云南武定迤腊厂铜矿含矿石英脉40 Ar-39Ar年龄及其意义

对武定迤腊厂铜矿成矿期石英进行了40Ar-39Ar同位素年龄测定,得到马鞍形年龄谱,坪年龄为(784.25±0.95)Ma,等时线年龄为(783.93±8.59)Ma.地质特征研究表明该矿床后期改造作用明显,并非同生沉积或成岩作用早期成矿,而与晋宁期Rodina大陆裂解有关.武定迤腊厂铜矿的形成可能是在Rodinia大陆裂解时,从深部带来大量成矿物质,改造成岩时期初始的矿化,形成矿床的叠加富集和最终定位,晋宁-澄江期是该矿床的主成矿期.     

东川桃园式铜矿Ar-Ar同位素年龄及意义

通过对东川桃园铜矿与铜矿共生石英的40Ar/39Ar同位素年龄的测定,得到马鞍形年龄谱,其坪年龄为768.43Ma±0.58Ma,等时线年龄为770.00Ma±5.44Ma。该矿床后期改造作用明显,并非同生沉积或成岩作用早期成矿,而与晋宁期Rodina大陆裂解有关。东川铜矿的形成可能是在Rodinia大陆裂解时,从深部带来大量成矿物质改造成岩时期初始的矿化,形成矿床的叠加富集和最终定位,因此,晋宁-澄江期是东川铜矿的主成矿期。     

The impact of hydrological changes on travertine deposits related to thermal springs in the Pamukkale area (SW Turkey)

Pamukkale thermal waters (35 °C), exhibiting calcium-bicarbonate-sulfate composition and high carbon dioxide concentration, are of a predominantly meteoric origin. The meteoric fluid, circulating through faults and fractures, is heated by magmatic intrusions at great depth, and ascends from deep reservoirs to the surface. Mixing with relatively cold groundwater in the near surface zone promotes different saturation conditions with respect to calcium carbonate that later precipitates at depth and/or the surface. Dissolution-deposition processes of calcium carbonate both at surface and depth environments may help to reconstruct past climate direction in the field. During wet climate conditions a high-rate of calcium carbonate accumulation would be expected to occur at the surface because thermal fluid would be under-saturated with respect to calcium carbonate at depth because of a relatively higher mixing ratio with cold groundwater. During dry climate conditions the thermal fluid would be super-saturated at depth because of the highly acidic environment. Hydrometeorological studies reveal that the annual precipitation at the Pamukkale hydrothermal field tends to decrease with time. This climatic change in the area was also detected from geological records. While humid climate conditions prevailed during the late Quaternary, the area has recently been affected by arid/semi-arid climate conditions, followed by some episodic transitions. This study has shown how the system has possibly reacted to different climate conditions since antiquity.     

Experimental study on reduction of U (Ⅵ) by an anaerobic bacterium, Shewanella putrefaciens: Application to sandstone-hosted interlayer oxidation-zone type uranium deposits, China

An experimental study on reduction of U (Ⅵ) by anaerobic bacteria, Shewane//a putrefaciens, is first reported here in China. The experimental conditions were: 35℃ and pH =7.0-7.4, corresponding to a physicochemical environments in which the sandstone-hosted interlayer oxidation-zone type uranium deposit formed in Northwest China's Xinjiang. Bacteria adopted in the present experiment, Shewanella putrefaciens, occur extensively in natural environment. Our study shows that nano-crystal precipitates of uraninite quickly occurred on the surface of the cells within one week. It was found that the pitchblende was characterized by a random arrangement of uraninite nanocrystals (2-4 nm) in it, significantly different from natural pitchblende in which uraninite nanocrystals are arranged in order. Finally, a possible mechanism of uranium biomineralization by microorganisms in the deposits is discussed. Our investigation may supply a technical train of thoughts for bioremediation of nuclear-contaminated water environments and for underground dissolving extraction of the sandstone-hosted uranium ores.     

西藏自治区乃东县劣布铜矿综合地质特征

文章介绍区域地质背景、矿区地物化特征，对成矿时代、流体包裹体特征进行初步研究，并指出找矿远景，希望对矿区的矿产勘查具有借鉴和指导意义。     

云南个旧卡房铜多金属矿床流体包裹体特征及其地质意义

卡房铜多金属矿床位于云南省个旧锡多金属矿集区, 作为该区南段典型的铜多金属矿床, 其深入的成矿流体性质及成矿物质来源研究尚为薄弱, 限制了对该矿床成因的深入认识。本文对产于玄武岩中的似层状铜多金属矿体(主要成矿类型)开展了精细的野外岩相学、矿物学、C-H-O同位素及流体包裹体原位成分分析。结果显示, 流体包裹体主要为气液两相水溶液包裹体, 石英流体包裹体均一温度为 264.5~330.5 ℃、盐度w(NaCleq)为16.24%~18.20%、密度为0.853~0.924 g/cm3; 萤石流体包裹体均一温度为199.8~339.1 ℃、盐度w(NaCleq)为8.81%~18.88%、密度为0.822~0.955 g/cm3; 方解石流体包裹体均一温度为112.1~199.4 ℃、盐度w(NaCleq)为4.96%~10.86%、密度为0.910~1.011 g/cm3, 表明卡房铜多金属矿床成矿流体具有中低温、中低盐度、低密度特征, 且早阶段到晚阶段, 成矿温度和流体盐度明显降低。与Cu矿共生的石英δDV-SMOW值为–83.9‰ ~ –78.9‰, δ18OH2O值为4.63‰~12.14‰, 方解石δ13CV-PDB值为–7.11‰~ 0.64‰; 同时, 石英单个流体包裹体原位分析结果显示流体包裹体富集大离子亲石元素, 如Na、K、Rb、Cs、Sr等。这些特征暗示了流体可能来源于与花岗质岩浆有关的热液流体, 热液流体上升过程中与围岩碳酸盐岩发生强烈的水-岩反应; 该过程可能萃取了玄武岩层中的Cu物质, 诱发了Cu的富集并最终成矿。     

