雅鲁藏布江结合带东段仁布-曲松地层分区上三叠统朗杰学(岩)群层序及构造样式再认识

雅鲁藏布江结合带东段夹在南、北两条蛇绿混杂岩带之间的一套活动类型的上三叠统朗杰学(岩)群,许多地质工作者对其地层层序、沉积特征、变形变质、物质来源以及形成的构造环境进行过研究。作者在前人工作成果的基础上,综合对比了已往区调工作获得的实际资料,以(构造)岩石地层为基础,结合沉积古生物特征、变形特征以及区域大地构造背景,对该岩(群)作了进一步的研究。初步认为:朗杰学(岩)群地层层序自老至新为宋热(岩)组、江雄(岩)组和姐德秀(岩)组(章村岩组);郎杰学(岩)群的构造样式为一"Ω"型两翼不对称的复式背斜构造。     

Geochronology and fluid inclusion study of the Yinjiagou porphyry–skarn Mo–Cu–pyrite deposit in the East Qinling orogenic belt,China

The Yinjiagou Mo–Cu–pyrite deposit of Henan Province is located in the Huaxiong block on the southern margin of the North China craton. It differs from other Mo deposits in the East Qingling area because of its large pyrite resource and complex associated elements. The deposit’s mineralization process can be divided into skarn, sulfide, and supergene episodes with five stages, marking formation of magnetite in the skarn episode, quartz–molybdenite, quartz–calcite–pyrite–chalcopyrite–bornite–sphalerite, and calcite–galena–sphalerite in the sulfide episode, and chalcedony–limonite in the supergene episode. Re–Os and ⁴⁰Ar–³⁹Ar dating indicates that both the skarn-type and porphyry-type orebodies of the Yinjiagou deposit formed approximately 143 Ma ago during the Early Cretaceous. Four types of fluid inclusions (FIs) have been distinguished in quartz phenocryst, various quartz veins, and calcite vein. Based on petrographic observations and microthermometric criteria the FIs include liquid-rich, gas-rich, H₂O–CO₂, and daughter mineral-bearing inclusions. The homogenization temperature of FIs in quartz phenocrysts of K-feldspar granite porphyry ranges from 341 °C to >550 °C, and the salinity is 0.4–44.0 wt% NaCl eqv. The homogenization temperature of FIs in quartz–molybdenite veins is 382–416 °C, and the salinity is 3.6–40.8 wt% NaCl eqv. The homogenization temperature of FIs in quartz–calcite–pyrite–chalcopyrite–bornite–sphalerite ranges from 318 °C to 436 °C, and the salinity is 5.6–42.4 wt% NaCl eqv. The homogenization temperature of FIs in quartz–molybdenite stockworks is in a range of 321–411 °C, and the salinity is 6.3–16.4 wt% NaCl eqv. The homogenization temperature of FIs in quartz–sericite–pyrite is in a range of 326–419 °C, and the salinity is 4.7–49.4 wt% NaCl eqv. The ore-forming fluids of the Yinjiagou deposit are mainly high-temperature, high-salinity fluids, generally with affinities to an H₂O–NaCl–KCl ± CO₂ system. The δ¹⁸O_H2O values of ore-forming hydrothermal fluids are 4.0–8.6‰, and the δD_V-SMOW values are between −64‰ and −52‰, indicating that the ore-forming fluids were primarily magmatic. The δ³⁴S_V-CDT values of sulfides range between −0.2‰ and 6.3‰ with a mean of 1.6‰, sharing similar features with deeply sourced sulfur, implying that the sulfur mainly came from the lower crust composed of poorly differentiated igneous materials, but part of the heavy sulfur came from the Guandaokou Group dolostone. The ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb values of sulfides are in the range of 17.331–18.043, 15.444–15.575, and 37.783–38.236, respectively, which is generally consistent with the Pb isotopic signature of the Yinjiagou intrusion, suggesting that the Pb chiefly originated from the felsic–intermediate intrusive rocks in the mine area, with a small amount of lead from strata. The Yinjiagou deposit is a porphyry–skarn deposit formed during the Mesozoic transition of a tectonic regime that is EW-trending to NNE-trending, and the multiepisode boiling of ore-forming fluids was the primary mechanism for mineral deposition.     

