Genesis of Luobuzhen Pb–Zn veins: Implications for porphyry Cu systems and exploration targeting at Luobuzhen-Dongshibu in western Gangdese belt,southern Tibet

Porphyry systems are known to form in magmatic arc environment and commonly include porphyry Cu, epithermal Pb–Zn–Au–Ag, skarn polymetallic mineralization, etc. The systems are rarely reported in collisional zones, such as the Gangdese belt in southern Tibet where many postcollisional porphyry copper deposits occurred. In addition, other types of mineral systems are rarely present except porphyry copper mineralization in the Gangdese belt. In this study, we present Pb–Zn-bearing quartz veins at Luobuzhen in the western Gangdese belt. The Luobuzhen Pb–Zn veins cross-cut dacite of the Linzizong Group with zircon U–Pb age of 50.1 ± 0.2 Ma and monzogranite with zircon U–Pb age of 17.1 ± 0.1 Ma. Ore minerals include sphalerite, galena, chalcopyrite, and pyrite; gangue minerals are quartz with minor chlorite and sericite. Primary fluid inclusions of quartz are liquid-rich, aqueous, and two-phase inclusions. The homogenization temperatures of these primary inclusions are moderate to high (267–400 °C), and salinities range from 8.9 to 18.4 wt.% NaCl equiv. Quartz has δ¹⁸O_SMOW values of 6.2–9.3‰, while sulfides have δ³⁴S_V-CDT values of −5.1‰ to 0.1‰, ²⁰⁶Pb/²⁰⁴Pb of 18.722–18.849, ²⁰⁷Pb/²⁰⁴Pb of 15.640–15.785, and ²⁰⁸Pb/²⁰⁴Pb of 39.068–39.560. These data suggest that magmatic fluids with contribution from meteoric water, magmatic sulfur, and lead derived from upper crust and metasomatized mantle by Indian continental materials would be critical for the Luobuzhen base metal mineralization.The Dongshibu area, located at ∼2 km east of the Luobuzhen, is characterized by high concentrations of Cu (up to 1450 ppm) and Mo (up to 130 ppm) of stream sediments, which is quite different from high concentrations in Pb, Zn, Ag, and Au shown in the Luobuzhen area. In addition, porphyry copper mineralization-related alteration and veins/veinlets occur in the Miocene monzogranite at Dongshibu. The monzogranite is characterized by high Sr/Y ratios, which are also shown on ore-forming intrusions in the Gangdese postcollisional porphyry copper deposits, and shows similar zircon Hf isotopes to the ore-related high Sr/Y intrusions from the Zhunuo porphyry copper deposit which is located ∼20 km northeast of the Luobuzhen-Dongshibu. A comprehensive analysis allows us to infer that the base metal veins at Luobuzhen are components of a porphyry Cu system with porphyry Cu mineralization likely present at Dongshibu and epithermal Au–Ag veins possibly occurring at Luobuzhen, which are indicative of the existence of porphyry copper systems in collisional zones. The potential porphyry Cu mineralization and epithermal Au–Ag veins should be targeted in future exploration at Luobuzhen-Dongshibu.     

南迦巴瓦构造结墨脱地区高Sr/Y花岗岩的成因: 地球化学、锆石U-Pb年代学及Hf同位素约束

墨脱花岗岩带位于南迦巴瓦构造结东侧,是冈底斯岩浆带的东南延伸部分。本文报道了该地区背崩和达木2个花岗岩体的全岩地球化学、锆石U-Pb年代学及锆石Hf同位素数据。锆石U-Pb定年结果表明,背崩和达木花岗岩体的年龄分别为62Ma和64.5Ma。岩石地球化学数据显示,两个花岗岩体SiO2含量为71.09%～74.37%,K2O的含量为1.38%～5.93%,A/CNK为1.01～1.02,均属于高钾钙碱性过铝质岩石。所有样品均显示出强烈的轻、重稀土分异((La/Dy)N=13.55～31.3;(La/Yb)N=16.82～50.41),平坦的Ho到Lu稀土元素分布样式((Ho/Yb)N=0.93～1.42),δEu主要介于0.78～1.09,总体上具有正-微弱负异常,具较高Ba、Sr/Y,La/Yb和低Y,Mg#(<45),亏损HFSE元素(Nb、Ti、Zr)。墨脱高Sr/Y花岗岩具有不均一的εHf(t)值(-11.22～4.87)和相对年轻的Hf模式年龄(552～1179Ma)。锆石Hf同位素数据和锆石饱和温度(746～791℃)均显示幔源物质在墨脱花岗岩形成过程中发挥了较为重要的作用。墨脱高Sr/Y花岗岩可能是在印度-亚洲大陆碰撞阶段,由新特提斯洋俯冲过程中产生的基性岩浆底侵作用使陆壳熔融并发生壳幔岩浆混合作用所形成。     

