湖南大坳矿区控矿构造特征及其对云英岩体型钨-锡矿的控制作用

云英岩体型钨-锡矿为大坳矿区的主要矿床类型,呈隐伏—半隐伏产出,自上而下呈楼层式产出,形态为似穹状。通过对区内构造特征及其形成机制的分析,探讨了构造对钨、锡成矿的控制作用。提出了区内构造的多期脉动式活动控制了多阶段钨、锡矿化作用的新认识,即NNE—近SN向区域性断裂控制了矿床就位,弧形裂隙系统控制了矿体的产状和形态。     

湖南柿竹园矽卡岩-云英岩型W-Sn-Mo-Bi矿床地质和成矿作用

柿竹园钨多金属矿床由三个阶段不同成矿作用复合叠加而形成。它们分别与似斑状黑云母花岗岩、等粒黑云母花岗岩和花岗斑岩脉有着成因联系。第一阶段矿化包括含矿块状外质矽卡岩和含矿退化蚀变岩；第二阶段为云英岩矿化，在空间上叠加于块状矽卡岩及外部的大理岩；第三阶段为与锰质矽卡岩相伴生的铅锌银矿化。本文详细地描述了前两阶段矿化的地质和成矿地球化学特征，并探讨了其成矿过程。在此基础上，建立了柿竹园矿床的多阶段成矿模     

Ammonia measurements at Niwot Ridge,Colorado and point arena,California using the tungsten oxide denuder tube technique

The applicability of the tungsten oxide denuder tube technique for the measurement of ammonia in the rural troposphere was investigated. The technique is based on selective chemisorption of NH₃ from a gas stream, thermal desorption, conversion to NO, and analysis by NO–O₃ chemiluminescence. Nitric acid, which is also collected and desorbed as NO, was distinguished from NH₃ by differences in desorption temperature. Substituted amines were also collected, but desorbed at a slightly lower temperature than NH₃ in dry air. At high relative humidities, alkylamines may be hydrolyzed to NH₃ on the denuder surface and hence detected as NH₃. Overheating of the denuder tube during the temperature-programmed desorption was found to cause significant irreversible degradation of system performance.The technique was used to measure NH₃ mixing ratios at two rural locations in the United States. At a mountain site in Colorado during the winter of 1984, the average NH₃ mixing ratio was 0.20 ppbv (=0.08 ppbv). At an isolated coastal site in northern California during the spring of 1985, the average NH₃ mixing ratio was 0.36 ppbv (=0.17 ppbv). Correlations of the latter measurements with wind direction and NO _x level suggest that the NH₃ mixing ratio in Pacific marine air at 40°N is <-0.25 ppbv.     

Evaluation of the tungsten oxide denuder tube technique as a method for the measurement of low concentrations of nitric acid in the troposphere

The applicability of the tungsten oxide denuder tube technique for the measurement of nitric acid in the rural troposphere was investigated. The technique is based on selective chemisorption of HNO₃ from the gas stream, thermal desorption, conversion to NO, and analysis by NO–O₃ chemiluminescence. Ammonia, which is also collected and desorbed as NH₃ and NO, was separated from the HNO₃-derived NO by linear temperature-programed thermal desorption. Possible interferences by NO₂, HCN, PAN, and n-propyl nitrate (NPN) were tested and found to be significant under conditions found in the lower troposphere. Simultaneous ambient measurements of HNO₃ were made with the tungsten oxide denuder tube and nylon filter methods at a rural site in the Colorado mountains (Niwot Ridge, CO). Nitric acid levels measured by the tungsten oxide denuder tube averaged a factor of 3 higher than levels measured by the nylon filter technique. Tests involving the placement of nylon materials in front of the tungsten oxide denuder tube show that there are species, as yet unidentified, present in the atmosphere that interfere with the measurement of HNO₃ by the tungsten oxide technique.     

