High-temperature, high-pressure eclogite and garnet pyroxenite occur as lenses in garnet peridotite bodies of the Gföhl nappe in the Bohemian Massif. The high-pressure assemblages formed in the mantle and are important for allowing investigations of mantle compositions and processes. Eclogite is distinguished from garnet pyroxenite on the basis of elemental composition, with mg number <80, Na2O > 0.75 wt.%, Cr2O3 < 0.15 wt.% and Ni < 400 ppm. Considerable scatter in two-element variation diagrams and the common modal layering of some eclogite bodies indicate the importance of crystal accumulation in eclogite and garnet pyroxenite petrogenesis. A wide range in isotopic composition of clinopyroxene separates [Nd, +5.4 to –6.0; (87Sr/86Sr)i, 0.70314–0.71445; 18OSMOW, 3.8–5.8%o] requires that subducted oceanic crust is a component in some melts from which eclogite and garnet pyroxenite crystallized. Variscan Sm-Nd ages were obtained for garnet-clinopyroxene pairs from Dobeovice eclogite (338 Ma), Úhrov eclogite (344 Ma) and Nové Dvory garnet pyroxenite (343 Ma). Gföhl eclogite and garnet pyroxenite formed by high-pressure crystal accumulation (±trapped melt) from transient melts in the lithosphere, and the source of such melts was subducted, hydrothermally altered oceanic crust, including subducted sediments. Much of the chemical variation in the eclogites can be explained by simple fractional crystallization, whereas variation in the pyroxenites indicates fractional crystallization accompanied by some assimilation of the peridotite host. 相似文献
Mantle-derived garnets recovered in diamond exploration programs show compositional variations in Cr, Ca, Mg, Fe and Ti that reflect the chemical, physical and lithological environments in which they occur, occasionally together with diamond. The association of diamond with mantle garnet has progressed through a number of geochemical advances, most notably those of Dawson and Stephens (1975) and Gurney (1984), which are integrated in this work with less well known petrological advances made primarily in xenolith and experimental petrology. A simple, robust garnet classification scheme is formulated which accommodates empirical garnet–diamond relationships for peridotitic (G10, G9, G12), megacrystic (G1), Ti-metasomatised (G11), pyroxenitic (G4, G5) and eclogitic (G3) lithologies in eight distinct garnet classes. The calcium-saturation characteristics of harzburgitic (G10), lherzolitic (G9) and wehrlitic (G12) garnets are described by a Ca-intercept projection that also shows promise as a relative barometer for garnet lherzolite (Grütter and Winter, 1997). Thermobarometric aspects of garnet–diamond associations are highlighted in the scheme through the use of the minor elements Mn and Na, though analysis by anything other than an electron microprobe is not required for classification. A “D” suffix is added to the G10, G4, G5 or G3 categories to indicate a strong compositional and pressure–temperature association with diamond. The scheme remains open to improvement, particularly with regard to delineation of pyroxenitic (or websteritic) diamond associations and to advances in Ca-in-garnet and Na-in-garnet thermobarometry. 相似文献
Major element and Re–Os isotope analysis of single sulfide inclusions in diamonds from the 240 Ma Jwaneng kimberlite has revealed the presence of at least two generations of eclogitic diamonds at this locality, one Proterozoic (ca. 1.5 Ga) and the other late Archean (ca. 2.9 Ga). The former generation is considered to be the same as that of eclogitic garnet and clinopyroxene inclusion bearing diamonds from Jwaneng with a Sm–Nd isochron age of 1.54 Ga. The latter is coeval with the 2.89 Ga subduction-related generation of eclogitic sulfide inclusion bearing diamonds from Kimberley formed during amalgamation of the western and eastern Kaapvaal craton near the Colesberg magnetic lineament.
