滇西兰坪盆地白秧坪Pb-Zn-Cu-Ag多金属矿床东矿带成矿年代学探讨

白秧坪Pb-Zn-Cu-Ag多金属矿集区夹持于金沙江和澜沧江断裂之间,隶属兰坪盆地北部,分为东、西2个矿带。文章采用闪锌矿、方铅矿的Rb-Sr法和成矿阶段方解石的Sm-Nd法,对白秧坪Pb-Zn-Cu-Ag多金属矿床东矿带华昌山和下区五矿段进行了成矿年代厘定,获得方铅矿以及闪锌矿和方铅矿的矿物组合Rb-Sr等时线年龄为(32.8±1.5)Ma,方解石的Sm-Nd等时线年龄为(33.32±0.43)Ma。研究表明,通过对特定矿床的主要矿石矿物采用Rb-Sr法和Sm-Nd法获得的年龄在误差范围内是一致的,从而起到了相互验证的作用,并对矿床的成矿背景具有一定的指示性。通过成矿年龄的探讨,认为东矿带铅锌为主的矿化期主要产生于青藏高原东缘晚碰撞阶段(40~26)Ma,伴随印度-亚洲大陆碰撞造山,形成逆冲推覆构造和赋矿地层,控制了Pb-Zn矿床的形成和发育。该期Pb-Zn矿床与兰坪盆地金顶和西矿带Pb-Zn矿床、囊谦盆地Pb-Zn矿床和沱沱河盆地Pb-Zn矿床具有一定的可比性。     

山东郭城牧牛山二长花岗岩的岩石成因:地球化学和锆石U—Pb年代学制约

山东胶莱盆地东北缘郭城牧牛山二长花岗岩的锆石LA--ICP--MS U--Pb年代学及岩石地球化学特征表明,牧牛山花岗岩为古元古代(2 138±15 Ma)岩浆侵入产物,是一套钾玄岩系列岩石,A/CNK为1.07~1.13。稀土配分曲线表现为右倾模式,轻稀土和重稀土分异明显,Eu/Eu*值为0.59~0.71。蛛网图表明明显富集大离子亲石元素(Rb、K),相对亏损高场强元素(Th、U、Nb、Ta、Ti、P)。岩石10 000 Ga/Al值(2.73~2.85),为A型花岗岩。岩石的Mg~#值为12~28,Nd/Th值为1.62~1.96,Rb/Sr值为4.70~9.71,显示壳源特征。综合分析认为,古元古代胶辽地块向西俯冲引发幔源岩浆底侵,导致地壳物质部分熔融形成牧牛山花岗岩。     

鄂尔多斯盆地低渗透油气藏形成研究现状与展望

鄂尔多斯盆地是中国规模最大的低渗透油气资源勘探与开发基地,其低渗透油气藏具有油层物性差、非均质性强、油藏成藏因素复杂、油藏分布受多种因素联合控制等特点。在回顾鄂尔多斯盆地低渗透油气藏成藏理论研究和勘探历史经验基础上,认为目前鄂尔多斯盆地低渗透油气藏成藏研究存在两大理论体系,即沉积学控制成藏理论和运移动力学控制成藏理论,前者从沉积特征出发,强调储层砂体沉积相、非均质性和成岩作用在低渗透性油藏形成中的控制作用,后者从石油运移与聚集过程出发,强调运移动力学在初次运移和二次运移中的重要作用。但是目前低渗透油气成藏研究存在一定的局限性和片面性,过分强调了单个地质因素的作用,其中沉积学控制成藏理论局限于沉积相划分和沉积模式建立方面,过多地强调了沉积相对成藏因素静态的控制作用,而忽视了油气成藏过程的动态属性;运移动力学控制成藏理论却过分强调了油气流体运移过程的模式化和公式化,过分夸大和随意解释了油气运移成藏记录——油气包裹体的作用及其原始地质意义,轻视了深部地层条件下油气运移的复杂性和油气包裹体记录的多解性。因此,传统的单因素控制油气成藏理论和相应的勘探研究方法已经不能确切揭示油气富集规律和有效指导勘探工作。低渗透油气藏成藏理论研究趋势是要重视分析油气藏地质记录,动态研究油气藏形成和演化历史过程,总结油气富集规律,为油气勘探战略部署提供重要资料。     

