交流电弧发射光谱的不同灵敏度谱线测定锡

根据交流电弧发射光谱法具有可同时测定多个元素和多条谱线的优势,探讨了利用Sn的灵敏线(317.502 nm)和次灵敏线(285.062 nm)同时测定Sn含量范围跨度较大的样品。对GBZ-Ⅱ型光谱相板测光仪的软件工作条件进行特殊设置,通过灵敏线317.502 nm测定样品中x~xxμg/g的Sn,次灵敏线285.062 nm测定样品中0.0x%~x%的Sn。本方法同时测定两条不同灵敏度的分析谱线,兼顾了交流电弧发射光谱法具有较高灵敏度的优点,拓展了样品的测试范围,避免了传统方法中对高含量样品需进行稀释后再次测定可能带来的污染以及人为引入的误差。     

TTGs and adakites: are they both slab melts?

Although both high-Al TTG (tonalite–trondhjemite–granodiorite) and adakite show strongly fractionated REE and incompatible element patterns, TTGs have lower Sr, Mg, Ni, Cr, and Nb/Ta than most adakites. These compositional differences cannot be easily related by shallow fractional crystallization. While adakites are probably slab melts, TTGs may be produced by partial melting of hydrous mafic rocks in the lower crust in arc systems or in the Archean, perhaps in the root zones of oceanic plateaus. It is important to emphasize that geochemical data can be used to help constrain tectonic settings, but it cannot be used alone to reconstruct ancient tectonic settings.

Depletion in heavy REE and low Nb/Ta ratios in high-Al TTGs require both garnet and low-Mg amphibole in the restite, whereas moderate to high Sr values allow little, if any, plagioclase in the restite. To meet these requirements requires melting in the hornblende eclogite stability field between 40- and 80-km deep and between 700 and 800 °C.

Some high-Al TTGs produced at 2.7 Ga and perhaps again at about 1.9 Ga show unusually high La/Yb, Sr, Cr, and Ni. These TTGs may reflect catastrophic mantle overturn events at 2.7 and 1.9 Ga, during which a large number of mantle plumes bombarded the base of the lithosphere, producing thick oceanic plateaus that partially melted at depth.     

三江地区义敦岛弧造山带演化和成矿系统

义敦岛弧是喜马拉雅巨型造山带中的一个复合造山带,它经历了印支期洋壳俯冲造山、燕山湖弧-陆碰撞和喜马拉雅期陆内走滑作用诸演化历史。可能由于洋壳板片俯冲角度不同,义敦晚三叠世古岛弧带(206～237 Ma)南北两段具有不同的发育历史,北段昌台弧以发育孤间裂谷为特色,具张性弧特征,发育扩张环境流体聚敛成矿系统,形成VMS型Zn-Pb-Cu矿床和浅成低温热液型Ag-Au-Hg矿床;南段中甸弧不发育弧后盆地,但广泛发育钙碱性弧火山岩-玢岩-斑岩杂岩系和挤压环境岩浆-流体成矿系统,形成斑岩型-夕卡岩型铜多金属矿床。在三叠纪-侏罗纪之交的弧-陆碰撞作用中,早期大陆板片俯冲形成同碰撞花岗岩带(约200 Ma),晚期造山后伸展作用,形成A型花岗岩带(75～138 Ma),伴随扬子大陆板片俯冲而发生的强烈剪切和推覆,在甘孜-理塘蛇绿混杂带发育挤压剪切环境流体聚敛成矿系统,形成剪切带型金矿。伴随造山后伸展和A型花岗岩侵位,发育伸张环境岩浆-流体聚敛成矿系统,主要形成夕卡岩型锡矿和构造破碎带热浪脉型银多金属矿床。印度-亚洲大陆碰撞在义敦造山带主要表现为陆内走滑作用,并控制碱性花岗岩和花岗斑岩的发育(50～30 Ma),伴随斑岩型金矿的形成。     

四川乡城-稻城地区花岗岩地球化学特征及构造背景探讨

四川乡城-稻城地区发育4套花岗岩体：包括石英闪长玢岩、花岗细晶岩、二长花岗（细晶）岩和花岗闪长岩,形成时代为印支期到燕山晚期。花岗岩的地球化学研究表明：w（SiO2）=57．82％～81．66％,σ=0．06～2．45,w（K2O＋Na2O）=1．38％～7．76％,AR=1．26～2．93,属于亚碱性岩体;EREE含量较低,轻稀土相对富集,δEu=0．09～1．28,（La／Yb）N=1．88～11．96,总体表现为右倾型。各套花岗岩微量元素地球化学特征差异明显,相对富集大离子亲石元素,贫化高场强元素,Rb／Sr=0．04～6．18。根据花岗岩的R1-R2,Rb—Yb＋Ta,Ta—Yb构造判别图解和区域构造演化史研究,认为二长花岗岩形成于板内构造环境,花岗细晶岩、闪长玢岩和花岗闪长岩形成于岛弧构造环境,其形成与义敦岛弧带碰撞造山活动有关。     