The Kimberley, Jwaneng, and Premier kimberlites are key localities for characterizing the relationship between episodic diamond genesis and Kaapvaal craton evolution. Kimberley has 3.2 Ga harzburgitic diamonds associated with creation of the western Kaapvaal cratonic nucleus, and 2.9 Ga eclogitic diamonds resulting from its accretion to the eastern Kaapvaal. Jwaneng has two main eclogitic diamond generations (2.9 and 1.5 Ga) reflecting both stabilization and subsequent modification of the craton. Premier has 1.9 Ga lherzolitic diamonds that postdate Bushveld–Molopo magmatism (but whose precursors have Archean Sm–Nd model ages), as well as 1.2 Ga eclogitic diamonds. Thus, Jwaneng provides the overlap between the dominantly Archean vs. Proterozoic diamond formation evident in the Kimberley and Premier diamond suites, respectively. In addition, the 1.5 Ga Jwaneng eclogitic diamond generation is represented by both sulfide and silicate inclusions, allowing for characterization of secular trends in diamond type and composition. Results for Jwaneng and Kimberley eclogitic sulfides indicate that Ni- and Os-rich end members are more common in Archean diamonds compared to Proterozoic diamonds. Similarly, published data for Kimberley and Premier peridotitic silicates show that Ca-rich (lherzolitic) end members are more likely to be found in Proterozoic diamonds than Archean diamonds. Thus, the available diamond distribution, composition, and age data support a multistage process to create, stabilize, and modify Archean craton keels on a billion-year time scale and global basis. 相似文献
Investigation of an eclogite xenolith, discovered in a Cretaceous granite from the Central Domain of the Dabieshan massif
in eastern China, yields new petrological insights into the high to ultrahigh-pressure metamorphism, experienced by the Qinling-Dabie
orogen. Prior to inclusion as a xenolith in the granite during the Early Cretaceous, this eclogite xenolith had recorded a
complex metamorphic evolution that complies with subduction and exhumation processes experienced by the continental crust
of the South China Block. Well-preserved mineral parageneses substantiate the prograde and retrograde stages revealed by inclusions
in porphyroblastic garnet and zoned minerals such as garnet, omphacite and amphibole in the matrix. The relatively low P/T
re-equilibration during a late metamorphic stage was textually inferred by the presence of aluminous and calcic-subcalcic
amphiboles such as katophorite, edenite, taramite and pargasite as main matrix phases. According to our U/Pb, Rb/Sr and new
40Ar/39Ar geochronological results, namely109 ± 1 and 112 ± 2 Ma plateau ages for muscovite and amphiboles, respectively, two successive
but distinct cooling stages account for the thermal history of the granite–migmatite gneiss dome that forms the Central Dabieshan
Domain. We argue that prior to the Cretaceous doming, the Central Dabieshan Domain experienced a tectono-metamorphic evolution
similar to that observed in the high-pressure to ultra high-pressure units developed in the Southern Dabieshan Domain and
Hong’an massif. 相似文献
Lawsonite eclogite pods ranging in size from 3 cm to 6 m occur in lawsonite blueschist and eclogite facies metasedimentary
and metabasaltic rocks in the Sivrihisar Massif, Turkey. Some pods have a core of lawsonite eclogite surrounded by alternating,
centimeter-scale layers of lawsonite blueschist, eclogite, and transitional eclogite–blueschist, all with similar basaltic
bulk composition. These pods also contain texturally late lawsonite-rich veins and layers. Most eclogites and blueschists
within the pods lack reaction textures, but some blueschists near pod margins contain texturally complex garnet as well as
glaucophane rims on omphacite, suggesting retrogression of eclogite to blueschist. Phase diagrams (pseudosections) calculated
for the lawsonite eclogite core of a meter-scale pod indicate that the eclogite equilibrated at ∼22–24 kbar, ∼520°C. Lawsonite
eclogite and blueschist at the tectonized margin of the same pod equilibrated at similar temperatures and slightly lower pressures.
The composite eclogite–blueschist pod is foliated, lineated, and folded. An earlier generation of lineated omphacite in the
pod core has a different spatial orientation than the lineation at the pod margin, although electron backscattered diffraction
data show that core and rim omphacite have similar lattice preferred orientation patterns. Petrologic and structural data
are consistent with mechanical formation of pods by folding and dissection of eclogite layers at high-P, and localized retrogression at pod margins during initial stages of exhumation at P–T conditions >425°C, 16 kbar. 相似文献