model of low-pressure N₂ adsorption, fractal dimensions of the pores varied from 2.737 to 2.823. Relationships between pore structure parameters and TOC content, mineral composition and fractal dimension reveal that the fractal dimension is mainly associated with micropores. Samples with higher TOC content, higher quartz content and lower clay content tend to contain more heterogeneous micropores, resulting in higher fractal dimensions and more complicated pore structure in shales. Therefore, fractal dimension is an effective parameter to reflect the complexity of pore structure and the degree of micropore development in O₃w-S₁l shale.