Reaction between slab-derived melts and peridotite in the mantle wedge: experimental constraints at 3.8 GPa

Laboratory experiments on natural, hydrous basalts at 1–4 GPa constrain the composition of “unadulterated” partial melts of eclogitized oceanic crust within downgoing lithospheric slabs in subduction zones. We complement the “slab melting” experiments with another set of experiments in which these same “adakite” melts are allowed to infiltrate and react with an overlying layer of peridotite, simulating melt:rock reaction at the slab–mantle wedge interface. In subduction zones, the effects of reaction between slab-derived, adakite melts and peridotitic mantle conceivably range from hybridization of the melt, to modal or cryptic metasomatism of the sub-arc mantle, depending upon the “effective” melt:rock ratio. In experiments at 3.8 GPa, assimilation of either fertile or depleted peridotite by slab melts at a melt:rock ratio 2:1 produces Mg-rich, high-silica liquids in reactions which form pyrope-rich garnet and low-Mg# orthopyroxene, and fully consume olivine. Analysis of both the pristine and hybridized slab melts for a range of trace elements indicates that, although abundances of most trace elements in the melt increase during assimilation (because melt is consumed), trace element ratios remain relatively constant. In their compositional range, the experimental liquids closely resemble adakite lavas in island-arc and continental margin settings, and adakite veins and melt inclusions in metasomatized peridotite xenoliths from the sub-arc mantle. At slightly lower melt:rock ratios (1:1), slab melts are fully consumed, along with peridotitic olivine, in modal metasomatic reactions that form sodic amphibole and high-Mg# orthopyroxene.     

义敦岛弧带夏塞银铅锌矿床地质、物化探特征及综合找矿模型

夏塞银铅锌矿床位于义敦岛弧带中段,为典型的与早白垩世A型花岗岩有关的热液脉型矿床。矿体呈脉状、透镜状产于NNW向断裂构造中,具有向北侧伏、尖灭再现特点。从花岗岩体接触带往北发育Sn-Cu→Cu-Zn→Ag-Pb矿化分带。硅化、绢云母化、绿泥石化等蚀变与成矿关系密切。成矿过程划分为锡石、毒砂、闪锌矿-黄铜矿、含银矿物-方铅矿、黄铁矿-碳酸盐5个成矿阶段。高精度磁法测量ΔT正异常能有效识别矿化带或控矿断裂带。土壤地球化学测量Ag、Pb、Zn、Cu元素变化曲线峰值能指示矿化体的存在。据此建立了夏塞银铅锌矿床地质、磁法和土壤地球化学测量综合找矿模型,经验证找矿效果良好。有望为夏塞—连龙银锡多金属矿集区热液脉型矿床找矿勘查和评价工作提供重要参考。     

云南中甸地区翁水晚三叠世火山岩地球化学特征及其构造意义

“三江”构造带中甸弧北部的印支期岩浆活动目前尚无正式的研究报道.本文的岩石学及年代学的研究表明,中甸弧北部的翁水地区存在印支期中酸性岩浆活动,锆石U-Pb定年结果显示这些火山岩在211.1±1.5Ma喷发,与该地区的印支期火山岩与斑岩矿床的成矿斑岩的形成时代一致.翁水安山岩岩石地球化学特征显示其以中性的安山岩为主,具有亏损Nb、Ta、Ti等高场强元素的典型岛弧岩浆成分特征.与同一构造单元内中句弧南部的烂泥塘-浪都安山岩进行主、微量元素的对比研究发现,两者均具有正常岛弧火山岩的成分组成特征.结合其形成时代和构造背景,初步认为中甸弧北部的翁水和南部的烂泥塘-浪都安山岩以及该区域的成矿斑岩很可能形成于同一构造-岩浆事件,都是甘孜-理塘洋晚三叠世俯冲作用的岩浆产物.     

