虎头崖岩体地质地球化学特征及其对东昆仑祁漫塔格印支中-晚期构造环境的制约

虎头崖岩体位于青海东昆仑祁漫塔格成矿亚带,形成于中-晚三叠世,主要由黑云母二长花岗岩、正长花岗岩组成,局部含闪长质暗色包体。岩石高硅、高钾、富碱,SiO2含量为70.71%～77.67%;K2O含量平均为4.7%;Na2O K2O为7.86%～9.1%;K2O/Na2O平均为1.36。A/CNK比值为1.01,KN/A比值为0.86,属于高钾钙碱性系列的微过铝质I型花岗岩类。∑REE含量中等,平均为120.10μg/g;δEu值0.04～0.47;（La/Yb）值为1.52～8.06 ;稀土元素球粒陨石标准化曲线显示Eu负异常、HREE较平坦的右倾“V”型特征。岩体富集LIL和HFS元素,而Ba、Sr、Nb、Ti、P元素明显的负异常。结合区域地层岩性特征、A/MF-C/MF图解和岩体微量元素蛛网图,认为花岗岩是基性源区部分熔融和地壳物质混合的产物。结合地质特征、构造演化背景、元素判别图解等,认为包括虎头崖岩体在内的印支中晚期花岗岩形成于同造山阶段的后碰撞构造环境。印支中晚期花岗岩形成机制为：在二叠纪末-三叠纪初阿尼玛卿洋盆向北部昆仑微陆块俯冲碰撞造山并形成同碰撞/板内构造环境,期间发育与幔源岩浆底侵关系密切的源区基性岩浆岩;中-晚三叠世期,主碰撞之后挤压应力相对松弛,深部压力降低,因地壳增厚升温、岩石熔点降低而导致源区中-基性岩浆部分熔融,并在相对开放的环境下高侵位成岩     

滇东北下田坝花岗岩年代学、地球化学及其构造意义

滇东北下田坝花岗岩的SiO2质量分数在71.1%～78.15%之间,Al2O3值在11.55%～14.90%之间,A/CNK=0.94～1.25,属于弱过铝质花岗岩。稀土元素总量(∑REE)为259.71×10-6～804.60×10-6,∑LREE/∑HREE为4.12～10.28,说明轻稀土较重稀土富集。岩石具有明显的负Eu异常(δEu=0.04～0.07),大离子亲石元素Rb、Ba、Pb、U等相对富集,高场强元素Nb、Ta、Zr、Ti等明显亏损,这些特征说明下田坝花岗岩是由壳源物质部分熔融形成的,具有A型花岗岩的特征。对下田坝花岗岩进行的激光探针等离子体质谱(LA-ICP-MS)锆石U-Pb同位素年代学研究获得了206Pb/238 U加权年龄年龄769±4.4Ma(MSWD=0.45),可代表花岗岩的形成年龄,下田坝花岗岩并非原来认为的早古生代花岗岩。结合对区域地质资料的分析认为,下田坝花岗岩的形成年龄与扬子地块西部Rodinia超大陆裂解事件在时间上一致,该花岗岩是在Rodinia超大陆裂解过程中由地幔柱活动引起的大陆裂谷环境中形成的,这也证实了扬子地块西南缘新元古代的裂谷环境已影响到滇东北的东川地区。     