云南金沙厂铅锌矿床地球化学特征及其指示意义

位于扬子地块西南缘的“川滇黔铅锌矿集区”是我国西南大面积低温成矿域的重要组成部分, 金沙厂铅锌矿床是其中典型矿床之一, 前人针对金沙厂矿床的成矿物质来源和成矿流体特征开展了大量研究, 但围岩对成矿的贡献和矿床成因仍不明确。针对这一问题, 本文系统分析了金沙厂闪锌矿及围岩的微量元素组成, 结合围岩和萤石的稀土元素特征, 探讨了围岩对成矿的贡献, 厘定了矿床成因。研究表明, 闪锌矿以富集Cd、Ge、Cu、Ga, 贫Fe、Mn、In、Co、Ni为特征, 这些元素多以类质同象的形式赋存在闪锌矿中, 个别元素如Cu、Ge等含量变化范围较大, 可能与低温流体有关。矿床中闪锌矿存在多种颜色的原因可能是Cu、Ge等多种元素共同作用的结果。近矿端的围岩明显富集Zn、Pb、As、Cd等元素, 而闪锌矿中同样富集这些元素, 说明围岩为成矿提供了部分金属元素。萤石继承了围岩的Eu、Ce负异常, 并受到了具有较高Ce负异常的成矿流体影响。萤石较围岩具有较高的Y/Ho比值, 说明萤石中的部分Y来源于围岩, 从而导致萤石具有较高的Y/Ho值。总体上, 该矿床中闪锌矿微量元素组成与MVT矿床基本一致, 明显有别于喷流沉积型、岩浆热液型和远端夕卡岩型矿床, 其成矿温度属于低温范围, 结合其矿床地质地球化学特征, 本文认为金沙厂铅锌矿床属于MVT铅锌矿床。     

华南锑矿带单锑型锑矿床“两层楼”二元成矿模型——以滇东南木利锑矿床为例

华南锑矿带是我国乃至世界上最重要的锑成矿带, 分布有众多大型-超大型单锑型锑矿床。本文以滇东南木利锑矿床作为主要研究对象, 并与华南锑矿带内单锑型矿床中最典型的锡矿山和独山锑矿田(床)进行详细的基础地质特征对比研究。发现对于单锑型锑矿田(床)而言, 无论是矿田尺度还是矿床尺度, 普遍具有“石英-辉锑矿”和“方解石-辉锑矿”两种矿石类型。同一矿田内, 部分矿床(段)以“石英-辉锑矿”的矿物组合为主, 部分以“方解石-辉锑矿”的矿物组合为主; 而矿床(段)尺度内, 又往往表现为上部“石英-辉锑矿”型矿物组合, 下部为“方解石-辉锑矿”型矿物组合的两层楼模式。该模型的提出对于华南锑矿带单锑型矿床成因研究和找矿勘查具有重要意义。     

云南镍钴矿成矿规律及找矿方向

镍、钴是我国重要的紧缺战略性矿产, 其保障程度对国家稳定和发展具有重要意义。云南省作为有色金属王国, 已发现了镍矿床(点)42处, 钴矿床(点)48处, 查明资源量位于全国前列, 具有较好的镍、钴矿找矿潜力。本文在前人研究工作基础上, 梳理了云南省镍、钴矿床的成因类型、时空分布和成矿作用, 总结成矿规律, 并探讨找矿方向。云南省镍、钴矿床可划分为岩浆型、岩浆热液型、海相火山岩型、受变质型、中-低温热液型和风化型6种矿床类型。镍、钴矿主要集中于扬子陆块及三江造山带, 镍矿床主要形成于印支期及喜马拉雅期, 钴矿床主要形成于喜马拉雅期、晋宁期及印支期。岩浆型和风化型镍、钴矿床与印支期扬子陆块的基性-超基性岩侵入活动关系密切, 中-低温热液型钴矿与喜马拉雅期的构造活动相关, 海相火山岩型和受变质型钴矿则是位于扬子陆块内与晋宁期火山活动相关的昆阳群和大红山岩群中。通过对全省镍、钴矿成矿作用分析和成矿规律总结, 结合潜力评价工作成果, 全省共圈定8处找矿远景区。为云南省新一轮找矿突破战略行动镍、钴矿勘查部署提供思路。     

胶东地区与金矿成矿有关的花岗岩体中的流体包裹体研究

与胶东金矿有密切关系的玲珑片麻状花岗岩、栾家河二长花岗岩、郭家岭花岗闪长岩、上庄二长花岗岩4种类型花岗岩中矿物包裹体的发育程度、类型、大小及其特点, 以及包裹体的显微测温结果, 反映出玲珑岩体是经历了高级区域变质作用形成的重熔型花岗岩, 郭家岭岩体是由高温、高粘度岩浆结晶成岩的。栾家河岩体是由一种富CO₂的高温、高粘度的岩浆中结晶演化而来, 岩体的侵入深度也较浅。上庄岩体形成温度压力较低。