稀土富铁金刚石增强型硬质合金复合齿的研究

采用稀土La掺杂的添加方式，优选富铁硬质合金基体的配方，通过基体的力学性质测试以及金相分析确定了YGl5富铁硬质合金的基体配方，确定出最佳稀土La添加量为0．5％质量比。单齿抗冲击试验表明，这种复合齿具有良好的抗冲击性能。室内钻进试验说明，适当配方的稀土富铁金刚石增强型硬质合金复合齿具有良好的抗冲击性，较强的研磨能力和对岩样的广谱性。同时，通过野外实际钻进进一步说明，这种复合齿钻头具有高时效性。通过调整金刚石的镀覆方式和物质，金刚石浓度以及烧结工艺，来控制复合齿的性能，从而使稀土富铁金刚石增强型硬质合金复合齿钻头具有高时效、长寿命等特点。     

黑钨矿矿囊熔离成因综述

一些与石英脉型钨锡矿化有关的花岗岩体内常发育有形态不同、规模不等、成分各异的矿化囊包体．其成因难手用岩浆结晶分异和岩浆期后热液成矿作用解释。地质和实验资料表明。此类花岗质岩浆体系中不仅存在液态分离作用形成熔离矿化囊包体。而且熔离成因的黑钨矿矿囊可作为岩体可以形成岩浆热液鸽矿的标志，同时说明石英脉型黑钨矿床的剥蚀深度较大。     

大吉山钨矿中钨铌锰矿与富钨铌锰矿的交生现象及其成因探讨

文章对大吉山钨锰矿矿石进行了电子探针分析 ,发现了一种主要元素为Nb、Ta、Fe、Mn、W的复杂氧化物矿物———钨铌锰矿。这种矿物与富钨铌锰矿交生 ,在成分上与后者呈渐变过渡。证实在自然界中黑钨矿与铌钽铁矿之间可能存在着广泛的W_Nb(Ta)类质同像置换现象。通过对其成分、形态和共生关系的研究 ,结合大吉山钨矿的形成期次 ,联系矿体与区域内两期花岗岩的内在关系 ,对大吉山钨矿的成因机制进行了探讨     

从"译文"想到龙潭多金属钨矿的重新评价

通过与美国Fort knox等7个大型金矿床[1]及广东莲花山斑岩型含金钨矿床的对比,认为龙潭现存铁帽状钨矿相当于含钨(锡)氧化物的硫化物带的中上部,其中下部主体硫化物带应是今后找金评价的重点.     

P—E5000原子吸收光谱仪的维修及零部件国产化

用实例介绍了对P－E5000原子吸收光谱仪的某些部件的替代和电路的改动，以及钨灯电路故障的维修。通过零部件的替代，使仪器得到及时维修，并且降低了成本。     

地球化学基准与环境监测实验室分析指标对比与建议

全球高质量一致性地球化学基准数据和建立全球地球化学一张图平台,是持续监测全球环境变化的定量参照标尺。本文通过对中国、欧洲、美国和澳大利亚汞、镉、钨地球化学数据对比和中国同一实验室间隔15年两次分析数据对比发现:镉元素在不同实验室和同一实验室间隔15年分析的数据是一致的(相关系数0.96),汞元素一致性较差(相关系数0.74),钨元素不具有可比性(相关系数0.56)。镉元素分析结果的高度一致是因为分析方法相同的和检出限相近;汞元素一致性较差,特别是低含量汞存在显著差异,是因为分析方法不同和检出限不同;钨元素在不同实验室不具有可比性是因为实验室分析方法存在显著差异。环境变化量必须大于野外采样误差(REsmpl)和实验室重复样误差(RDlab)之和(RCenv>REsmpl+RDlab),才能确认观测点发生了环境显著变化。因此,必须将采样误差和实验室分析误差降到最低。本文提出实验室分析的6点基本要求:①原始样品过10目筛,使用无污染加工到粒度小于200目;②使用成熟的多方法分析71种元素+其他指标,其中主量组分以玻璃熔片X射线荧光光谱法(XRF)分析为主,微量元素以四酸分解样品,电感耦合等离子体质谱法(ICP-MS)和电感耦合等离子体发射光谱法(ICP-OES)为主要分析技术,配合其他特殊分析方法;③分析检出限必须低于地壳克拉克值,报出率不低于90%;④使用的标准物质必须具有涵盖所有分析元素的认定值;⑤实验室重复样分析相对误差含量小于3倍检出限RD≤40%,大于3倍检出限RD≤20%,主量元素、铁族元素和重金属元素重复样分析相对误差RD≤20%;⑥主量组分SiO2、Al2O3、Fe2O3、FeO、MnO、MgO、CaO、Na2O、K2O、TiO2、P2O5、H2O^+(结晶水)、有机碳、CO2、SO2等15项,或SiO2、Al2O3、Fe2O3、FeO、MnO、MgO、CaO、Na2O、K2O、TiO2、P2O5、LOI(烧失量)等12项加和为99.3%~100.7%。