The last glacial-interglacial transition and dinoflagellate cysts in the western Mediterranean Sea

Using the analysis of dinoflagellate cysts in three deep-sea sediments cores situated in the Sicilian-Tunisian Strait, in the Gulf of Lions and in the Alboran Sea, we reconstruct the paleoenvironmental changes that took place during the last glacial-interglacial transition in the western Mediterranean Sea. The development of the warm microflora Impagidinium aculeatum and especially Spiniferites mirabilis appears to be an important proxy for recognizing warm periods as the Bölling/Alleröd and the Early Holocene. Bitectatodinium tepikiense, Spiniferites elongatus and Nematosphaeropsis labyrinthus mark the end of the Heinrich event 1 and the Younger Dryas. This cold microfloral association confirms the drastic climate changes in the western Mediterranean Sea synchronous to the dry and cold climate which occurred in the South European margin. The dinocyst N. labyrinthus shows high percentages in all studied regions during the Younger Dryas. Its distribution reveals a significant increase from the South to the North of this basin during this cold brief event. Thus, we note that this species can be considered as a new eco-stratigraphical tracer of the Younger Dryas in the western Mediterranean Sea.     

The Ledsjö end moraine—a subaquatic push moraine composed of glaciomarine clay in central Sweden

During the Younger Dryas cold event, the Scandinavian ice sheet readvanced in southwest Sweden and formed the Middle Swedish end-moraine zone (MSEMZ). Recent highway construction near Skara has created an exposure through the prominent ridge at Ledsjö. Through sketching and measurement of structural information, we have documented the internal character of the Ledsjö moraine. The moraine consists predominantly of clay with numerous sand pods and lenses, which show undeformed, brittle deformed, or fluidized structures. Based on geomorphology and structural geology, it is clear the moraine was made during two advances. As ice advanced, proglacial marine clay was subglacially mobilized by the ice and extruded at the ice margin forming a ramp of debris-flow sediment. Contemporaneously, subglacial meltwater transported sand to the margin, where the meltwater became a buoyant plume, and sand was deposited near the ice margin by currents moving away from as well as toward the ice margin. These processes resulted in interbedded sand and clay. Continued advance of the ice margin deformed this package and further pushed the assemblage into a ridge form with gravity sliding of portions of the ridge. Prior to the second advance, sand was deposited on the proximal side of the initial ridge. During readvance, this sand was thrust faulted and intruded by mobilized clay. Up ice of the intruded sands, subglacial, extensional deformation created a complex shear zone of faulted sand and clay. The Ledsjö moraine represents a subaerial example of submarine push moraines like the submerged moraines recently documented in Svalbard.     

Centennial-scale Asian monsoon variability during the mid-Younger Dryas from Qingtian Cave,central China

The regional climate correlation within the Northern Hemisphere in the cold/dry mid-Younger Dryas event (YD) remains elusive. A key to unraveling this issue is sufficient knowledge of the detailed climate variability at the low latitudes. Here we present a high-resolution (3-yr) δ¹⁸O record of an annually laminated stalagmite from central China that reveals a detailed Asian monsoon (AM) history from 13.36 to 10.99 ka. The YD in this record is expressed as three phases, characterized by gradual onsets but rapid ends. During the mid-YD, the AM variability exhibited an increasing trend superimposed by three centennial oscillations, well-correlated to changes in Greenland temperatures. These warming/wetting fluctuations show a periodicity of ~ 200 yr, generally in agreement with centennial changes in cosmogenic nuclides indicated by the ¹⁰Be flux from the Greenland ice. This relationship implies that centennial-scale climate changes during the mid-YD are probably caused by solar output and rapidly transported over broad regions through atmosphere reorganization.     

Arc magmatism in the Delhi Fold Belt: SHRIMP U–Pb zircon ages of granitoids and implications for Neoproterozoic convergent margin tectonics in NW India

The northwestern region of Peninsular India preserves important records of Precambrian plate tectonics and the role of Indian continent within Proterozoic supercontinents. In this study, we report precise SHRIMP zircon U–Pb ages from granitoids from the Sirohi terrane located along the western fringe of the Delhi Fold Belt in Rajasthan, NW India. The data reveal a range of Neoproterozoic ages from plagiogranite of Peshua, foliated granite of Devala, and porphyritic granite of Sai with zircon crystallization from magmas at 1015 ± 4.4 Ma, 966.5 ± 3.5 and 808 ± 3.1 respectively. The plagiogranite shows high SiO₂, Na₂O and extremely low K₂O, Rb, Ba, comparable with typical oceanic plagiogranites. These rocks possess low LREE and HREE concentrations and a relatively flat LREE–HREE slope, a well-developed negative Eu-anomaly and conspicuous Nb and Ti anomalies. Compared to the plagiogranite, the foliated Devala granite shows higher SiO₂ and moderate Na₂O, together with high K₂O and comparatively higher Rb, Ba, Sr and REE, with steep REE profiles and a weak positive Eu anomaly. In contrast to the plagiogranite and foliated granite, the porphrytic Sai granite has comparatively lower SiO₂ moderately higher Na₂O, extremely high Y, Zr, Nb and elevated REE. The geochemical features of the granitoids [HFSE depletion and LILE enrichment, Nb- and Ta-negative anomalies], and their plots in the fields of Volcanic Arc Granites and those from active continental margins in tectonic discrimination diagrams suggest widespread Neoproterozoic arc magmatism with changing magma chemistry in a protracted subduction realm. Our results offer important insights into a long-lived active continental margin in NW India during early and mid Neoproterozoic, consistent with recent similar observations on Cryogenian magmatic arcs widely distributed along the margins of the East African Orogen, and challenge some of the alternate models which link the magmatism to extensional tectonics associated with Rodinia supercontinent breakup.     