中天山早奥陶世弧岩浆岩的确定——来自桑树园子一带花岗质片麻岩年代学和地球化学证据

对新疆中天山东段桑树园子一带侵入中元古界星星峡群中的花岗质片麻岩进行LA-ICP-MS锆石U-Pb定年和地球化学研究.LA-ICP-MS锆石U-Pb定年结果表明,花岗质片麻岩原岩形成时代为(475.7±1.6) Ma,属早奥陶世岩浆活动产物,同时锆石25个测点中未发现有任何前寒武纪的残存锆石或时代信息.结合造岩矿物组合特征,认为其原岩为中-酸性侵入岩.岩石地球化学分析表明,花岗质片麻岩SiO2含量为62.45％～66.52％,K2O/Na2O变化于1.74～1.99,A/CNK值介于0.94～0.95,具高钾和弱过铝质的特征.稀土分布曲线呈右倾轻稀土富集型,弱的负铕异常,δEu值为0.69～0.76.岩石富集大离子亲石元素Rb,Sr,Ba,K等,亏损Nb和Ta等高场强元素及Ti和P,具Ⅰ型花岗岩特征.微量元素构造环境判别图解表明,花岗质片麻岩原岩可能形成于与俯冲有关的大陆边缘弧构造环境.结合岩石的锆石LA-ICP-MS定年结果和区域地质背景,认为桑树园子花岗质片麻岩原岩可能是以干沟蛇绿岩为代表的中天山北缘古大洋向南俯冲的弧岩浆岩记录.     

Mantle peridotites from the Western Pacific

We review petrographical and petrological characteristics of mantle peridotite xenoliths from the Western Pacific to construct a petrologic model of the lithospheric mantle beneath the convergent plate boundary. The peridotite varies from highly depleted spinel harzburgite of low-pressure origin at the volcanic front of active arcs (Avacha of Kamchatka arc and Iraya of Luzon–Taiwan arc) to fertile spinel lherzolite of high-pressure origin at the Eurasian continental margin (from Sikhote-Alin through Korea to eastern China) through intermediate lherzolite–harzburgite at backarc side of Japan island arcs. Oxygen fugacity recorded by the peridotite xenoliths decreases from the frontal side of arc to the continental margin. The sub-arc type peridotite is expected to exist beneath the continental margin if accretion of island arc is one of the important processes for continental growth. Its absence suggests replacement by the continental lherzolite at the region of backarc to continental margin. Asthenospheric upwelling beneath the continental region, which has frequently occurred at the Western Pacific, has replaced depleted sub-cratonic peridotite with the fertile spinel lherzolite. Some of these mantle diapirs had opened backarc basins and strongly modified the lithospheric upper mantle by metasomatism and formation of Group II pyroxenites.     

Lithium isotopic composition of Central American Volcanic Arc lavas: implications for modification of subarc mantle by slab-derived fluids

Li contents and isotopic compositions were determined for a suite of well-characterized basaltic lavas from the Central American Volcanic Arc (CAVA). Variable Li/Y (0.2–0.5), Li/Sc (0.1–0.4), and δ⁶Li values (+2.6 to −7.7‰) attest to significant compositional heterogeneity in the subarc mantle. Within specific arc segments, these parameters correlate strongly with each other and with a number of other constituents (e.g., K, Rb, Ba, B/La, ¹⁰Be/⁹Be, ⁸⁷Sr/⁸⁶Sr, U/Ce, and ²³⁰Th/²³²Th, among others); these correlations are particularly strong for Nicaragua samples. Coupling of this particular set of constituents is best explained in terms of addition of ‘subduction components' to the subarc mantle. Moreover, their selective enrichment with respect to relatively fluid-immobile incompatible elements signifies the dominance of fluid vs. silicate melt transport of slab components to the subarc mantle. Several interesting nuances are revealed by the Li data. First, although Li and B are strongly correlated in both Costa Rica and Nicaragua, there are systematic along-strike variations in Li/B that are consistent with these elements having different ‘fluid release patterns' from subducted slab segments. For example, Li/B is highest in Costa Rica where auxiliary evidence indicates higher subduction zone temperatures; apparently B is preferentially depleted and Li retained in the slab under warmer conditions. The same relations are reflected in Li/¹⁰Be and other subduction tracer systematics, all of which point to larger subduction contributions below Nicaragua. Yet, even Nicaragua lavas vary widely in levels of subduction enrichment. High-Ti basalts from Nejapa are the least enriched and have the highest δ⁶Li (1.4 to 2.6‰); these values are greater than in fresh MORB (ca. −4‰) and are not easily explained by additions of subducted Li because most oceanic crustal rocks and marine sediments have lower δ⁶Li than MORB (with typical values between −8 and −20‰). Thus, it appears the Nejapa data may be representative of isotopically light mantle domains. Relatively light δ⁶Li values in an undepleted spinel lherzolite (+11.3‰) from Zabargad Is. (Red Sea) and in primitive backarc basalts (−1.6 to −0.5‰) from Lau Basin support this conclusion. Considering representative fluid and mantle endmember compositions, the CAVA data are consistent with limited (up to a few percent) additions of slab-derived fluids to a heterogeneous mantle containing variably depleted and enriched domains to form the respective magma sources. In our view, the subarc mantle is heterogeneous on a small scale, but some arc sectors clearly received greater slab inputs than others.