羌塘盆地白垩系海相油页岩特征及其形成条件分析

近年来,在羌塘盆地胜利河、长梁山、长蛇山、托纳木等地发现的油页岩为目前我国规模最大的海相油页岩矿床,具有重要的工业开采价值。海相油页岩的主要矿物成分为碳酸盐、粘土矿物和石英,并见有黄铁矿、石膏、菱镁矿等矿物。粘土矿物以伊利石为主,少量高岭石,不含蒙脱石。有机地球化学分析表明,这些油页岩的有机质丰度较高,有机质类型较好。胜利河油页岩TOC含量在4.31%~21.37%之间,均值为8.40%;托纳木油页岩的TOC含量也较高,最大值为25.68%,平均为9.32%;长梁山剖面油页岩的TOC含量在2.96%~23.47%之间,平均值为9.56%;长蛇山油页岩的TOC含量在4.53%~9.49%之间,平均值为7.74%。长蛇山油页岩干酪根类型主要为Ⅱ1型,少数为Ⅱ2和Ⅲ型;胜利河油页岩主要为Ⅱ1和Ⅱ2型干酪根,而托纳木油页岩的干酪根类型主要为Ⅱ1型和Ⅰ型。白垩系海相油页岩的形成受多方面因素控制,包括缺氧富氧状态、古生产力、古气候、粘土矿物的混积作用、古地形条件以及海平面变化等。其中,油页岩的总有机碳含量(TOC)与古环境元素指标Mo、V存在较强的相关关系,相关系数分别为0.975和0.917,而与古生产力指标P/Ti、Ba/Al之间为弱相关或无相关关系,相关系数分别为0.481和-0.739。因此,本文认为海相油页岩的形成以"保存模式"为主,有机质沉积时的水体环境对高有机质含量的油页岩的形成起主导作用,并在此基础上建立了海相油页岩的形成演化模式。     

柴达木盆地西北古近系-新近系异常高压形成机制分析

柴达木盆地西北(以下简称“柴西北区”)古近系-新近系异常超压普遍存在。对超压的空间分布特征和形成机制的研究是评价该地区油气成藏条件与资源潜力的关键。依据柴西北区钻井实测压力数据及基于等效深度法计算的地层压力结果,对研究区异常高压的平面和剖面分布特征进行分析。在此基础上,结合柴西北区典型钻井泥岩声波时差曲线特征、不同时期沉积速率、各地层岩性特征、有机质生烃潜力及柴西北地区遭受的构造挤压作用,对研究区超压的形成机制进行分析,并对各控制要素在超压形成过程中的贡献进行定量评价。研究结果表明：柴西北区地层超压起始深度位于大约1 500 m,主要发育在古始新统路乐河组-中新统上干柴沟组内,总体上异常高压随深度加深逐渐增大。研究区超压的形成是多种因素综合作用的结果,其中欠压实作用、有机质生烃和构造挤压作用是该区超压形成演化的重要原因。对控制超压形成的各要素定量评价结果显示：欠压实作用是柴西北区超压形成的最重要控制因素,其贡献率高达60%;构造挤压作用次之,其贡献率在20%～30%左右;有机质生烃演化作用对超压形成也有影响,但贡献率相对较小。此外对柴西北区咸湖环境下的盐度分布特征研究初步表明,地层孔隙流体盐度和咸水半咸水环境下沉积的含盐塑性地层对超压的形成和保存也有一定的影响。     

Depositional System of the Carboniferous Huanglong Formation, Eastern Sichuan Basin: Constraints from Sedimentology and Geochemistry

Using analyses of the lithology, sequences, paleoenvironment, and tectonic setting, the depositional system of the Carboniferous Huanglong Formation in the eastern Sichuan Basin was identified. The lithological characteristics of the Lower Member, Middle Member, and Upper Member were analyzed and classified. Before the use of carbon, oxygen, and strontium isotopes in the analysis, all of the geochemical data were tested for validity. On the basis of the Z values obtained from carbon and oxygen isotopes, the paleoenvironments of the three members were elucidated. Lower Member was dominantly an enclosed marine environment with intense evaporation and little freshwater input into the sea. Middle Member developed in a semi-enclosed to normal marine environment with many rivers. Upper Member was formed in a normal marine environment. The east Sichuan Basin was enclosed by paleouplifts before the deposition of the Huanglong Formation, forming a relatively enclosed depositional setting. Paleogullies developed in the Silurian strata that underlie the Carboniferous rocks; these paleogullies can be identified. On the basis of a comprehensive analysis, we propose that the Huanglong Formation developed in a platform system. Four microfacies were identified: supratidal flat, dolostone flat, grain shoal, and shelf microfacies. The high-permeability and high-porosity characteristics of the grain shoal microfacies are favorable for hydrocarbon accumulation, while the supratidal flat and shelf microfacies developed very few high-quality reservoirs. The paleogullies, in which increased amounts of grain shoal microfacies developed, controlled the distribution of high-quality reservoirs.     

