On the pH-dependent formation constants of iron(III)-sulfur(IV) transient complexes

An experimental study is described of Fe(III)-S(IV) formation constants measured as a function of pH (1–3), ionic strength (0.2–0.5 M) and [Fe(III)] _T (2.5–5.0×10^–4 M) using a continuous-flow spectrophotometric technique to make observations 160 ms after mixing. Preliminary experiments using pulse-accelerated-flow (PAF) spectrophotometry to measure rate constants on a microsecond timescale are also described. The conditional formation constant at 25 °C can be modeled with the following equation: {ie307-1} where {ie307-2}K ₇ andK ₈ can be interpreted as intrinsic constants for the coordination of HSO ₃ ^– by FeOH²⁺ and Fe³⁺, respectively, but until further evidence is obtained they should be regarded as fitting constants. PAF spectrophotometry showed that the initial reaction of Fe(III) with S(IV) (pH 2.0) is characterized by a second-order rate constant of 4×10⁶ M^–1 s^–1 which is comparable to rate of reaction of FeOH²⁺ with SO ₄ ^2– . However, the PAF results should be regarded as preliminary since unexpected features in the initial data indicate that the reaction may be more complex than expected.     

Kinetics of redox cycling of iron coupled with fulvic acid

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.     

地下水非稳定流的LTFAM算法

渗流域内应用拉普拉斯变换(LT)建立相应的有限分析(FAM)方程,顾及渗流域内地下水流的初始条件和边界条件,可在LT空间构成一个封闭的以水头像函数为变量的线性方程组。将此方程组所得的解,通过Stehfest数值反演公式,可归化为时间域的解(水头)。由于时间t被隐含在数值方程内,从而克服了传统数值法按时段(△t)逐步迭代的缺陷,提高了计算效率,也为用嵌入法建立地下水流管理模型提供了一条捷径。     

基于土地适宜性评价与元胞自动机模型的城市开发边界划定方法

城市开发边界的划定可以在一定程度上引导城市空间的良性扩张。为了研究边界划定的方法,以我国某港口城市作为研究区域,在空间增长模拟的方向进行探索。研究中借助土地适宜性评价和元胞自动机边界工具,构建既符合生态资源环境要求又符合城市发展需要的边界划定,同时,为了实现城市用地健康和动态管控举措,提出了建立健全土地用地管理机制的要求。     

随钻测录井地质导向二维分解实时绘图方法

根据随钻测录井实时地质导向和大斜度、水平井评价成图技术需求，针对传统绘图方法存在的弊端，提出了将测录井信息、井眼轨迹和地质模型进行二维分解的实时绘图方法。针对二维分解绘图方法绘图时空复杂度较高的问题，给出了不同事件驱动下的局部实时计算和拷屏重绘算法，控制了对CPU和内存的消耗、提高了绘图效率，消除了实时绘图的闪烁和卡顿现象。应用实例表明，二维分解实时绘图方法能够实现大尺度随钻测录井地质导向图形的流畅、无卡顿实时绘图，可提高大斜度、水平井储层模型评价的刻画精度和时效。     

四川木里耳泽岩溶型金矿床形成条件和成矿机制

四川本里耳泽金-菱铁矿建造矿床,赋存于上二叠统海相碳酸盐岩层中,矿化受古岩溶的严格控制,组成矿石的基本矿物为菱铁矿,金不均匀地分布于菱铁矿矿体内。成矿溶液来自加热的循环地下水。成矿过程分为早阶段和中-晚阶段。成矿温度为156-210℃,成矿深度小于1km.成矿物质主要来自地层。成矿热液呈碱性和弱还原性,贫硫,含中等盐度。矿床形成时的地质构造环境较稳定。这是我国仅见的一种特殊金矿类型。     

贵州中三叠统烂泥沟金矿有机质的初步研究

烂泥沟金矿是以浊积岩为容矿岩石的微细浸染型金矿。有机岩石学分析表明,矿石与围岩中干酪根类型无明显差别,同属腐泥-腐植型。与围岩相比,矿石中干酪根成熟度(R₀=2.74%-3.06%)和含金性(6.15-24.8μg/g)均较高;干酪根总含金量在全岩中所占的比例是围岩高于矿石。氯仿沥青“A”的检测说明,矿石样品中可溶性有机质形成于强还原和高盐度环境,沥青质和含硫有机化合物发育。研究认为,干酪根含金性与碳的活化有关;不饱和的有机基因对金的动一定转换可能具有重要意义。     

扬子地台前寒武纪－寒武纪界线地层的微体植物化石群

前寒武纪一寒武纪界线地层在扬子地台发育良好、分布广泛,并有包括微体植物群、海藻、瓶形原生物、具硬体动物及‘澄江动物群’等化石的发现。因而,扬子地台成为研究前寒武纪－寒武纪界线生物地层的代表地区之一。基于对扬子地台前寒武纪－寒武纪界线地层已知微体植物化石记录的回顾和论定,总结概括了下寒武统微体植物化石组合：寒武系最底部硅质磷块岩中的Ｍｉｃｒｈｙｓｔｒｉｄｉｕｍ－Ｐａｒａｃｙｍａｔｉｏｓｐｈａｅｒａ－Ｍｅｇａｔｈｒｉｘ组合和较高层位页岩的Ｓｋｉａｇｉａ－Ａｎｎｕｌｕｍ－Ａｒｃｈａｅｏｄｉｓｃｉｎａ组合。它们分别与Ａｎａｂａｒｉｔｅｓ－Ｃｉｒｃｏｔｈｅｃａ－Ｐｒｏｔｏｈｅｒｔｚｉｎａ小壳动物化石带和Ｐａｒａｂａｄｉｅｌｌａ及Ｅｏｒｅｄｌｉｃｈｉａ三叶虫带相对应。与东欧地台疑源类生物地层相对照,扬子地台Ｍｉｃｒｈｙｓｔｒｉｄｉｕｍ－Ｐａｒａｃｙｍａｔｉｏｓｐｈａｅｒａ－Ｍｅｇａｔｈｒｉｘ组合的纵向分布大体和东欧地台Ａｓｔｅｒｉｄｉｕｍｔｏｒｎａｔｕｍ－Ｃｏｍａｓｐｈａｅｒｉｄｉｕｍｖｅｌｖｅｔｕｍ组合带相一致,而以上两地台的化石组合产出层位可能都略高于纽芬兰东部剖面,依据Ｐｈｙｃｏｄｅｓｐｅｄｕｍ所厘定的寒武系底界?     

坡地农林复合系统的结构类型与效益分析─以长江三峡库区坡地农业为例

本义认为现代术语的农林复合系统来源于生产实践,体现了农业与林业的有机结合、品种生态和经济的有机结合、产品多样化以及管理科学化4个方面相统一的特点。文章在分析三峡库区农林复合系统的类型结构基础上,提出了农林复合系统可以进行层次结构划分的观点。最后,以典型案例研究方法入手,对1种农林结构类型进行效益分析,结果表明,采用植物篱农林复合坡地系统,是现阶段生产力水平下实现坡地生态经济协调发展的有效途径,值得广泛推广。     

TOWARD ESTABLISHING THE CONCEPT OF PHYSICAL URBAN AREA IN CHINA

I.IntroduchollWiulegeOgraphystudiestheterritoria1systemsabouttherelationsbforeenhumanbeingSandthenature[I4],urbanmpaphyfocusesspecificallyonthespatialoopltizationandprocessofurbanterritory,anditsinteraCtionwiti1Otherterritorialsystems.Usually,wedoresearch…