义敦岛弧带夏塞早白垩世A型花岗岩成因:锆石U-Pb年代学、地球化学及Hf同位素制约

义敦岛弧带晚中生代侵入岩体目前仍缺乏高精度的年代学数据制约,其成因也存在争论。作者首次在岛弧带中段夏塞银铅锌多金属矿区发现与成矿关系密切的黑云母二长花岗岩。本文对其开展了年代学、地球化学和Hf同位素分析,探讨成因及构造背景。LA-ICP-MS锆石U-Pb定年结果为103±1 Ma(MSWD=0.5),为早白垩世晚期岩浆活动产物。花岗岩属高钾钙碱性岩系,具有高硅、富碱和铁、贫钙和镁特征,Si O2含量为72.94%~74.98%,K2O+Na2O=7.56%~8.08%,铝饱和指数A/CNK=1.06~1.10,属弱过铝质岩石。岩石富集Zr、Hf等高场强元素和U、Th等大离子亲石元素,明显亏损Ba和Sr。REE具有明显的Eu负异常(δEu=0.13~0.25),总体呈较陡右倾的LREE富集和HREE相对亏损特征。岩相学和地球化学显示其为铝质A型花岗岩。Hf同位素组成εHf(t)=–2.7~0.6,二阶段模式年龄TDM2=925~1095 Ma。地球化学及Hf同位素揭示夏塞岩体为软流圈地幔与壳源长英质岩浆混合成因,并经历了斜长石、正长石和褐帘石等矿物的分离结晶。夏塞花岗岩体具有后碰撞花岗岩特征,形成于早白垩世晚期弧-陆碰撞造山后伸展构造背景。     

P–T–t–D paths of Everest Series schist, Nepal

U(–Th)–Pb geochronology, geothermobarometric estimates and macro‐ and micro‐structural analysis, quantify the pressure–temperature–time–deformation (P–T–t–D) history of Everest Series schist and calcsilicate preserved in the highest structural levels of the Everest region. Pristine staurolite schist from the Everest Series contains garnet with prograde compositional zoning and yields a P–T estimate of 649 ± 21 ° C, 6.2 ± 0.7 kbar. Other samples of the Everest Series contain garnet with prograde zoning and staurolite with cordierite overgrowths that yield a P–T estimate of 607 ± 25 ° C, 2.9 ± 0.6 kbar. The Lhotse detachment (LD) marks the base of the Everest Series. Structurally beneath the LD, within the Greater Himalayan Sequence (GHS), garnet zoning is homogenized, contains resorption rinds and yields peak temperature estimates of ～650 ± 50 ° C. P–T estimates record a decrease in pressure from ～6 to 3 kbar and equivalent temperatures from structurally higher positions in the overlying Everest Series, through the LD and into GHS. This transition is interpreted to result from the juxtaposition of the Everest Series in the hangingwall with the GHS footwall rocks during southward extrusion and decompression along the LD system. An age constraint for movement on the LD is provided by the crystallization age of the Nuptse granite (23.6 ± 0.7 Ma), a body that was emplaced syn‐ to post‐solid‐state fabric development. Microstructural evidence suggests that deformation in the LD progressed from a distributed ductile shear zone into the structurally higher Qomolangma detachment during the final stages of exhumation. When combined with existing geochronological, thermobarometric and structural data from the GHS and Main Central thrust zone, these results form the basis for a more complete model for the P–T–t–D evolution of rocks exposed in the Mount Everest region.     

Liquidus Equilibria in the System K2O-Na2O-Al2O3-SiO2-F2O-1-H2O to 100 MPa: II. Differentiation Paths of Fluorosilicic Magmas in Hydrous Systems

We investigated phase equilibria in the six-component systemNa₂O–K₂O–Al₂O₃–SiO₂–F₂O_–1–H₂Oat 100 MPa to characterize differentiation paths of naturalfluorine-bearing granitic and rhyolitic magmas. Topaz and cryoliteare stable saturating solid phases in calcium-poor systems.At 100 MPa the maximum solidus depression and fluorine solubilityin evolving silicic melts are controlled by the eutectics haplogranite–cryolite–H₂Oat 640°C and 4 wt % F, and haplogranite–topaz–H₂Oat 640°C and 2 wt % F. Topaz and cryolite form a binaryperalkaline eutectic at 660°C, 100 MPa and fluid saturation.The low-temperature nature of this invariant point causes displacementof multiphase eutectics with quartz and alkali feldspar towardsthe topaz–cryolite join and enables the silicate liquidusand cotectic surfaces to extend to very high fluorine concentrations(more than 30 wt % F) for weakly peraluminous and subaluminouscompositions. The differentiation of fluorine-bearing magmasfollows two distinct paths of fluorine behavior, depending onwhether additional minerals buffer the alkali/alumina ratioin the melt. In systems with micas or aluminosilicates thatbuffer the activity of alumina, magmatic crystallization willreach either topaz or cryolite saturation and the system solidifiesat low fluorine concentration. In leucogranitic suites precipitatingquartz and feldspar only, the liquid line of descent will reachtopaz or cryolite but fluorine will continue to increase untilthe quaternary eutectic with two fluorine-bearing solid phasesis reached at 540°C, 100 MPa and aqueous-fluid saturation.The maximum water solubility in the haplogranitic melts increaseswith the fluorine content and reaches 12· 5 ±0· 5 wt % H₂O at the quartz–cryolite–topazeutectic composition. A continuous transition between hydrousfluorosilicate melts and solute-rich aqueous fluids is not documentedby this study. Our experimental results are applicable to leucocraticfluorosilicic magmas. In multicomponent systems, however, thepresence of calcium may severely limit enrichment of fluorineby crystallization of fluorite. KEY WORDS: granite; rhyolite; topaz; cryolite; magmatic differentiation     