新疆喀拉通克铜镍硫化物矿床Y9岩体年代学与成岩成矿机制探讨

新疆喀拉通克是中国大型铜镍硫化物矿床中基性程度最低的,显示出罕见的Cu平均品位大于Ni平均品位。矿区划分为南、北2个岩带,南岩带主要为原生矿,北岩带主要为氧化矿。文章研究对象为北岩带中的Y9岩体,近年发现其下部存在原生矿石。通过单颗粒锆石SHRIMP测年,获得Y9岩体中辉长岩的结晶年龄为(287±4)Ma,与Y1岩体的成岩年龄〔(287±5)Ma〕一致,结合岩石地球化学和同位素地球化学特征,证明喀拉通克矿区南、北岩带具有同期同源岩浆演化的特征,岩浆源自亏损型地幔部分熔融与不含沉积物消减板片脱水物质的混合。研究认为喀拉通克铜镍矿床形成于亏损地幔在相对较高的氧逸度条件下低程度部分熔融,产生硫化物不饱和的岩浆,岩浆源区相对富水和较高的氧逸度,原始岩浆具有较高的钛含量,具有富碱亲合性。     

盘南刘家田井田逆冲推覆构造特征

刘家田井田总体构造特征为逆冲推覆构造,主要分为F2断层下盘基底构造单元和上盘推覆体构造单元。推覆体构造单元断层主要发育在推覆体前缘和西部软弱岩组一带,并伴有褶皱现象。基底单元东部断层较发育,构造相对简单;西部由于受推覆构造运动的影响,断层较发育,与F4断层呈"y"形组合特征,破坏了煤层的连续性,对煤层赋存产生较大影响。加强刘家田井田构造特征及控煤作用分析,对该井田深部及盘县逆冲断裂带附近找煤具有重要意义。     

Mo-related Adakitic Granitoids from Non-island-arc Setting: Jecheon Pluton of South Korea

Abstract. The Jecheon granitoids, having an elongated shape of NE-SW 27 km and NW-SE 13 km (190 km²), are composed mostly of magnetite-series hornblende-biotite granodiorite and biotite granite, which intrude into the Neoproterozoic metamor-phic and Paleozoic sedimentary rocks of the Ogcheon Belt. The granitoids have Triassic-Jurassic age of 202.7 ±1.9 Ma with very high ⁸⁷Sr/⁸⁶Sr initial ratio of 0.7140. The granodiorite has 63–69 % SiO₂, 15.1–17.3 % Al₂O₃, <1.6 % MgO, 6–15 ppm Y and Sr/Y ratios of 24–76, and is depleted in HREE. Biotite granite together, the Jecheon pluton has adakitic characteristics, which are unique in a continental tectonic setting. The granitoids may have been generated by partial melting of an older adakitic granitoid of I-type basement, or by separation of early crystallized garnet and hornblende from an anatectic melt.     

东海盆地X凹陷Y气田的天然气成因、成藏模式及勘探意义

本文旨在厘清东海盆地X凹陷Y气田天然气成因,建立成藏模式,以指导下步勘探部署。本文从天然气组分、烷烃气碳同位素、轻烃、凝析油生物标志化合物等分析入手,系统研究了油气成因类型及来源,并结合构造演化史、生烃史分析,建立了Y气田成藏模式,提出了大中型气田的勘探方向。主要认识如下：（1）天然气组分碳同位素、轻烃和埋藏史分析表明,Y气田天然气为凹中始新统平湖组烃源岩在龙井运动期（距今13 Ma）生成的高成熟煤型气;（2）凝析油姥鲛烷/植烷、规则甾烷等特征,反映了凹中区平湖组烃源岩发育于弱氧化−弱还原潮坪、潟湖沉积环境,生烃母质中存在一定数量的低等水生生物;（3）Y气田具有“凹中区平湖组烃源岩、花港组大型水道砂储集体、挤压构造作用”时空耦合的成藏模式,明确了凹中挤压背斜带是X凹陷大中型气田勘探的主攻方向。     