Paleomagnetic evidence for a large counterclockwise rotation of northern Greece prior to the Tertiary clockwise rotation

Abstract

This study aims at unravel the geotectonic evolution of northern Greece prior to the already established Tertiary clockwise rotation. Therefore, Mesozoie sediments, Early Mesozoie ophiolites and Carboniferous granites were sampled. While the metamorphosed and/or too weakly magnetized limestones had to be rejected, the gabbros and serpentinites of the 80 km long Chalkidiki belt (40.4°N, 23.3”E), and the granites of the northern Pelagonian zone (40.8°N, 21.2°E) have yielded similar results interpretable in terms of geoleetonies. In both areas the demagnetizing process has revealed a poh phased magnetic evolution.

The oldest magnetizations, labelled M (D=311°, I=20°, a₉₅, = 15°; VGP: 37°N, 272.5°, for the ophiolites; D=320.5°, I = 26°, a₉₅ =11°; VGP : 46°N, 264.5”E, for the granites) are interpreted as overprints acquired in Late Jurassic-Cretaceous times. The younger magnetizations, called C2 (D = 66°, I = 28°, a₉₅ = 9°; VGP : 28°N, 117°E, in the ophiolites ; D=64°, I = 2° a₉₅, = 11°; VCP : 20°N, I28°E, in the granites) are Tertiary overprints. Northeasterly C’ directions with negative inclinations (and conversely) are considered as overprints empiaceli prior to the Ca magnetizations ; they are interpreted as due to a barkthrusting of the ophiolilic belt of Chalkidiki and of the N. Pelagonian granitic belt, during the Early - Middle Tertiary convergence phase. The large deviation from the M to the C₂ directions, also observed by other authors in Mesozoic volcanics and sediments, results from a counterclockwise rotation of the Hellenides, probably in the Late Cretaceous as it is the case for the counterclockwise rotations of the western Mediterranean microplates. The deviation from the C₂ to the present field direction is due to a clockwise rotation of all Hellenic zones, probably in several phases.     

河北平原沉积物中记录的新仙女木事件

河北平原的高阳、羊二庄、南庄头孢粉剖面和阳原、怀涿盆地的冻融褶皱清楚地记录了冰期向全新世过渡中的新仙女木气候逆转事件.河北平原的新仙女木降温事件以冷干为特征,降温幅度约8℃.     

Lower crustal melting and the role of open-system processes in the genesis of syn-orogenic quartz diorite–granite–leucogranite associations: constraints from Sr–Nd–O isotopes from the Bandombaai Complex, Namibia

The Bandombaai Complex (southern Kaoko Belt, Namibia) consists of three main intrusive rock types including metaluminous hornblende- and sphene-bearing quartz diorites, allanite-bearing granodiorites and granites, and peraluminous garnet- and muscovite-bearing leucogranites. Intrusion of the quartz diorites is constrained by a U–Pb zircon age of 540±3 Ma.

Quartz diorites, granodiorites and granites display heterogeneous initial Nd- and O isotope compositions (_{Nd (540 Ma)}=−6.3 to −19.8; δ¹⁸O=9.0–11.6‰) but rather low and uniform initial Sr isotope compositions (⁸⁷Sr/⁸⁶Sr_initial=0.70794–0.70982). Two leucogranites and one aplite have higher initial ⁸⁷Sr/⁸⁶Sr ratios (0.70828–0.71559), but similar initial _Nd (−11.9 to −15.8) and oxygen isotope values (10.5–12.9‰). The geochemical and isotopic characteristics of the Bandombaai Complex are distinct from other granitoids of the Kaoko Belt and the Central Zone of the Damara orogen. Our study suggests that the quartz diorites of the Bandombaai Complex are generated by melting of heterogeneous mafic lower crust. Based on a comparison with results from amphibolite-dehydration melting experiments, a lower crustal garnet- and amphibole-bearing metabasalt, probably enriched in K₂O, is a likely source rock for the quartz diorites. The granodiorites/granites show low Rb/Sr (<0.6) ratios and are probably generated by partial melting of meta-igneous (intermediate) lower crustal sources by amphibole-dehydration melting. Most of the leucogranites display higher Rb/Sr ratios (>1) and are most likely generated by biotite-dehydration melting of heterogeneous felsic lower crust. All segments of the lower crust underwent partial melting during the Pan-African orogeny at a time (540 Ma) when the middle crust of the central Damara orogen also underwent high T, medium P regional metamorphism and melting. Geochemical and isotope data from the Bandombaai Complex suggest that the Pan-African orogeny in this part of the orogen was not a major crust-forming episode. Instead, even the most primitive rock types of the region, the quartz diorites, represent recycled lower crustal material.     

