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《Planetary and Space Science》2002,50(9):871-876
C10H6-Fe+ complexes were observed by Fourier transform mass spectrometry by Marty et al. (Chem. Phys. Lett. 256 (1996) 669). In this article, we present the infra-red (IR) spectra of the two isomers calculated by ab initio methods of quantum chemistry. In the past, the same approach has predicted successfully unexpected features of the IR spectra of polycyclic aromatic hydrocarbon (PAH) cations which were confirmed by measurements in matrices (J. Phys. Chem. 98 (1994) 9187). The C10H6-Fe+ systems are models for larger PAHs-Fe+ complexes, which are believed to play a key rôle in space chemistry. 相似文献
3.
Yanjun ZHANG Fenglong ZHANG Full QI Fuquan NI 《东北亚地学研究》2006,9(2):199-203
In view of the situation of excavation of open coal mine for the underground water disaster,we should carry out simulation studies for the numerical value of the water lowering project and improve the accuracy and the level of the water lowering project.On the basis of the hydrological geological conditions of certain open mine digging,a more reasonable seepage numerical model was built according to MODFLOW.It was simulated in advance that the process of the confined water level descending with the time,and combining with the actual observations to test the correctness of the model.The calculation showed that the results coincided well with the results of actual measurement.Based on this,different water lowering numerical simulations were built for the open coal mine digging.It could be simulated and forecast that the changes of the groundwater level in drainage process within and outside the mine pit,and it was quantitatively assessed that the possible water lowering result of the opencast water drainage process,which provide an important basis for the actual water lowering project and the possible project disposal. 相似文献
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新疆阿尔泰蒙库铁矿床的成矿流体及成矿作用 总被引:30,自引:8,他引:22
蒙库大型铁矿床赋存于上志留统—下泥盆统康布铁堡组变质火山-沉积岩系中,容矿岩石为石榴子石矽卡岩、变粒岩、浅粒岩和大理岩。矿体总体顺层分布,空间上与矽卡岩密切相关。研究表明,矽卡岩期石榴子石以发育玻璃质熔融包裹体、流体熔融包裹体和流体包裹体为特征,晚期矽卡岩阶段矿物中发育液相包裹体,变质期矿物中主要发育液相包裹体和含子矿物包裹体。矽卡岩期熔融包裹体的均一温度为1100℃,早期矽卡岩阶段流体包裹体均一温度变化于193~499℃,在450℃、350℃和230℃出现峰值。中期矽卡岩阶段均一温度变化于236~550℃,峰值为350℃。区域变质期均一温度介于132~513℃,在350℃、230℃和190℃出现峰值。流体包裹体的盐度w(NaCleq)介于1.23%~60.31%,流体密度变化于0.60~1.16g/cm3。石榴子石、石英和方解石的δ18OSMOW变化于0.2‰~8.4‰,δ18OH2O介于-5.1‰~5.33‰,δD为-127‰~-81‰,表明矽卡岩期成矿流体主要是岩浆水,混合少量大气降水;变质期流体主要为大气降水,为混合变质水。方解石δ13CPDB变化于-6.1‰~-2.3‰,表明流体中碳来自深部或地幔。成矿时代为早泥盆世早期(略晚于404~400Ma),成矿作用与矽卡岩的退化变质作用有关。 相似文献
7.
山东省济宁强磁异常区深部铁矿初步验证及其意义 总被引:8,自引:1,他引:7
山东省济宁磁异常是一个重、磁同源体,面积大于100 km2,磁异常峰值为3800nT。钻探验证在孔深1041.57~1796.54m位置发现铁矿体,矿体总厚度74.04~220m,磁性铁平均品位15.89~25.19%。矿石类型有条带状方解磁铁石英岩和条带状磁铁石英大理岩,矿石的主要组成矿物为石英、方解石、磁铁矿、磁赤铁矿、菱铁矿。矿体产于济宁岩群浅变质岩系中,矿床特征与条带状铁建造(BIF)铁矿或鞍山式铁矿有明显区别,铁矿成因类型属与千枚岩、变质中酸性火山岩、大理岩有关的沉积变质型铁矿床。该区铁矿资源潜力巨大。 相似文献
8.
Controlling of landsides safely and economically is a great challenge to mine operators because landslides are major geological
problems especially in open-pit mines. In this paper, a case history at Panluo open-pit mine is presented in detail to share
the experiences and lessons with mine operators. Panluo open-pit mine is located in the southwestern Fujian province of China.
It is the largest open-pit iron mine in the Fujian province and was planned in 1965 and is in full operation from 1978. In
July 1990, an earthquake of magnitude 5.3 in Taiwan Strait and big rainstorms impacted the mine slope, causing tension cracks
and rather large-scale failures, and forming a U-shaped landslide. Total potential volume was estimated to be up to 1.0 × 106 m3. This directly threatened the mine production. In order to protect the mine production and the dwellers’ safety around, a
dynamic comprehensive method was implemented including geotechnical investigations, in-situ testing and monitoring, stability
analysis, and many mitigation and preventive measures. These measures slowed down the development and further occurrence of
the landslide. The results showed that the landslides were still active, it was slowed with the control measures and moved
rapidly with rainfall and mining down. However, no catastrophic accidents occurred and the pit mining was continued till it
was closed at the elevation of 887 m in 2000. As a successful case of landslide control at an open-pit mine for 10 years,
this paper reports the controlling measures in details. These experiences of landslide control may be beneficial to other
similar mines for landslide control. 相似文献
9.
Investigations were carried out at three underground coal mines in India to study the response of surface structures to underground
blasting and the likelihood of damage to the structures. The structures in the vicinity of the underground blasting area were
single and multistoried residential houses. The amplitudes of vibration due to underground blasting were monitored simultaneously
on the ground surface near the foundation of the structures and on various floors of the structures. The vibrations were also
monitored near the important surface installations. It was observed that the magnitude of vibration in structures decreased
with the increase in the height of the structures. The frequency of blast vibration from underground blasting was higher than
the natural frequency of the structures. Little energy was transmitted into the structures, which caused reduction in the
vibration level in the structures. The reduction in the vibration levels was up to 45% in the houses. It indicates that the
dominant frequency of blast vibration plays an important role in persistence of vibration and its amplification or reduction
characteristics in the structures. This paper deals with the effect of the vibrations on structures/houses standing above
the blasting faces in underground workings and their potential to likely damage to the structures at different Indian geo-mining
conditions. 相似文献
10.
Summary Left in place pillars of abandoned mines are subject to weathering (e.g action of water, bacteria) that degrades their mechanical
strength and eventually leads to collapse. A simple weathering model is proposed, that is governed by two parameters: the
rate of progression of weathered front and the rate of degradation of the compressive strength with time. Both plane strain
and axisymmetric analyses are performed and closed form solutions of the variation with time of the bearing capacity of the
pillar are given. Experimental data of the tests conducted on gypsum and anhydrite specimens attacked by water are presented.
It is shown that in order to fit the experimental data a third parameter must be introduced. New closed form solutions are
given and the data are used for estimating the time to failure of abandoned gypsum mines in Northern Italy.
Authors’ address: Dr. Riccardo Castellanza, Research Assistant, Department of Structural Engineering, Milan University of
Technology (Politecnico), Piazza Leonardo da Vinci 32, 20133 Milan, Italy 相似文献