藏南冈底斯南缘程巴岩体高Sr/Y花岗闪长岩和包体形成机制及Sr-Nd-Hf同位素制约

程巴岩体位于藏南冈底斯岩基东段南缘,由花岗闪长岩、细粒闪长质包体等组成。测得的锆石U-Pb年龄可以代表岩石的形成年龄,即花岗闪长岩形成年龄为29.40±0.18Ma与29.42±0.25Ma,细粒闪长质捕虏体形成年龄为30.02±0.15Ma。花岗闪长岩具有较高的Si O2(65.2%~66.2%)、K2O(3.2%~4.0%),较低的铁(TFe O=3.2%~4.0%)和Mg O(约2%),同时具有高Sr(774×10-6~813×10-6)、低Y(9.9×10-6~11.2×10-6)、高Sr/Y值(63.4~82.2)等特征;闪长质包体表现出较低的Si O2(53%~56.1%)和K2O(1.5%~3.2%),较高的铁(TFe O=6.1%~8.1%)、Mg O(4.0%~6.2%)和Na2O/K2O≥2,同时具有负Eu异常(Eu/Eu*=0.432~0.804)。2种岩性都富集LREE及LILE,亏损HREE及HFSE,具有较高且一致的εHf(t)值(+1.1~+6.2)和全岩εNd(t)值(-2.9~-5.9)。以上数据表明,花岗闪长岩与细粒闪长质包体由同一岩浆分离结晶形成,花岗闪长岩经历磷灰石和角闪石的分离结晶,其高Sr/Y值为岩浆分离结晶的结果,并不代表原始岩浆组分。     

Petrogenesis of Permo-Triassic intrusive rocks in Northern Liaoning Province,NE China: implications for the closure of the eastern Paleo-Asian Ocean

ABSTRACT

The Changchun-Yanji belt recorded widespread Permo-Triassic magmatism, but their origins remain unclear, inhibiting a comprehensive understanding of the magmatic response to the final closure of the Paleo-Asian ocean in the eastern Central Asian Orogenic Belt (CAOB). Here, we present new geochronological, geochemical, and Hf isotopic data for the Permo-Triassic plutons from Northern Liaoning province, NE China. Combined the published ages with our new data, the Permo-Triassic magmatism in the eastern CAOB can be divided into five episodes: early Permian (293–274 Ma), middle–late Permian (270–257 Ma), latest late Permian–Middle Triassic (255–242 Ma), Late Triassic (240–215 Ma), and latest Late Triassic (209–200 Ma). The middle Permian and Late Triassic mafic plutons (i.e. ~266 Ma Mengjiagou gabbro–diorite, ~240 Ma Jiancaicun gabbro and ~224 Ma Shudetun gabbro-diorite) contain relatively high TFe₂O₃, MgO, Cr and Ni contents with positive ε_Hf(t) values (+1.2 to +7.2), suggesting a depleted mantle origin. These mafic rocks together with the coeval granitoids make up typical bimodal associations, suggesting that they were formed under an extensional environment. The conclusions are also supported by occurrence of A-type granites during 270–257 Ma and 240–215 Ma. By contrast, the granitoids of 255–242 Ma in the eastern CAOB, including the Jianshanzi (~251 Ma) and Daganhe (~242 Ma) monzogranites, show typical geochemical features of adakitic granites, with high Sr/Y ratios and negative ε_Hf(t) values (–8.6 to – 22.0), suggesting that the magmas were generated through partial melting of thickened ancient lower crust. Combined with previous studies, a four-stage tectonic evolution scenario was proposed: (1) active continental margin stage during 293–274 Ma; (2) continuing subduction resulted in the initiation collision, moderate crustal thickening, and slab break-off during 270–257 Ma; (3) final closure of the Paleo-Asian Ocean associated with continued crustal thickening occurred during 255–242 Ma; (4) lithospheric delamination in a post-collisional extensional environment occurred during 240–215 Ma.     

化学共沉淀法制备小颗粒红色荧光粉(Y,Gd)BO3∶Eu3+

为了满足彩色等离子体平板显示(PDP)用荧光粉的要求,采用化学共沉淀法并结合超声波分散技术制备PDP用(Y,Gd)BO3∶Eu3 红色荧光粉.在稀土离子浓度、烧结温度等实验的基础上,得到分子式为(Y0.85Gd0.1)BO3∶Eu0.05、烧结温度为1 000℃的最佳实验方案.同时选择了不同的分散试剂并结合超声波分散技术对样品进行了后处理实验.结果表明:当分散试剂为乙醇时,样品的相对发光强度最高;同时,采用后处理试剂并结合超声波分散技术对样品进行后处理大大降低了粉体的团聚现象并增强了粉体的分散性,提高了粉体的质量.与传统的固相法相比,此法不仅大大降低了合成温度,同时,粉体的质量比固相法合成的要好,粉体的亮度高(以国外红粉为参考),样品经后处理后,颗粒细小、均匀,粒径分布约为300 nm.     

北虫草菌Y3胞内与胞外多糖的免疫药理研究

对北虫草菌Ｙ３胞内与胞外多糖的免疫药理活性进行实验研究。结果表明,北虫草多糖可显著提高小鼠腹腔巨噬细胞吞噬功能,增强血清溶菌酶活力,提高小鼠肝、红细胞ＳＯＤ活力,并可对抗环磷酰胺引起的外周血白细胞数目下降。北虫草菌Ｙ３多糖对小鼠迟发型超敏反应与溶血空斑实验都有促进作用,提示其对特异性与非特异性免疫的增强作用。