花岗岩成因研究的若干问题

花岗岩是大陆地壳的重要组成,是地质学研究的重要课题。本文对当前花岗岩研究中的几个重要问题进行了讨论,内容包括:(1)花岗岩的成因分类,(2)花岗岩浆起源的温度与压力条件,(3)结晶分异作用与花岗岩成分变化,(4)花岗岩成因与壳幔演化,(5)花岗岩形成的构造环境等。通过分析认为,高分异花岗岩成因类型的确定是比较困难的,在有些情况甚至不可能准确分类。花岗岩的锆饱和温度和锆石钛温度计可对花岗岩浆形成的温度提供重要信息,但花岗岩浆起源的压力条件确定相对困难。花岗岩主要形成于俯冲带或碰撞造山带后造山的拉张构造背景中,在这两种情况下,挥发份和热的加入可使地壳发生部分熔融而形成花岗岩。本文还对我国近年来花岗岩研究的进展情况做了概要性叙述,并就我国东部中生代花岗岩研究的近期突破问题进行了分析。     

花岗岩类岩石成因的磷灰石微区地球化学和同位素示踪

花岗岩类岩石是大陆地壳最重要的组成部分,通常伴生金属矿产,其成因研究可用来探索大陆地壳的形成、演化及动力学机制,并指导矿产资源的勘探。花岗岩类岩石是由岩浆经过结晶分异、地壳混染和岩浆混合等复杂演化过程形成的,且其母岩浆通常来源于不同的岩浆源区。如何准确示踪岩浆源区性质和精细刻画岩浆演化、岩石成岩过程是花岗岩成因研究的关键。磷灰石作为花岗岩类岩石中常见的副矿物,其结晶历史时间长——贯穿整个岩浆演化阶段,且富含F、Cl等挥发分和Sr、REE等微量元素,其化学特征和同位素组成在示踪花岗岩岩浆源区和成岩过程方面有独特的优势。随着微区分析技术的发展,磷灰石的微区地球化学成分记录了寄主岩浆的成分及其变化过程,可从微观角度揭示花岗岩的成因。本文结合前人研究成果及作者近年来的相关工作,系统综述磷灰石微区地球化学研究的进展,探讨如何在岩相学观察的基础上利用磷灰石的结晶过程、微区成分环带和微区同位素组成示踪岩浆源区、岩浆演化和成岩过程,以期为探索花岗岩精细成岩过程提供有效示踪方法。

     

作为赋存于花岗岩中钨锡矿化勘探指南的流体包裹体异常——前景展望

Studies of the distribution and abundance of fluid inclusions in granitic quartz associated with granite-hosted Sn-W mineralization of the British Isles reveal local and regional scale anomalies.At a sampling interval of c.5～50m,inclusion abundances increase towards zones of vein and stockwork mineralization exemplified by case history examples from exploration prospects in the Mourne Mountains of Northern Ireland and the Carrock Fell mining district of northwestern England.These steam aureoles provide a greater exploration target than the zone of visible alteration and mineralization and the lithogeochemical halo.But it is important to link them to geochemical data on fluid inclusion compositions,such as the semi-quantitative data from decrepitation-linked,ICP-AES (D-ICP)analysis,to optimize their exploration potential.Regional scale fluid inclusion anomalies,based on sampling intervals of c. 2km from the Sn-W mineralized granites of southwest England also broadly correlate with zones of intense mineralization in some areas. Regional-scale D-ICP analyses of quartz from SW England granites did not provide any convincing regional scale anomalies linked to mineralization except for positive boron anomalies around the centrally-mineralized Birch Tor area of the Dartmoor granite.Follow-up D-ICP analysis of quartz from stream sediments from this area,however,could be used to discriminate between samples related to mineralization from those draining unmineralized areas,using multivariate statistical analysis.At the present stage of development, the main contribution of fluid inclusion studies to mineral exploration is mostly limited to the conceptual stage where they continue to contribute to ore genetic theory and models.Costs and lack of knowledge transfer between research scientists and mineral explorationists limit their direct use during regional and target selection stages of exploration.Analysis of steam sediment quartz,using the more sensitive ICP-MS technique as a variant of the D-ICP method,appears to offer the greatest potential for future development as an exploration tool.