Seismic structure of the Helan–Liupan–Ordos western margin tectonic belt in North-Central China and its geodynamic implications

We study high-resolution three-dimensional P-wave velocity (Vp) tomography and anisotropic structure of the crust and uppermost mantle under the Helan–Liupan–Ordos western margin tectonic belt in North-Central China using 13,506 high-quality P-wave arrival times from 2666 local earthquakes recorded by 87 seismic stations during 1980–2008. Our results show that prominent low-velocity (low-V) anomalies exist widely in the lower crust beneath the study region and the low-V zones extend to the uppermost mantle in some local areas, suggesting that the lower crust contains higher-temperature materials and fluids. The major fault zones, especially the large boundary faults of major tectonic units, are located at the edge portion of the low-V anomalies or transition zones between the low-V and high-V anomalies in the upper crust, whereas low-V anomalies are revealed in the lower crust under most of the faults. Most of large historical earthquakes are located in the boundary zones where P-wave velocity changes drastically in a short distance. Beneath the source zones of most of the large historical earthquakes, prominent low-V anomalies are visible in the lower crust. Significant P-wave azimuthal anisotropy is revealed in the study region, and the pattern of anisotropy in the upper crust is consistent with the surface geologic features. In the lower crust and uppermost mantle, the predominant fast velocity direction (FVD) is NNE–SSW under the Yinchuan Graben and NWW–SEE or NW–SE beneath the Corridor transitional zone, Qilian Orogenic Belt and Western Qinling Orogenic Belt, and the FVD is NE–SW under the eastern Qilian Orogenic Belt. The anisotropy in the lower crust may be caused by the lattice-preferred orientation of minerals, which may reflect the lower-crustal ductile flow with varied directions. The present results shed new light on the seismotectonics and geodynamic processes of the Qinghai–Tibetan Plateau and its northeastern margin.     

Silicate melt inclusions in the Qiushuwan granitoids,northern Qinling belt,China: Implications for the formation of a porphyry Cu–Mo deposit as a reduced magmatic system

Melt inclusions (MIs) in quartz from granitoids in the northern Qinling belt were studied using microthermometry and laser Raman spectroscopy. The total homogenization of melt inclusions occurs in a mean range between 1050 and 1100 °C. Laser Raman experiments reveal H₂O, C₂H₆, C₄H₆ and CH₄ as the dominant volatile compounds. Our results provide insights into the temperatures of magma crystallization and the dominantly reducing environment during the early magmatic stage. Based on ore mineralogy, and on the volatile species content in the MIs, we evidence firstly that the Qiushuwan porphyry Cu–Mo deposit in the Qinling–Dabie–Sulu orogenic belt was derived from a reduced magmatic system, emplaced at relatively deep domains more than 10 km deep, and secondly, that the magmas that are responsible for the generation of Qiushuwan were either derived from an inherently reduced source, or reduced during ascent and emplacement. The mechanism might have involved the assimilation of sedimentary material with minimal crustal interaction. The parental magmas likely underwent reduction essentially by loss of all of their SO₂ by degassing, as evidenced by the low S content in melt inclusions. These reduced materials provided adequate sulfur source for the formation of the porphyry Cu–Mo deposits with obvious zonation, which plays a key role in the mineralization; finally, we conclude that the reduced environment and the relatively deep domain of magma emplacement probably limited the extent of mineralization, generating only a relatively small Cu–Mo deposit in Qiushuwan, located within the northern Qinling accretionary belt.     

内蒙古莫力达瓦旗哈达阳绿泥石白云母构造片岩LA-ICP-MS锆石U-Pb年龄及其地质意义

嫩江—黑河构造带地处松嫩地块与兴安地块的结合部位,一直以来是业内学者关注的焦点。在构造带内内蒙古莫力达瓦旗哈达阳一带野外实地调研过程中,发现一套变质变形程度与周围地质体差异很大的地层。岩石组合为绿泥石白云母构造片岩、二云母微晶片岩、黝帘白云糜棱片岩等。采用LA-ICP-MS技术获得的绿泥石白云母构造片岩中锆石U-Pb年龄为413.9Ma±2.7Ma。通过分析区域地质演化历史及不同时代地质体特征,认为沿红山梁—哈达阳—依克特一带存在一条构造混杂堆积岩带,这套强变形岩石应为构造混杂岩带的一部分,其原岩形成时代为早泥盆世,后期构造定位应与嫩江—黑河构造带最后于早石炭世末拼合作用有关。     

Geochemistry,and zircon U–Pb and molybdenite Re–Os geochronology of Jilongshan Cu–Au deposit,southeastern Hubei Province,China