Contact Partial Melting of Granitic Country Rock, Melt Segregation, and Re-injection as Dikes into Ferrar Dolerite Sills, McMurdo Dry Valleys, Antarctica

Numerous, interconnected, granitic dikes (<30 cm in widthand hundeds of meters in length) cut Ferrar dolerite sills ofthe McMurdo Dry Valleys, Antarctica. The source of the graniticdikes is partial melting of granitic country rock, which tookplace in the crust at a depth of about 2–3 km adjacentto contacts with dolerite sills. Sustained flow of doleriticmagma through the sill generated a partial melting front thatpropagated into the granitic country rock. Granitic partialmelts segregated and collected at the contact in a melt-rich,nearly crystal-free reservoir adjacent to the initial doleritechilled margin. This dolerite chilled margin was subsequentlyfractured open in the fashion of a trapdoor by the graniticmelt, evacuating the reservoir to form an extensive complexof granitic dikes within the dolerite sills. At the time ofdike injection the dolerite was nearly solidified. Unusuallycomplete exposures allow the full physical and chemical processesof partial melting, segregation, and dike formation to be examinedin great detail. The compositions of the granitic dikes andthe textures of partially melted granitic wall rock suggestthat partial melting was characterized by disequilibrium mineraldissolution of dominantly quartz and alkali feldspar ratherthan by equilibrium melting. It is also unlikely that meltingoccurred under water-saturated conditions. The protolith granitecontains only 7 vol.% biotite and estimated contact temperaturesof 900–950°C suggest that melting was possible ina dry system. Granite partial melting, under closed conditions,extended tens of meters away from the dolerite sill, yet meltsegregation occurred only over less than one-half a meter fromthe dolerite chilled margin where the degree of partial meltingwas of the order of 50 vol.%. This segregation distance is consistentwith calculated length scales expected in a compaction-drivenprocess. We suggest that the driving force for compaction wasdifferential stress generated by a combination of volume expansionas a result of granite partial melting, contraction during doleritesolidification, and relaxation of the overpressure driving doleriteemplacement. On a purely chemical basis, the extent of meltsegregation necessary under fractional and batch melting tomatch the Rb concentrations between melt and parent rock isa maximum of 48 and 83 vol.% melt, respectively. KEY WORDS: Antarctica; dike injection; disequilibrium; granite partial melting; silicic melt segregation     