显微荧光光谱技术在油气成藏研究中的应用——以塔里木盆地巴什托上古生界油气藏为例

根据原油在紫外光的激发下产生荧光的特点,通过显微荧光光谱方法,对有机包裹体的荧光光谱进行定量化分析,利用其主峰波长与荧光强度、主峰波长与红/绿商的相关性,对塔里木盆地巴什托上古生界油气藏的成藏特征进行了初步研究。在研究区所采集的32块岩石样品中共获得64个荧光光谱数据。分析结果表明,巴什托上古生界油气藏存在3个油源,其主峰波长主要集中在439~443nm、469~472 nm和498~503 nm三个值段上,且为不同演化阶段的混源充注。前两者来自于寒武—奥陶系烃源岩,由下至上充注成藏;后一油源来自于石炭系巴楚组,随演化程度的变化同时向上、下两个方向充注。综合同期捕获不同主峰波长的有机包裹体,推测研究区至少存在4期油充注、1期天然气充注。     

下垫面对WRF模式模拟黑河流域区域气候精度影响研究

利用高精度的土地覆盖、土壤质地类型和地形高度值替换了天气研究和预报模式Weather Research and Forecasting Model(WRF)中的相关数据,通过数值模式试验检验了下垫面数据对WRF模拟精度的影响。同时,通过与黑河综合遥感联合试验中7个测站观测数据的比较,以平均误差、均方根误差和相关系数为指标,分析了WRF模式下垫面数据改变对近地表气象要素的模拟精度的影响。结果表明:(1)WRF模式本身的地形高度信息在黑河流域上游地区有较大误差,造成了一定的模拟误差。而使用高精度的下垫面数据可以提高WRF模式在黑河流域上游复杂区域的模拟能力;(2)2m气温除了随地形高度递减外,还受土壤质地和土地覆盖小幅度影响,而且进行地形订正后的2m气温与2m湿度的模拟在下垫面为水体的区域对比强烈,因此为模式提供准确的水体分布信息也至关重要;(3)2m气温和湿度等要素的模拟差异值与地形高度资料的差异呈负相关,而降雨量的差异与地形高度差异呈微弱的正相关,与土壤质地差异和土地覆盖差异的相关性也比较弱。     

Trace Metal Solid State Speciation in Aerosols of the Northern Levantine Basin,East Mediterranean

An established three stage sequential leach scheme was applied to a series of selected high volume aerosol samples (n = 35) collected from the Turkish Eastern Mediterranean coastline (Erdemli). Samples were selected according to their air mass back trajectory history to reflect the contrasting mixtures of aerosol material present in the Eastern Mediterranean marine aerosol. Two populations were adopted, those samples which were classed as “anthropogenic” and those which were “Saharan” dominated aerosol populations. Applying the three stage leach it was possible to define the proportion for each of the considered metals (Al, Fe, Cu, Pb, Cd, Zn and Mn) present in the (a) “exchangeable” (b) “carbonate / oxide” and (c) “refractory” phases, representing novel solid state aerosol speciation data for this marine system. Clear trends were established, conforming with data from previous studies with mainly crustal derived metals (Al and Fe) being present in the refractory phases (Al > 88%; Fe > 84%) and those influenced by anthropogenic sources being dominating in the exchangeable phase, although for these metals the variability was comparatively high (12–64%; 19–85%; 40–100% for Zn, Pb and Cd, respectively). For the majority, greater exchangeable fractions were present the lower the crustal source contribution to the aerosol population, whereas the “refractory” fraction exhibited contrasting behaviour. This was illustrated by the novel application of the mixing diagram, presenting each of the three speciation stages against the corresponding percent anthropogenic contribution to each collected sample. Zn, Pb and Cd all illustrated progressive decrease in the percent exchangeable with increasing crustal contribution to the aerosol population. The percent exchangeable was discussed in terms of its use to represent the upper limit of the bioavailable fraction of metal associated with the aerosol, post deposition. The mixing diagram approach enabled the prediction of the residual fractions for Cd, Pb and Zn (41 ± 4%; 62 ± 4% and 82 ± 5%, respectively,) in Saharan end-member material.     

四川盆地暴雨对初值敏感性的模拟研究

本文基于区域暴雨数值预报模式AREM,针对2007年7月发生在四川地区的多次强降水过程进行数值试验,检验了NCEP和站点资料（STN）初始分析场资料预报结果,发现由于台站资料稀少,NCEP资料在四川地区的评分较高。讨论了四川盆地降水对初值的高度敏感性,揭示了四川盆地降水对初值中各个物理量场的不同敏感性,其中,降水对初值中湿度场的响应最为显著。初值不仅决定着降水的范围和强度,还对降水的发生时间产生明显影响。