The Jilongshan skarn Cu–Au deposit is located at the Jiurui ore cluster region in the southwestern part of the Middle–Lower Yangtze River valley metallogenic belt. The region is characterized by NW‐, NNW‐ and EW‐trending faults and the mineralization occurs at the contact of lower Triassic carbonate rocks and Jurassic granodiorite porphyry intrusions. The intrusives are characterized by SiO₂, K₂O, and Na₂O concentrations ranging from 61.66 to 67.8 wt.%, 3.29 to 5.65 wt.%, and 2.83 to 3.9 wt.%, respectively. Their A/CNK (A/CNK = n(Al₂O₃)/[n(CaO) + n(Na₂O) + n(K₂O)]) ratio, δEu, and δCe vary from 0.77 to 1.17, 0.86 to 1, and 0.88 to 0.96, respectively. The rocks show enrichment in light rare earth elements ((La/Yb)_N = 7.61–12.94) and large ion lithophile elements (LILE), and depletion in high field strength elements (HFSE), such as Zr, Ti. They also display a peraluminous, high‐K calc‐alkaline signature typical of intrusives associated with skarn and porphyry Cu–Au–Mo polymetallic deposits. Laser ablation inductively coupled plasma spectrometry (LA‐ICP‐MS) zircon U–Pb age indicates that the granodiorite porphyry formed at 151.75 ± 0.70 Ma. A few inherited zircons with older ages (677 ± 10 Ma, 848 ± 11 Ma, 2645 ± 38 Ma, and 3411 ± 36 Ma) suggest the existence of an Archaean basement beneath the Middle–Lower Yangtze River region. The temperature of crystallization of the porphyry estimated from zircon thermometer ranges from 744.3 °C to 751.5 °C, and 634.04 °C to 823.8 °C. Molybdenite Re–Os dating shows that the Jilongshan deposit formed at 150.79 ± 0.82 Ma. The metallogeny and magmatism are correlated to mantle–crust interaction, associated with the subduction of the Pacific Plate from the east. Copyright © 2013 John Wiley & Sons, Ltd.     

南非主要金矿集区研究现状及存在问题

南非是世界上金矿石资源量最为丰富的国家,其金矿床主要产于东北部地区,主要有三种类型:1赋存于兰德盆地砾岩型建造中的"兰德"砾岩型金矿床,2产在绿岩带中的绿岩带型金矿床,和3主要与白云岩有关的白云岩型金矿床,以前两种类型为主。"兰德"砾岩型金矿床通常品位高,开采规模最大,目前采矿的深度最大,是南非最重要的矿床类型,其矿床成因长期以来存有争议,主要有两种观点,分别是砂矿模式和热液模式,就目前资料来看笔者等认为其代表了两个不同的矿化阶段;绿岩带型金矿床则以巴伯顿地区为代表,矿床具有规模大、易开采等特征,因此在南非金矿床开采中占有重要位置,其矿床主要赋存于石英脉或剪切带中,矿床成因主要有三种,分别是火山成矿模式、转换滑脱构造模式和构造交叉模式。     

黑龙江争光金矿床隐爆角砾岩特征及其地质意义

黑龙江争光金矿床位于大兴安岭东北缘的多宝山矿集区,矿体主要呈脉状产于燕山期闪长岩体与中奥陶统多宝山组的内外接触带上,受断裂构造控制明显。在野外地质调查过程中,发现了3个隐爆角砾岩体（J-1、J-2、J-3）,角砾岩体从中心向外侧有较显著的岩石类型分带,中心为热液隐爆角砾岩,向外角砾增大,逐渐过渡为震碎角砾岩。根据胶结物的不同和穿插关系可将其分为四期,最早期为硅质胶结,中期为绿泥石胶结,其次为矿质胶结,最后为灰黑色安山质胶结,其中第二期和第三期隐爆作用与矿化关系密切。通过对隐爆角砾岩地质特征的研究,结果表明在Ⅱ号矿带绿泥石胶结隐爆角砾岩体深部具有寻找与矿质胶结隐爆角砾岩有关金铜矿化体的潜力,这对争光金矿床深部及外围找矿具有一定的指导意义。     

赞比亚西北省铜-钴矿地质及找矿潜力

[摘 要]赞比亚位于著名的中非新元古代沉积型铜（-钴）矿带上,铜带省和西北省是该国最主要的铜-钴矿集中分布区;相对于找矿程度已经很高的铜带省,西北省成矿地质条件优越,且地质工作程度较低,因此拥有巨大的找矿潜力,已成为该国找矿突破的重点区域。目前西北省主要著名的矿山/矿床有3个：坎桑希、卢穆瓦纳、卡伦比拉。这些铜-钴-金-铀-镍矿床的含矿地层、矿化特征与铜带省传统经典的沉积型铜-钴矿既有相似性,又明显具有差别。本文通过对西北省区域地质和已发现矿床地质特征的介绍,对该省的找矿潜力进行初步分析。