扬子陆块西缘中元古代晚期元谋花岗岩的时代、成因及构造意义

扬子陆块西缘晚中元古代地质演化史一直存在较大争议,本文选择以扬子西缘元谋杂岩中一套二长花岗岩为研究对象,开展岩相学、锆石U-Pb年代学、全岩地球化学等综合研究,为认识和理解扬子西缘晚中元古代地质演化提供支撑。两件元谋二长花岗岩样品的LA-ICP-MS锆石U-Pb年龄分别为1086±10 Ma（MSWD=1.4,n=50）和1099±10 Ma（MSWD=1.8,n=58）。所有样品具有高硅（SiO₂为69.44%~73.98%）、富碱（Na₂O+K₂O为6.11%~7.72%）、贫钙（CaO为0.39%~1.46%）、贫镁（MgO为0.52%~0.76%）、低钛（TiO₂为0.30%~0.59%）的特点,同时表现出强过铝质（A/CNK=1.19~1.35）及中钾钙碱性–钾玄岩系列特征。它们具有高的稀土元素总量（∑REE=211.60×10^-6~349.01×10^-6）,呈现轻稀土元素富集和重稀土元素亏损（（La/Yb）_N=4.32~7.36）;富集Rb、U、Th等大离子亲石元素和Zr、Th、Hf等,亏损Nb、Ta、Ba等元素,并具有明显的负Eu异常（δEu=0.46~0.59）,锆石饱和温度介于827~912℃之间,展示了A型花岗岩的属性。这些二长花岗岩可能是通过中上地壳的中酸性火成岩的部分熔融形成,结合前人的研究成果,它们最可能形成于弧后的伸展环境,综合扬子陆块周缘晚中元古代的岩浆记录,元谋杂岩中1.09 Ga二长花岗岩的形成应与扬子陆块开始参与Rodinia超大陆聚合有关。     

内蒙古沙麦钨矿花岗岩岩石地球化学、锆石U-Pb年代学及其地质意义

沙麦钨矿床位于内蒙古东乌旗地区,是该区目前已探明的中型岩浆热液型钨矿床。矿体主要赋存在黑云母二长花岗岩和黑云母二长花岗斑岩中,对这两种花岗质岩石的岩相学、岩石地球化学和LA-ICP-MS锆石U-Pb年代学进行了研究。结果表明,黑云母二长花岗岩锆石U-Pb年龄为135.6±1.6 Ma和136.3±1.8 Ma,黑云母二长花岗斑岩锆石U-Pb年龄为138.6±1.1 Ma,二者侵位时间均为早白垩世。两种花岗质岩体具有富SiO₂(73.73%～78.23%)、高钾钠(Na₂O+K₂O)(7.56%～8.89%)、贫MgO(0.09%～0.20%)、贫CaO(0.51%～0.89%)、贫TiO₂(0.03%～0.12%)的特征,属于过铝质-高钾钙碱性系列;微量元素富集Rb、K、Th和U,相对亏损Sr、Ba、Nb、P和Ti元素,具有强烈的Eu负异常,具有较高的FeO^T含量,较高的FeO^T/MgO和FeO^T/(FeO^T+M...     

卸荷-增孔压条件下花岗岩残积土的力学特性

建（构）筑物因土中孔隙水压力升高而失稳破坏的情形屡见不鲜,常剪应力增孔压试验是相关研究的常用手段,但迄今鲜见考虑施工期开挖卸荷影响的试验研究。为探究初始卸荷对花岗岩残积土增孔压过程力学行为的影响,在常规增孔压试验中增加了初始卸荷阶段,开展了一系列考虑初始卸荷程度和卸荷滞时影响的卸荷-增孔压试验,分析土体变形、屈服和强度特性的初始卸荷效应与卸荷滞时效应,并与常规增孔压试验结果对比以揭示初始应力路径的影响。试验结果表明：增孔压过程的变形发展具有明显的阶段性,土体屈服后因其剪胀潜势和变形迅速而产生负超静孔压增量,有效平均应力转而增大;初始卸荷对增孔压过程土体力学性能具有明显的劣化作用,表现为刚度与屈服强度均随初始卸荷程度的增大而衰减;与被动压缩这种“加荷”式应力路径相比,初始卸荷的不利影响更为显著;土体力学性能的劣化随卸荷滞时的增长而加剧;屈服摩擦角随初始卸荷程度的增大逐渐减小,但始终大于临界状态摩擦角。     

Geochronology,Petrogenesis and Tectonic Setting of the Late Jurassic I-type Granites in the North Qinling Orogenic Belt,Central China

The North Qinling Orogenic Belt(NQOB) is a composite orogenic belt in central China. It started evolving during the Meso–Neoproterozoic period and underwent multiple stages of plate subduction and collision before entering intra-continental orogeny in the Late Triassic. The Meso–Cenozoic intra-continental orogeny and tectonic evolution had different responses in various terranes of the belt, with the tectonic evolution of the middle part of the belt being particularly controversial. The granites...